Low temperature shape relaxation of 2-d islands by edge diffusion

We present a precise microscopic description of the limiting step for low temperature shape relaxation of two dimensional islands in which activated diffusion of particles along the boundary is the only mechanism of transport allowed. In particular, we are able to explain why the system is driven irreversibly towards equilibrium. Based on this description, we present a scheme for calculating the duration of the limiting step at each stage of the relaxation process. Finally, we calculate numerically the total relaxation time as predicted by our results and compare it with simulations of the relaxation process.Comment: 11 pages, 5 figures, to appear in Phys. Rev.

Admixed pellets for fast and efficient delivery of plasma enhancement gases: Investigations at AUG exploring the option for EU-DEMO

Gas and pellet injection are envisaged for particle fuelling in EU-DEMO. The gas system will provide edge and divertor fuelling and any further gas species required for operation. Pellets, mm-sized bodies formed from solid hydrogen fuel, are designed for efficient and fast core fuelling. However, they can also be employed for a more efficient delivery of plasma enhancement gases, by admixing them with the fuelling pellets. To check this option for EU-DEMO, explorative investigations have been performed at ASDEX Upgrade (AUG). The AUG system produces ice in a batch process sufficient for about 100 pellets, initially designed for operation with pure H$_2$ or D$_2$. On a trial basis, pellet formation was tested using an H$_2$/D$_2$ mixture and admixtures containing small amounts (up to 2 mol%) of N$_2$, Ar, Kr or Xe in the D$_2$ host. A homogeneous and reproducible ice composition was found for the H$_2$/D$_2$ = 1:1 case. For all the admixed gases, a depletion of the admixture in the ice with increasing atomic number is observed. Nevertheless, the fast and efficient delivery of admixed pellets was clearly demonstrated in dedicated plasma experiments at AUG. Detailed investigations showed that the Ar supplied via admixed pellets has a higher radiation efficiency and a faster radiation rise than an Ar/D$_2$ gas puff. Furthermore, Ar density measurements in a discharge with admixed pellet injection show reasonable agreement with findings of a fading admixed species’ concentration along the ice rod and assumptions on the pellet ablation location in the plasma. Investigations performed at the Oak Ridge National Laboratory with a large batch extruder using up to 2 mol% Ne in D$_2$ confirmed that production of much larger ice quantities can be achieved. These initial explorative investigations clearly reveal the great potential of admixed pellets, although they also demonstrate that further technology efforts are required before their benefits can be utilized

Template-Assisted Synthesis and Characterization of Passivated Nickel Nanoparticles

Potential applications of nickel nanoparticles demand the synthesis of self-protected nickel nanoparticles by different synthesis techniques. A novel and simple technique for the synthesis of self-protected nickel nanoparticles is realized by the inter-matrix synthesis of nickel nanoparticles by cation exchange reduction in two types of resins. Two different polymer templates namely strongly acidic cation exchange resins and weakly acidic cation exchange resins provided with cation exchange sites which can anchor metal cations by the ion exchange process are used. The nickel ions which are held at the cation exchange sites by ion fixation can be subsequently reduced to metal nanoparticles by using sodium borohydride as the reducing agent. The composites are cycled repeating the loading reduction cycle involved in the synthesis procedure. X-Ray Diffraction, Scanning Electron Microscopy, Transmission Electron microscopy, Energy Dispersive Spectrum, and Inductively Coupled Plasma Analysis are effectively utilized to investigate the different structural characteristics of the nanocomposites. The hysteresis loop parameters namely saturation magnetization and coercivity are measured using Vibrating Sample Magnetometer. The thermomagnetization study is also conducted to evaluate the Curie temperature values of the composites. The effect of cycling on the structural and magnetic characteristics of the two composites are dealt in detail. A comparison between the different characteristics of the two nanocomposites is also provided

Hybrid nanoparticles based on sulfides, oxides, and carbides

The methods for synthesis of hybrid nanoparticles based on sulfides, oxides, and carbides of heavy and transition metals were considered. The problem of the influence of the method of synthesis of the hybrid nanoparticles on their atomic structure, morphology of the nanomaterials, and functional properties was analyzed. The areas of practical use of the hybrid nanoparticles were proposed. © 2013 Springer Science+Business Media New York

Synthesis of macrocyclic receptors with intrinsic fluorescence featuring quinizarin moieties

An unprecedented class of macrocycles with intrinsic fluorescence consisting of phenolic trimers and quinizarin is developed. Though they are lacking strong hydrogen bonds as observed in calixarenes, the two examples introduced here each adopt a vase-like conformation with all four aromatic units pointing in one direction (syn orientation). This “cone” conformation has been confirmed by NMR spectroscopy, molecular modeling, and X-ray crystallography. The laminar, electron-rich fluorophore as part of the macrocycle allows additional contacts to enclosed guest molecules

Aggregation and settling in aqueous polydisperse alumina nanoparticle suspensions

Nanoparticle suspensions (also called nanofluids) are often polydisperse and tend to settle with time. Settling kinetics in these systems are known to be complex and hence challenging to understand. In this work, polydisperse spherical alumina (Al2O3) nanoparticles in the size range of ~10-100nm were dispersed in water and examined for aggregation and settling behaviour near its isoelectric point (IEP). A series of settling experiments were conducted and the results were analysed by photography and by Small Angle X-ray Scattering (SAXS). The settling curve obtained from standard bed height measurement experiments indicated two different types of behaviour, both of which were also seen in the SAXS data. But the SAXS data were remarkably able to pick out the rapid settling regime as a result of the high temporal resolution (10s) used. By monitoring the SAXS intensity, it was further possible to record the particle aggregation process for the first time. Optical microscopy images were produced on drying and dried droplets extracted from the suspension at various times. Dried deposits showed the rapid decrease in the number of very large particles with time which qualitatively validates the SAXS prediction, and therefore its suitability as a tool to study unstable polydisperse colloids. Keywords: Nanoparticles, nanofluids, polydisperse, aggregation, settling, alumina, microscopy, SAX