Ce(IV) Oxidation of Cyclopentanone, Cyclohexanone, Cycloheptanone, Cyc1ooctanone, Acetone, Butanone, Acetoacetic Ester & Benzoylacetone

579-58

Kinetics of Reaction of Methylene Iodide with Alkoxide Ion in Binary Solvent Mixtures

136-14

Pre-processing Algorithm for Rectification of Geometric Distortions in Satellite Images

A number of algorithms have been reported to process and remove geometric distortions in satellite images. Ortho-correction, geometric error correction, radiometric error removal, etc are a few important examples. These algorithm require supplementary meta-information of the satellite images such as ground control points and correspondence, sensor orientation details, elevation profile of the terrain, etc to establish corresponding transformations. In this paper, a pre-processing algorithm has been proposed which removes systematic distortions of a satellite image and thereby removes the blank portion of the image. It is an input-to-output mapping of image pixels, where the transformation computes the coordinate of each output pixel corresponding to the input pixel of an image. The transformation is established by the exact amount of scaling, rotation and translation needed for each pixel in the input image so that the distortion induced during the recording stage is corrected.Defence Science Journal, 2011, 61(2), pp.174-179, DOI:http://dx.doi.org/10.14429/dsj.61.42

Bound State Wave Functions through the Quantum Hamilton - Jacobi Formalism

The bound state wave functions for a wide class of exactly solvable potentials are found utilizing the quantum Hamilton-Jacobi formalism. It is shown that, exploiting the singularity structure of the quantum momentum function, until now used only for obtaining the bound state energies, one can straightforwardly find both the eigenvalues and the corresponding eigenfunctions. After demonstrating the working of this approach through a number of solvable examples, we consider Hamiltonians, which exhibit broken and unbroken phases of supersymmetry. The natural emergence of the eigenspectra and the wave functions, in both the unbroken and the algebraically non-trivial broken phase, demonstrates the utility of this formalism.Comment: replaced with the journal versio

Optical absorption and photoluminescence spectroscopy of the growth of silver nanoparticles

Results obtained from the optical absorption and photoluminescence (PL) spectroscopy experiments have shown the formation of excitons in the silver-exchanged glass samples. These findings are reported here for the first time. Further, we investigate the dramatic changes in the photoemission properties of the silver-exchanged glass samples as a function of postannealing temperature. Observed changes are thought to be due to the structural rearrangements of silver and oxygen bonding during the heat treatments of the glass matrix. In fact, photoelectron spectroscopy does reveal these chemical transformations of silver-exchanged soda glass samples caused by the thermal effects of annealing in a high vacuum atmosphere. An important correlation between temperature-induced changes of the PL intensity and thermal growth of the silver nanoparticles has been established in this Letter through precise spectroscopic studies.Comment: 15 pages,4 figures,PDF fil

Sinusoidal Excitations in Two Component Bose-Einstein Condensates

The non-linear coupled Gross-Pitaevskii equation governing the dynamics of the two component Bose-Einstein condensate (TBEC) is shown to admit pure sinusoidal, propagating wave solutions in quasi one dimensional geometry. These solutions, which exist for a wide parameter range, are then investigated in the presence of a harmonic oscillator trap with time dependent scattering length. This illustrates the procedure for coherent control of these modes through temporal modulation of the parameters, like scattering length and oscillator frequency. We subsequently analyzed this system in an optical lattice, where the occurrence of an irreversible phase transition from superfluid to insulator phase is seen.Comment: 6 pages, 1 figur

Canonical steering ellipsoids of pure symmetric multiqubit states with two distinct spinors and volume monogamy of steering

Quantum steering ellipsoid formalism provides a faithful representation of all two-qubit states and helps in obtaining correlation properties of the state through the steering ellipsoid. The steering ellipsoids corresponding to the two-qubit subsystems of permutation symmetric $N$-qubit states is analysed here. The steering ellipsoids of two-qubit states that have undergone local operations on both the qubits so as to bring the state to its canonical form are the so-called canonical steering ellipsoids. We construct and analyze the geometric features of the canonical steering ellipsoids corresponding to pure permutation symmetric $N$-qubit states with two distinct spinors. Depending on the degeneracy of the two spinors in the pure symmetric $N$-qubit state, there arise several families which cannot be converted into one another through Stochastic Local Operations and Classical Communications (SLOCC). The canonical steering ellipsoids of the two-qubit states drawn from the pure symmetric $N$-qubit states with two distinct spinors allow for a geometric visualization of the SLOCC-inequivalent class of states. We show that the states belonging to the W-class correspond to oblate spheroid centered at $(0,0,1/(N-1))$ with fixed semiaxes lengths $1/\sqrt{N-1}$ and $1/(N-1)$. The states belonging to all other SLOCC inequivalent families correspond to ellipsoids centered at the origin of the Bloch sphere. We also explore volume monogamy relations of states belonging to these families, mainly the W-class of states.Comment: 13 pages, 13 figures; Revised version; Comments welcom

Arabidopsis DOF Transcription Factors Act Redundantly to Reduce CONSTANS Expression and Are Essential for a Photoperiodic Flowering Response

SummaryFlowering of Arabidopsis is induced by long summer days (LDs). The transcriptional regulator CONSTANS (CO) promotes flowering, and its transcription is increased under LDs. We systematically misexpressed transcription factors in companion cells and identified several DOF proteins that delay flowering by repressing CO transcription. Combining mutations in four of these, including CYCLING DOF FACTOR 2 (CDF2), caused photoperiod-insensitive early flowering by increasing CO mRNA levels. CO transcription is promoted to differing extents by GIGANTEA (GI) and the F-box protein FKF1. We show that GI stabilizes FKF1, thereby reducing CDF2 abundance and allowing transcription of CO. Despite the crucial function of GI in wild-type plants, introducing mutations in the four DOF-encoding genes into gi mutants restored the diurnal rhythm and light inducibility of CO. Thus, antagonism between GI and DOF transcription factors contributes to photoperiodic flowering by modulating an underlying diurnal rhythm in CO transcript levels