Shallow gas seismic structures: forms and distribution on Santa Catarina Island, Southern Brazil

Abstract This paper presents the spatial distribution of shallow gas structures and classifies them on the basis of two different data sets of CHIRP seismic records, one from the Conceição Lagoon (CL) and the other from North Bay (NB), both on Santa Catarina Island, Southern Brazil. Side scan sonar data from the CL were used to facilitate the understanding. The sub bottom (SB) seismic data were processed and interpreted by means of the SeisPrho software, the side scan sonar (SSS) data by SonarWiz5 software and the spatial extension being measured with the help of GIS. The shallow gas structures were defined in accordance with their shapes in the seismic recordings (echo-character). At the CL, shallow gas accumulations were found in the form of seepages and features presenting shallow gas structures between the surface and 8.20 ms (around 12.3 m). Accumulations of gas were found in the form of Acoustic Blanking with Acoustic Plume, and also Black Shadows. Pockmarks were found on the lagoon floor and associated with gas seepages (average size diameter 0.97 ± 0.19 m and density from 54 to 242 units per 50 m2). In the NB three types of shallow gas features were found in the seismic profile, namely Acoustic Blanking, Turbidity Pinnacles and Intra-sedimentary plumes. The depth varied from the surface to 12.10 ms (around 18.15 m). In both environments, the gas is escaping from the sediment into the water column. The Pockmarks in the CL and the Acoustic Plume features and sediment rich in total sulfur in the NB validate these findings

Effects of Casting Size on Microstructure and Mechanical Properties of Spheroidal and Compacted Graphite Cast Irons: Experimental Results and Comparison with International Standards

The aim of this research was to investigate the effects of casting size (10-210 mm) on the microstructure and mechanical properties of spheroidal (SGI) and compacted (CGI) graphite cast irons. A comparison of the experimental mechanical data with those specified by ISO standards is presented and discussed. The study highlighted that the microstructure and mechanical properties of SGI (also known as ductile or nodular cast iron) are more sensitive to casting size than CGI (also known as vermicular graphite cast irons). In particular, in both types of cast iron, hardness, yield strength and ultimate tensile strength decreased, with increasing casting size, by 27% in SGI and 17% in CGI. Elongation to failure showed, instead, an opposite trend, decreasing from 5 to 3% in CGI, while increasing from 5 to 11% in SGI. These results were related to different microstructures, the ferritic fraction being more sensitive to the casting size in SGI than CGI. Degeneration of spheroidal graphite was observed at casting size above 120 mm. The microstructural similarities between degenerated SGI and CGI suggested the proposal of a unified empirical constitutional law relating the most important microstructural parameters to the ultimate tensile strength. An outstanding result was also the finding that standard specifications underestimated the mechanical properties of both cast irons (in particular SGI) and, moreover, did not take into account their variation with casting size, at thicknesses over 60 mm

Designing a Novel Graphitic White Iron for Metal-to-Metal Wear Systems

Metal-to-metal wear systems are widely used in various industries, but heat-induced adhesive wear has been limiting the lifetime of the components for many years. An idea of introducing interconnected flake graphite networks into white iron was developed by the authors, which can potentially solve this problem by increasing the overall thermal conductivity. To optimize the thermal conductivity and wear resistance, five alloys with different chromium and carbon contents were designed, produced, and investigated to develop the first generation of graphitic white iron. Mathematical models were developed to correlate the graphite phase concentration and cooling rate with carbon equivalent. It was shown that graphite volume percent needs to be higher than 7 pct to have a consistent thermal conductivity increase. Hardness model developed in this article suggested that M7C3 has a higher hardness than the plate cementite, and hardness increases with increasing chromium content in the carbides. The as-solidified microstructure was characterized using a SEM, and solidification sequence was established for this novel alloy system. Unexpectedly, for the first time, study of alloy with 11 wt pct Cr shows that M7C3 was formed during eutectic reaction and then transformed into cementite at a lower temperature