Recent Approaches for the Determination of Forming Limits by Necking and Fracture in Sheet Metal Forming

Forming limit diagrams (FLD’s) are used to evaluate the workability of metal sheets. FLD’s provide the failure locus at which plastic instability occurs and localized necking develops (commonly designated as the forming limit curve - FLC), and the failure loci at the onset of fracture by tension (FFL) or by in-plane shear (SFFL). The interest of metal formers in controlling localized necking is understandable because the consequence of plastic instability is an undesirable surface blemish in components. However, because under certain loading conditions fracture can precede necking in sheet metal forming processes, there is a growing interest in characterizing the forming limits by necking and fracture in the FLD’s. This paper gathers together a number of recently developed methodologies for detecting the onset of local necking and fracture by in-plane tension or in-plane shear, and discusses their applicability to determine experimentally the FLC’s, FFL’s and SFFL’s.Ministerio de Economía y Competitividad DPI2012-3291

Tube Expansion by Single Point Incremental Forming: An Experimental and Numerical Investigation

In this paper, we revisit the formability of tube expansion by single point incremental forming to account for the material strain hardening and the non-proportional loading paths that were not taken into consideration in a previously published analytical model of the process built upon a rigid perfectly plastic material. The objective is to provide a new insight on the reason why the critical strains at failure of tube expansion by single point incremental forming are far superior to those of conventional tube expansion by rigid tapered conical punches. For this purpose, we replaced the stress triaxiality ratio that is responsible for the accumulation of damage and cracking by tension in monotonic, proportional loading paths, by integral forms of the stress triaxiality ratio that are more adequate for the non-proportional paths resulting from the loading and unloading cycles of incremental tube expansion. Experimental and numerical simulation results plotted in the effective strain vs. stress triaxiality space confirm the validity of the new damage accumulation approach for handling the non-proportional loading paths that oscillate cyclically from shearing to biaxial stretching, as the single point hemispherical tool approaches, contacts and moves away from a specific location of the incrementally expanded tube surface.Junta de Andalucía (Consejería de Economía y Conocimiento) US-1263138Fundação para a Ciência e da Tecnologia of Portugal UIDB/50022/202

Estimating the time-dependent performance of nanocatalysts in fuel cells based on a cost-normalization approach

CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQCOORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPESResearchers have developed new catalysts for fuel cells (FC), whose performances are compared after applying different normalization procedures. However, there is not a standard procedure. The current produced from CO electrooxidation was compared for Pt4271119801988CONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQCOORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPESCONSELHO NACIONAL DE DESENVOLVIMENTO CIENTÍFICO E TECNOLÓGICO - CNPQCOORDENAÇÃO DE APERFEIÇOAMENTO DE PESSOAL DE NÍVEL SUPERIOR - CAPES454516/2014-2SEM INFORMAÇÃOThe authors acknowledge financial assistance from CNPq (grant No. 454516/2014-2), FUNDECT (grant No. 026/2015), CAPES and FINE

Assessing the efficiency of protected areas to represent biodiversity : a small island case study

Protected areas (PAs) have been selected using either subjective or objective criteria applied to an extremely limited subset of biodiversity. Improved availability of species distribution data, better statistical tools to predict species distributions and algorithms to optimize spatial conservation planning allow many impediments to be overcome, particularly on small islands. This study analyses whether 219 species are adequately protected by PAs on Pico Island (theAzores, Portugal), and if they are as efficient as possible, maximizing species protection while minimizing costs. We performed distribution modelling of species’ potential distributions, proposed individual conservation targets (considering the context of each species in the archipelago and their current conservation status) to determine the efficiency of current PAs in meeting such targets and identify alternative or complementary areas relevant for conservation. Results showed that current PAs do not cover all taxa, leaving out important areas for conservation. We demonstrate that by using optimization algorithms it is possible to include most species groups in spatial conservation planning in the Azores with the current resources. With increasing availability of data and methods, this approach could be readily extended to other islands and regions with high endemism levels.info:eu-repo/semantics/publishedVersio

Aryl-capped lysine-dehydroamino acid dipeptide supergelators as potential drug release systems

Employing amino acids and peptides as molecular building blocks provides unique opportunities for generating supramolecular hydrogels, owing to their inherent biological origin, bioactivity, biocompatibility, and biodegradability. However, they can suffer from proteolytic degradation. Short peptides (<8 amino acids) attached to an aromatic capping group are particularly attractive alternatives for minimalistic low molecular weight hydrogelators. Peptides with low critical gelation concentrations (CGCs) are especially desirable, as the low weight percentage required for gelation makes them more cost-effective and reduces toxicity. In this work, three dehydrodipeptides were studied for their self-assembly properties. The results showed that all three dehydrodipeptides can form self-standing hydrogels with very low critical gelation concentrations (0.050.20 wt%) using a pH trigger. Hydrogels of all three dehydrodipeptides were characterised by scanning tunnelling emission microscopy (STEM), rheology, fluorescence spectroscopy, and circular dichroism (CD) spectroscopy. Molecular modelling was performed to probe the structural patterns and interactions. The cytotoxicity of the new compounds was tested using human keratinocytes (HaCaT cell line). In general, the results suggest that all three compounds are non-cytotoxic, although one of the peptides shows a small impact on cell viability. In sustained release assays, the effect of the charge of the model drug compounds on the rate of cargo release from the hydrogel network was evaluated. The hydrogels provide a sustained release of methyl orange (anionic) and ciprofloxacin (neutral), while methylene blue (cationic) was retained by the network.This work was supported by the Portuguese Foundation for Science and Technology (FCT) in the framework of the Strategic Funding of CQUM (UID/QUI/00686/2019), IPC (UIDP/CTM/05256/2020 and UIDB/05256/2020) and REQUIMTE/LAQV (UIDB/50006/2020). L.H. acknowledges grant CEECINST/00156/2018. FCT, FEDER, PORTUGAL2020 and COMPETE2020 are also acknowl edged for funding under research project PTDC/QUI-QOR/29015/2017 (POCI-01-0145-FEDER 029015). TGC thanks FCT under the scope of the strategic funding of UIDB/04469/2020 unit, and LABBELS—Associate Laboratory in Biotechnology, Bioengineering and Microelectromechanical Systems, LA/P/0029/2020.info:eu-repo/semantics/publishedVersio

Object-oriented Programming Laws for Annotated Java Programs

Object-oriented programming laws have been proposed in the context of languages that are not combined with a behavioral interface specification language (BISL). The strong dependence between source-code and interface specifications may cause a number of difficulties when transforming programs. In this paper we introduce a set of programming laws for object-oriented languages like Java combined with the Java Modeling Language (JML). The set of laws deals with object-oriented features taking into account their specifications. Some laws deal only with features of the specification language. These laws constitute a set of small transformations for the development of more elaborate ones like refactorings

Rainfall Prediction in the State of Paraíba, Northeastern Brazil Using Generalized Additive Models

The state of Paraíba is part of the semi-arid region of Brazil, where severe droughts have occurred in recent years, resulting in significant socio-economic losses associated with climate variability. Thus, understanding to what extent precipitation can be influenced by sea surface temperature (SST) patterns in the tropical region can help, along with a monitoring system, to set up an early warning system, the first pillar in drought management. In this study, Generalized Additive Models for Location, Scale and Shape (GAMLSS) were used to filter climatic indices with higher predictive efficiency and, as a result, to perform rainfall predictions. The results show the persistent influence of tropical SST patterns in Paraíba rainfall, the tropical Atlantic Ocean impacting the rainfall distribution more effectively than the tropical Pacific Ocean. The GAMLSS model showed predictive capability during summer and southern autumn in Paraíba, highlighting the JFM (January, February and March), FMA (February, March and April), MAM (March, April and May), and AMJ (April, May and June) trimesters as those with the highest predictive potential. The methodology demonstrates the ability to be integrated with regional forecasting models (ensemble). Such information has the potential to inform decisions in multiple sectors, such as agriculture and water resources, aiming at the sustainable management of water resources and resilience to climate risk

Avaliar a eficiência das áreas protegidas para representar a biodiversidade: o caso de estudo de uma pequena ilha

A secção Biologia é coordenada pelo Professor Universitário Armindo Rodrigues.[…]. Nos Açores podem ser encontradas inúmeras espécies endémicas que tornam este arquipélago importante, do ponto de vista da conservação dos valores naturais. A rede de APs nos Açores está organizada em Parques Naturais de Ilha, no Parque Marinho dos Açores e em APs de importância local. O Parque Natural de Ilha (PNI) engloba diferentes categorias de áreas terrestres e marinhas, que possuem diferentes objectivos de conservação. No sentido de avaliar a adequação dos actuais limites das APs do ponto de vista da conservação das espécies, tendo a Ilha do Pico como caso de estudo, foram analisadas 219 espécies nativas dos Açores (briófitos, plantas vasculares, moluscos, artrópodes e vertebrados), na sua maioria endémicas. […].info:eu-repo/semantics/publishedVersio

Behavioural syndrome in a solitary predator is independent of body size and growth rate.

Models explaining behavioural syndromes often focus on state-dependency, linking behavioural variation to individual differences in other phenotypic features. Empirical studies are, however, rare. Here, we tested for a size and growth-dependent stable behavioural syndrome in the juvenile-stages of a solitary apex predator (pike, Esox lucius), shown as repeatable foraging behaviour across risk. Pike swimming activity, latency to prey attack, number of successful and unsuccessful prey attacks was measured during the presence/absence of visual contact with a competitor or predator. Foraging behaviour across risks was considered an appropriate indicator of boldness in this solitary predator where a trade-off between foraging behaviour and threat avoidance has been reported. Support was found for a behavioural syndrome, where the rank order differences in the foraging behaviour between individuals were maintained across time and risk situation. However, individual behaviour was independent of body size and growth in conditions of high food availability, showing no evidence to support the state-dependent personality hypothesis. The importance of a combination of spatial and temporal environmental variation for generating growth differences is highlighted