361 research outputs found
Magnetism and d-wave superconductivity on the half-filled square lattice with frustration
The role of frustration and interaction strength on the half-filled Hubbard
model is studied on the square lattice with nearest and next-nearest neighbour
hoppings t and t' using the Variational Cluster Approximation (VCA). At
half-filling, we find two phases with long-range antiferromagnetic (AF) order:
the usual Neel phase, stable at small frustration t'/t, and the so-called
collinear (or super-antiferromagnet) phase with ordering wave-vector
or , stable for large frustration. These are separated by a phase with
no detectable long-range magnetic order. We also find the d-wave
superconducting (SC) phase (), which is favoured by frustration if
it is not too large. Intriguingly, there is a broad region of coexistence where
both AF and SC order parameters have non-zero values. In addition, the physics
of the metal-insulator transition in the normal state is analyzed. The results
obtained with the help of the VCA method are compared with the large-U
expansion of the Hubbard model and known results for the frustrated J1-J2
Heisenberg model. These results are relevant for pressure studies of undoped
parents of the high-temperature superconductors: we predict that an insulator
to d-wave SC transition may appear under pressure.Comment: 12 pages, 10 figure
Efficient oxidative dearomatisations of substituted phenols using hypervalent iodine (iii) reagents and antiprotozoal evaluation of the resulting cyclohexadienones against T. b. rhodesiense and P. falciparum Strain NF54
Quinones and quinols are secondary metabolites of higher plants that are associated with many biological activities. The oxidative dearomatization of phenols induced by hypervalent iodine(III) reagents has proven to be a very useful synthetic approach for the preparation of these compounds, which are also widely used in organic synthesis and medicinal chemistry. Starting from several substituted phenols and naphthols, a series of cyclohexadienone and naphthoquinone derivatives were synthesized using different hypervalent iodine(III) reagents and evaluated for their in vitro antiprotozoal activity. Antiprotozoal activity was assessed against Plasmodium falciparum NF54 and Trypanosoma brucei rhodesiense STIB900. Cytotoxicity of all compounds towards L6 cells was evaluated and the respective selectivity indices (SI) were calculated. We found that benzyl naphthoquinone 5c was the most active and selective molecule against T. brucei rhodesiense (IC50 = 0.08 muM, SI = 275). Furthermore, the antiprotozoal assays revealed no specific effects. In addition, some key physicochemical parameters of the synthesised compounds were calculated
Signal-to-noise measurements utilizing a novel dual-energy multimedia detector
Dual-energy measurements are presented utilizing a novel slot-scan digital radiographic imaging detector, operating on gaseous solid state ionization principles. The novel multimedia detector has two basic functional components: a noble gas-filled detector volume operating on gas microstrip principles, and a solid state detector volume. The purpose of this study is to investigate the potential use of this multimedia detector for enhanced dual-energy imaging. The experimental results indicate that the multimedia detector exhibits a large subtracted signal-to-noise ratio. Although the intrinsic merit of this device is being explored for medical imaging, potential applications of the multimedia detector technology in other industrial areas, such as aerospace imaging, aviation security, and surveillance, are also very promising
Heart Rate during Conflicts Predicts Post-Conflict Stress-Related Behavior in Greylag Geese
Background: Social stressors are known to be among the most potent stressors in group-living animals. This is not only manifested in individual physiology (heart rate, glucocorticoids), but also in how individuals behave directly after a conflict. Certain ‘stress-related behaviors ’ such as autopreening, body shaking, scratching and vigilance have been suggested to indicate an individual’s emotional state. Such behaviors may also alleviate stress, but the behavioral context and physiological basis of those behaviors is still poorly understood. Methodology/Principal Findings: We recorded beat-to-beat heart rates (HR) of 22 greylag geese in response to agonistic encounters using fully implanted sensor-transmitter packages. Additionally, for 143 major events we analyzed the behavior shown by our focal animals in the first two minutes after an interaction. Our results show that the HR during encounters and characteristics of the interaction predicted the frequency and duration of behaviors shown after a conflict. Conclusions/Significance: To our knowledge this is the first study to quantify the physiological and behavioral responses to single agonistic encounters and to link this to post conflict behavior. Our results demonstrate that ‘stress-related behaviors’ are flexibly modulated by the characteristics of the preceding aggressive interaction and reflect the individual’s emotional strain, which is linked to autonomic arousal. We found no support for the stress-alleviating hypothesis, but we propose tha
Juvenile Greylag Geese (Anser anser) Discriminate between Individual Siblings
Social species that maintain individualised relationships with certain others despite continuous changes in age, reproductive status and dominance rank between group members ought to be capable of individual recognition. Tests of “true” individual recognition, where an individual recognises unique features of another, are rare, however. Often kinship and/or familiarity suffice to explain dyadic interactions. The complex relationships within a greylag goose flock suggest that they should be able to recognise individuals irrespective of familiarity or kinship. We tested whether six-week-old hand-raised greylags can discriminate between two of their siblings. We developed a new experimental protocol, in which geese were trained to associate social siblings with geometrical symbols. Subsequently, focals were presented with two geometrical symbols in the presence of a sibling associated with one of the symbols. Significant choice of the geometrical symbol associated with the target present indicated that focals were able to distinguish between individual targets. Greylag goslings successfully learned this association-discrimination task, regardless of genetic relatedness or sex of the sibling targets. Social relationships within a goose flock thus may indeed be based on recognition of unique features of individual conspecifics
Pressure Dependence of Born Effective Charges, Dielectric Constant and Lattice Dynamics in SiC
The pressure dependence of the Born effective charge, dielectric constant and
zone-center LO and TO phonons have been determined for -SiC by a linear
response method based on the linearized augmented plane wave calculations
within the local density approximation. The Born effective charges are found to
increase nearly linearly with decreasing volume down to the smallest volume
studied, , corresponding to a pressure of about 0.8 Mbar. This
seems to be in contradiction with the conclusion of the turnover behavior
recently reported by Liu and Vohra [Phys.\ Rev.\ Lett.\ {\bf 72}, 4105 (1994)]
for -SiC. Reanalyzing their procedure to extract the pressure dependence of
the Born effective charges, we suggest that the turnover behavior they obtained
is due to approximations in the assumed pressure dependence of the dielectric
constant , the use of a singular set of experimental data
for the equation of state, and the uncertainty in measured phonon frequencies,
especially at high pressure.Comment: 25 pages, revtex, 5 postscript figures appended, to be published in
Phys. Rev.
Glacier thinning, recession and advance, and the associated evolution of a glacial lake between 1966 and 2021 at Austerdalsbreen, western Norway
The Jostedalsbreen is the largest ice cap in Norway and mainland Europe. Rapid retreat of many of its outlet glaciers since the 2000s has led to the formation of several glacial lakes. Processes causing the formation and expansion of glacial lakes and their interaction with a glacier and terminal moraine have not been widely addressed yet. In this study, we investigate the degradation of the front of the southeast-facing outlet glacier Austerdalsbreen. Based on a variety of remotely sensed data (UAV-based and airborne orthophotos and DEMs, satellite images), we analyze the coincident glacial and proglacial changes of Austerdalsbreen and quantify the evolution of this transition zone during the last decades. In particular, we focus on the short-term evolution of the glacial lake since 2010, we examine the context of a glacier advance in the 1990s, and we report long-term changes by utilizing 1960s imagery. We discuss the evolution and conditions of Austerdalsbreen compared to other outlet glaciers of Jostedalsbreen. Overall, the glacier terminus has experienced a recession in the last decades. The 1990s terminus advance was more restricted than at other nearby outlet glaciers due to glacier surface debris cover, which is a critical factor for the glacier and lake evolution. However, in the most recent period, since 2012, a distinct expansion of a glacial lake is quantifiable. Since the rates of glacier surface lowering also considerably increased since approximately 2017 and the glacier retreated since the beginning of the 2000s with a clear maximum length decrease in 2015, we interpret the recently formed glacial lake as a contributory factor of glacial changes
Low-regret climate change adaptation in coastal megacities – evaluating large-scale flood protection and small-scale rainwater detention measures for Ho Chi Minh City, Vietnam
Urban flooding is a major challenge for many megacities
in low-elevation coastal zones (LECZs), especially in Southeast Asia. In
these regions, the effects of environmental stressors overlap with rapid
urbanization, which significantly aggravates the hazard potential. Ho Chi
Minh City (HCMC) in southern Vietnam is a prime example of this set of
problems and therefore a suitable case study to apply the concept of
low-regret disaster risk adaptation as defined by the Intergovernmental
Panel on Climate Change (IPCC). In order to explore and evaluate potential
options of hazard mitigation, a hydro-numerical model was employed to
scrutinize the effectiveness of two adaptation strategies: (1) a classic
flood protection scheme including a large-scale ring dike as currently
constructed in HCMC and (2) the widespread installation of small-scale
rainwater detention as envisioned in the framework of the Chinese Sponge
City Program (SCP). A third adaptation scenario (3) assesses the combination of both approaches (1) and (2).
From a hydrological point of view, the reduction in various flood intensity
proxies that were computed within this study suggests that large-scale flood protection is comparable but slightly more effective than small-scale
rainwater storage: for instance, the two adaptation options could reduce the normalized flood severity index (INFS), which is a measure combining flood depth and duration, by 17.9 % and 17.7 %, respectively. The
number of flood-prone manufacturing firms that would be protected after
adaptation, in turn, is nearly 2 times higher for the ring dike than for
the Sponge City approach. However, the numerical results also reveal that
both response options can be implemented in parallel, not only without
reducing their individual effectiveness but also complementarily with
considerable added value. Additionally, from a governance perspective,
decentralized rainwater storage conforms ideally to the low-regret paradigm:
while the existing large-scale ring dike depends on a binary commitment (to
build or not to build), decentralized small- and micro-scale solutions can
be implemented gradually (for example through targeted subsidies) and add
technical redundancy to the overall system. In the end, both strategies are
highly complementary in their spatial and temporal reduction in flood
intensity. Local decision-makers may hence specifically seek combined
strategies, adding to singular approaches, and design multi-faceted
adaptation pathways in order to successfully prepare for a deeply uncertain
future.</p
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