493 research outputs found
Ab initio Quantum and ab initio Molecular Dynamics of the Dissociative Adsorption of Hydrogen on Pd(100)
The dissociative adsorption of hydrogen on Pd(100) has been studied by ab
initio quantum dynamics and ab initio molecular dynamics calculations. Treating
all hydrogen degrees of freedom as dynamical coordinates implies a high
dimensionality and requires statistical averages over thousands of
trajectories. An efficient and accurate treatment of such extensive statistics
is achieved in two steps: In a first step we evaluate the ab initio potential
energy surface (PES) and determine an analytical representation. Then, in an
independent second step dynamical calculations are performed on the analytical
representation of the PES. Thus the dissociation dynamics is investigated
without any crucial assumption except for the Born-Oppenheimer approximation
which is anyhow employed when density-functional theory calculations are
performed. The ab initio molecular dynamics is compared to detailed quantum
dynamical calculations on exactly the same ab initio PES. The occurence of
quantum oscillations in the sticking probability as a function of kinetic
energy is addressed. They turn out to be very sensitive to the symmetry of the
initial conditions. At low kinetic energies sticking is dominated by the
steering effect which is illustrated using classical trajectories. The steering
effects depends on the kinetic energy, but not on the mass of the molecules.
Zero-point effects lead to strong differences between quantum and classical
calculations of the sticking probability. The dependence of the sticking
probability on the angle of incidence is analysed; it is found to be in good
agreement with experimental data. The results show that the determination of
the potential energy surface combined with high-dimensional dynamical
calculations, in which all relevant degrees of freedon are taken into account,
leads to a detailed understanding of the dissociation dynamics of hydrogen at a
transition metal surface.Comment: 15 pages, 9 figures, subm. to Phys. Rev.
The Shapes of Dirichlet Defects
If the vacuum manifold of a field theory has the appropriate topological
structure, the theory admits topological structures analogous to the D-branes
of string theory, in which defects of one dimension terminate on other defects
of higher dimension. The shapes of such defects are analyzed numerically, with
special attention paid to the intersection regions. Walls (co-dimension 1
branes) terminating on other walls, global strings (co-dimension 2 branes) and
local strings (including gauge fields) terminating on walls are all considered.
Connections to supersymmetric field theories, string theory and condensed
matter systems are pointed out.Comment: 24 pages, RevTeX, 21 eps figure
Hadronic EDMs, the Weinberg Operator, and Light Gluinos
We re-examine questions concerning the contribution of the three-gluon
Weinberg operator to the electric dipole moment of the neutron, and provide
several QCD sum rule-based arguments that the result is smaller than - but
nevertheless consistent with - estimates which invoke naive dimensional
analysis. We also point out a regime of the MSSM parameter space with light
gluinos for which this operator provides the dominant contribution to the
neutron electric dipole moment due to enhancement via the dimension five color
electric dipole moment of the gluino.Comment: 6 pages, RevTeX, 3 figures; v2: references added; v3: typos
corrected, to appear in Phys. Rev.
Non-Equilibrium Statistical Physics of Currents in Queuing Networks
We consider a stable open queuing network as a steady non-equilibrium system
of interacting particles. The network is completely specified by its underlying
graphical structure, type of interaction at each node, and the Markovian
transition rates between nodes. For such systems, we ask the question ``What is
the most likely way for large currents to accumulate over time in a network
?'', where time is large compared to the system correlation time scale. We
identify two interesting regimes. In the first regime, in which the
accumulation of currents over time exceeds the expected value by a small to
moderate amount (moderate large deviation), we find that the large-deviation
distribution of currents is universal (independent of the interaction details),
and there is no long-time and averaged over time accumulation of particles
(condensation) at any nodes. In the second regime, in which the accumulation of
currents over time exceeds the expected value by a large amount (severe large
deviation), we find that the large-deviation current distribution is sensitive
to interaction details, and there is a long-time accumulation of particles
(condensation) at some nodes. The transition between the two regimes can be
described as a dynamical second order phase transition. We illustrate these
ideas using the simple, yet non-trivial, example of a single node with
feedback.Comment: 26 pages, 5 figure
Mass spectra of doubly heavy Omega_QQ' baryons
We evaluate the masses of baryons composed of two heavy quarks and a strange
quark with account for spin-dependent splittings in the framework of potential
model with the KKO potential motivated by QCD with a three-loop beta-function
for the effective charge consistent with both the perturbative limit at short
distances and linear confinement term at long distances between the quarks. The
factorization of dynamics is supposed and explored in the nonrelativistic
Schroedinger equation for the motion in the system of two heavy quarks
constituting the doubly heavy diquark and the strange quark interaction with
the diquark. The limits of approach, its justification and uncertainties are
discussed. Excited quasistable states are classified by the quantum numbers of
heavy diquark composed by the heavy quarks of the same flavor.Comment: 14 pages, revtex4-file, 3 eps-figures, 5 tables, typos correcte
Direct Measurements of the Branching Fractions for and and Determinations of the Form Factors and
The absolute branching fractions for the decays and
are determined using singly
tagged sample from the data collected around 3.773 GeV with the
BES-II detector at the BEPC. In the system recoiling against the singly tagged
meson, events for and events for decays are observed. Those yield
the absolute branching fractions to be and . The
vector form factors are determined to be
and . The ratio of the two form
factors is measured to be .Comment: 6 pages, 5 figure
Measurements of J/psi Decays into 2(pi+pi-)eta and 3(pi+pi-)eta
Based on a sample of 5.8X 10^7 J/psi events taken with the BESII detector,
the branching fractions of J/psi--> 2(pi+pi-)eta and J/psi-->3(pi+pi-)eta are
measured for the first time to be (2.26+-0.08+-0.27)X10^{-3} and
(7.24+-0.96+-1.11)X10^{-4}, respectively.Comment: 11 pages, 6 figure
BESII Detector Simulation
A Monte Carlo program based on Geant3 has been developed for BESII detector
simulation. The organization of the program is outlined, and the digitization
procedure for simulating the response of various sub-detectors is described.
Comparisons with data show that the performance of the program is generally
satisfactory.Comment: 17 pages, 14 figures, uses elsart.cls, to be submitted to NIM
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