Hybrid molecular dynamic Monte Carlo simulation and experimental production of a multi-component Cu-Fe-Ni-Mo-W alloy

ABSTRACT: High-entropy alloys are a class of materials intensely studied in the last years due to their innovative properties. Their unconventional compositions and chemical structures hold promise for achieving unprecedented combinations of mechanical properties. The Cu-Fe-Ni-Mo-W multicomponent alloy was studied using a combination of simulation and experimental production to test the possibility of formation of a simple solid solution. Therefore, Molecular Dynamics and hybrid Molecular Dynamic/Monte Carlo simulations from 10K up to the melting point of the alloy were analyzed together with the experimental production by arc furnace and powder milling. The Molecular Dynamics simulations starting with a bcc type-structure show the formation of a singlephase bcc solid solution type-structure, whereas using Monte Carlo one, generally produced a two-phase mixture. Moreover, the lowest potential energy was obtained when starting from a fcc type-structure and using Monte Carlo simulation giving rise to the formation of a bcc Fe-Mo-W phase and a Cu-Ni fcc type-structure. Dendritic and interdendritic phases were observed in the sample produced by arc furnace while the milled powder evidence an separation of two phases Cu-Fe-Ni phase and W-Mo type-structures. Samples produced by both methods show the formation of bcc and a fcc type-structures. Therefore, the Monte Carlo simulation seems to be closer with the experimental results, which points to a two-phase mixture formation for the Cu-Fe-Ni-Mo-W multicomponent system.info:eu-repo/semantics/publishedVersio

Damage threshold of CuCrFeTiV high entropy alloys for nuclear fusion reactors

A CuCrFeTiV high entropy alloy was prepared and irradiated with swift heavy ions in order to check its adequacy for use as a thermal barrier in future nuclear fusion reactors. The alloy was prepared from the elemental powders by ball milling, followed by consolidation by spark plasma sintering at 1178 K and 65 MPa. The samples were then irradiated at room temperature with 300 keV Ar+ ions with fluences in the 3 × 1015 to 3 × 1018 Ar+/cm2 range to mimic neutron-induced damage accumulation during a duty cycle of a fusion reactor. Structural changes were investigated by X-ray diffraction, and scanning electron microscopy and scanning transmission electron microscopy, both coupled with X-ray energy dispersive spectroscopy. Surface irradiation damage was detected for high fluences (3 × 1018 Ar+/cm2) with formation of blisters of up to 1 μm in diameter. Cross-sectional scanning transmission electron microscopy showed the presence of intergranular cavities only in the sample irradiated with 3 × 1018 Ar+/cm2, while all irradiation experiments produced intragranular nanometric-sized bubbles with increased density for higher Ar+ fluence. The Williamson-Hall method revealed a decrease in the average crystallite size and an increase in residual strain with increasing fluence, consistent with the formation of Ar+ bubbles at the irradiated surface.publishedVersio

Improvement of Mechanical Properties with Non-Equimolar CrNbTaVW High Entropy Alloy

ABSTRACT: CrNbTaVWx with (x = 1 and 1.7) high entropy alloys have been devised for thermal barriers between the plasma-facing tungsten tiles and the copper-based heat sink in the first wall of fusion nuclear reactors. These novel materials were prepared by ball milling and consolidated by Upgrade Field Assisted Sintering Technology at 1873 K under an applied pressure of 90 MPa for 10 min. In this work, the structural and mechanical properties of these materials were evaluated. Consolidated samples presented a major phase with a bcc-type structure with lattice parameter value of 0.316 nm for CrNbTaVW and CrNbTaVW1.7 compositions. Moreover, observation of the microstructures evidences also two minor phases: Ta-Nb-Cr and Ta-V rich (in which carbon is detected). Despite the similarity in the structural properties of these two alloys, their mechanical properties are distinct. The flexural stress for the sample with higher amount of W (CrNbTaVW1.7) is higher by 50% in the 298-873 K range, with an increased strain to fracture, which can be associated with reduced brittleness caused by the additional W incorporation.info:eu-repo/semantics/publishedVersio

LocalEnergy: Local Resources for Multifunctional Tetrahedrite-based Energy: Harvesting Applications

info:eu-repo/semantics/publishedVersio

Estudos sobre a nutrição mineral do cafeeiro: XL. Fitomassa e conteúdo de macro e micronutrientes no material podado

An experiment has carried out in commercial coffee plantation (varie ty Mundo Novo, 7 years old, 1904 "covas" per ha, previous yield 3,180 kg cleancoffe, Ipanema Agro Indústria S.A., Alfenas, MG, Brazil) designed to estimate the quantities of biomass, macro and micronutrients there in, removed by different types of pruning, namely: (1) stumping at 0,40 m above ground;(2) capping at 1,00 m; (3) capping at 1,50 m; (4) capping at 2,00 m; (5) capping at 1,50 m and cutting of laterals at 15 cm from the main stem. Analyses of data and material allowed for the following conclusions to be drawn. (1) Biomass removed by pruning was higher when pruning was done by stumping (24.3 tons of fresh weight and 11.9 tons dry weight) and by capping at 1,00 m above ground (20.6 and 10.1 tons, respectively); these treatments were followed by capping at 1,50 m plus cutting off laterals which yielded 19.4 and 8.3 tons of fresh and dry weight; the fresh and try weight corresponding to capping at 1,50 and 2,00 m above ground were: 12.1 and 5.4, 5.6 and 2.5 tons por hectare. (2) Simple regression equations describe with a high degree of significance the relationship between height of pruning and biomass removed there off. (3) The amount of macro and micronutrients, as expected, relate well with the quantity of plant material which corresponds to each treatment. Total amounts for macronutrients were, according to the order of the treatments given above (in kg/ha): N - 320; 294; 162; 80 and 261; P - 18; 15; 10; 44 and 16; K - 286; 266; 168; 78 and 273; Ca - 149; 139; 63; 33 and 101; Mg - 30; 33; 16; 8 and 26; S - 10; 7; 6; 3 and 10. In the same order, the amounts of micronutrients were, in g/ha: B - 306; 337; 163; 83 and 268; Cu - 229; 219; 121; 51 and 191; Fe - 2783; 2328; 1367; 544 and 2088; Mn - 437; 779; 264; 142 and 412; Zn - 174; 152; 74; 28 and 121. (4) Simple regression equations were derived which express the relationship between quantities of macro and micronutrients removed and the heighth of pruning. (5) Recycling of the biomass curt off fy pruning could contribute to savings in the rates of fertilizer to be applied in the period of regrowth. Most of the nutrients, however, from two thirds to three fourths of the total, are found in branches and stems which is likely to more slonly released.Foi conduzido um ensaio numa plantação comercial de café de variedade Mundo Novo de 9 anos de idade, com uma população de 1904 covas/ha, destinada a avaliar a quantidade de biomassa e de nutrientes removidas por diferentes tipos de poda: recepa a 0,40m; decote a 1,00, 1,50 e 2,00 m; decote a 1,50m com esqueletamento. A análise do material e dos dados permitiu tirar-se as seguintes conclusões: (1) a biomassa removida pela poda foi maior na recepa (24,3 t de matéria fresca e 11,9 de matéria seca) e no decote a 1,00 m (20,6 e 10,1 t, respectivamente); seguia-se o decote a 1,50 m com esqueletamento que deu 19,4 e 8,3 t de matéria fresca e seca por hectare; os pesos da matéria fresca e seca correspondentes aos decotes a 1,50 m e 2,00 m foram: 12,1 e 5,4; 5,6 e 2,5 t/ha; (2) a relação existente entre a altura de poda e quantidade de fitomassa removida é descrita por equações de regressão simples; (3) as quantidades de nutrientes removidas são proporcionais as quantidades de material podado sendo as seguintes de acordo com a ordem dos tratamentos dado, em kg/ha: N - 320, 294, 162, 80 e 261; P - 18, 15, 10, 44 e 16; K - 286, 266, 168, 78 e 273; Ca - 149, 139, 63, 33 e 101: Mg - 30, 33, 16, 8 e 26; S - 10, 7,6, 3 e 10; as quantidades de micronutrientes removidas foram, em g/ha: B - 306, 337, 163, 83 e 268; Cu - 229, 219, 121, 51 e 191; Fe - 2783, 2328, 1367, 544 e 2,088; Mn - 437, 779, 264, 142 e 412; Zn - 174, 152, 74, 28 e 121; (3) foram derivadas equações de regressão simples que relacionam quantidade extraídas e altura da poda; (4) a reciclagem de fitomassa contribui com economia substancial de fertilizantes para a nova vegetação. Cerca de dois terços e três quartos de nutrientes, entretanto, estão contidos no material lenhoso de caules e ramos o que deve fazer que a sua disponibilidade seja mais lenta

Adubos verdes e seus efeitos no rendimento da cana-de-açúcar em sistema de plantio direto.

O objetivo deste trabalho foi avaliar adubos verdes e seus efeitos no rendimento da cana-de-açúcar em sistema de plantio direto (SPD). O trabalho foi realizado em Campos dos Goytacazes (RJ), no período de dezembro de 2003 a julho de 2005. O delineamento experimental foi em blocos casualizados, com quatro repetições. Os tratamentos foram: feijão-de-porco (Canavalia ensiformis), mucuna-preta(Mucuna aterrimum), crotalária (Crotalária juncea) em plantio direto e vegetação espontânea em preparo convencional (testemunha). Com crotalária aos 35 dias após emergência (DAE) houve maior taxa de cobertura do solo – 87% – e, aos 92 DAE produziu 17.852 kg ha-1 de matéria seca, respectivamente, 41%, 78% e 407% superior ao feijão-de-porco, mucuna e vegetação espontânea, além de superá-las em acúmulos de K, Mg, S, Zn e Fe. O feijão-de-porco e a mucuna proporcionaram o maior teor de N na parte aérea. Com feijão-de-porco, os teores de P e Ca foram maiores que a crotalária e a mucuna. Com vegetação espontânea, o maior teor de K foi na parte aérea. As leguminosas acumularam maiores quantidades de N e Cu do que a vegetação espontânea. A crotalária e o feijão-de-porco acumularam 66% a mais de P na parte área que a mucuna. O SPD utilizando a adubação verde contribuiu significativamente para a maior produtividade de cana-de-açúcar, 135.863 kg ha-1, sendo 37% superior ao PC com a vegetação espontânea

Non-linear QCD dynamics and exclusive production in epep collisions

The exclusive processes in electron-proton ($ep$) interactions are an important tool to investigate the QCD dynamics at high energies as they are in general driven by the gluon content of proton which is strongly subject to parton saturation effects. In this paper we compute the cross sections for the exclusive vector meson production as well as the deeply virtual Compton scattering (DVCS) relying on the color dipole approach and considering the numerical solution of the Balitsky-Kovchegov equation including running coupling corrections. We show that the small-$x$ evolution given by this evolution equation is able to describe the DESY-HERA data and is relevant for the physics of the exclusive observables in future electron-proton colliders and in photoproduction processes to be measured in coherent interactions at the LHC.Comment: 6 pages, 4 figure