The P21/m - C2/m phase transition in synthetic amphiboles in the system

The P21/m ↔ C2/m phase-transition has been studied by high-T FTIR analysis on a series of synthetic amphiboles in the Li2O–Na2O–MgO–SiO2–H2O (LNMSH) system. Spectra were collected in the T range 25–450 ◦C on KBr disks. All examined amphiboles have P21/m symmetry at room T. Their OH-stretching FTIR spectrum consists of two main bands at ∼ 3740 and 3715 cm−1. At the transition temperature (Tc), these bands merge into one single absorption centred at ∼ 3720 cm−1, and no further change is observed beyond this T. Significant modifications consisting in peak shifting and band broadening are also observed in the MIR (medium infrared) 1300–640 cm−1 region. Tc values for the different compositions were estimated based on various methods; the most reliable procedure is considered to be the fit of Landau 2-4-6 potentials using band shifts observed in the MIR region. The Tc values obtained for all samples are consistent with previous results obtained on two members of the series examined here by single-crystal or synchrotron powder HT-XRD (high-T X-ray diffraction). They correlate linearly with the aggregate cation radius at M(6) [Tc (◦C) = 803–533 rM(6) ; R2 = 0.97]. This work thus provide a measure of the role played by the size of the M(6) polyhedron in determining the Tc in simple chemical systems where the B-site occupancy (and geometry) is the only variable. The slope of the equation is far less steep in the LNMSH system than in cummingtonite; crystal-chemical reasons for this behaviour are discussed, and the local order between A and monovalent B cations is suggested to be the major constraint. In more complex systems, inspection of the available data shows that other factors such as the aggregate size of the strip of octahedra must be taken into account

Enabling solid biomass fired small scale cogeneration systems with the twin screw wet steam expander technology

Distributed power generation in industrial, urban and commercial applications is a key topic for the strategic development and implementation of modern energy policies. Solid biomass fired small scale cogeneration plants can play an important role in Europe to improve environmental and economic impact of such policies. As a result of advances in the design and development of twin-screw wet steam expanders, they now appear as an efficient enabling technology for this small scale de-centralized cogeneration plants. Same as backpressure turbines, twinscrew steam expander can generate power by reducing the pressure between the steam source and the downstream steam/heat user, but with the advantage of adopting wet steam as working fluid. The paper will describe the principles of steam screw expander operation and performance characterization and discuss installations of the expander genset in various industrial and urban (district heating) applications where steam is generated with solid biomass fired saturated steam boilers

Physico-Mechanical Performances of Mortars Prepared with Sorted Earthquake Rubble: The Role of CDW Type and Contained Crystalline Phases

Construction and demolition waste (CDW) from earthquake rubbles was used here as recycled aggregates (RA) in cementitious binders. The materials were sorted in six groups: concrete (CO), natural stone (NS), tile (TI), brick (BR), perforated brick (PF) and roof tile (RT). The abundance (wt.%) of crystalline phases in each RA type was determined by X-ray Powder Diffraction (XRPD). Each group of RAs was used alone (100 wt.% of RA) and mixed with quartz-rich virgin aggregates (VA) to prepare 13 types of mortars (12 specimens per type): one reference mortar (RM) with only VA, six recycled aggregate mortars (RAM) and six recycled-plus-virgin aggregate mortars (RVAM). The physical and mechanical properties of aggregates and mortars reflect the type and abundance of crystalline phases in each CDW group. Recycled mortars rich in concrete, natural stones and tiles have better mechanical performance than mortars prepared with recycled bricks, perforated bricks and roof tiles. For each RA, RVAMs have superior mechanical characteristics than the corresponding RAM. Since the type and amount of phases contained in recycled aggregates strongly control the mechanical performance of new construction materials, they should be routinely quantified as reported here, in addition to other physical features (water absorption, density, etc.). The separation of heterogeneous CDW into homogeneous RA groups is necessary for the production of new construction materials with stable and predictable performances to ensure CDW recycling, especially in areas hit by major adverse events, where large amounts of still valuable materials could be used for reconstruction processes

Maxillary sinus augmentation with three different biomaterials: Histological, histomorphometric, clinical, and patient-reported outcomes from a randomized controlled trial

Background: Lateral maxillary sinus augmentation (MSA) is a predictable bone regeneration technique in case of atrophy of the posterior-upper maxilla. Aimed at obtaining quantity and quality of bone suitable for receiving osseointegrated implants, its success is largely due to the skill of the surgeon, but also to the characteristics of the biomaterial used. Methods: Twenty-four patients needing MSA were included in the study. The patients were randomly allocated to three different groups: anorganic bovine bone mineral as control, tricalcium phosphate with or without hyaluronic acid (HA) as test groups. Nine months after MSA, bone biopsies were harvested for the histomorphometric analysis. Secondary outcomes were mean bone gain, intraoperative and postoperative complications, implant insertion torque, implant failure, and patient-reported outcome measures. Results: Although the percentage of new bone was not statistically different between the three groups (P =.191), the percentages of residual biomaterial was significantly higher (P <.000) and nonmineralized tissue significantly lower (P <.000) in the control than in the test groups. Test groups did not differ significantly from each other for all histomorphometric parameters. The implant insertion torque was significantly higher in the control group (P <.0005). The rest of the secondary outcomes were not significantly different between the groups. Conclusion: MSA is a safe and predictable procedure in terms of histological, clinical, and PROAMs, regardless of the biomaterial used. The addition of HA did not influence the outcomes

Coulomb stress transfer and fault interaction over millennia on non-planar active normal faults: TheMw 6.5-5.0 seismic sequence of 2016-2017, central Italy

In order to investigate the importance of including strike-variable geometry and the knowledge of historical and palaeoseismic earthquakes when modelling static Coulomb stress transfer and rupture propagation, we have examined the August-October 2016 A.D. and January 2017 A.D. central Apennines seismic sequence (Mw 6.0, 5.9, 6.5 in 2016 A.D. (INGV) and Mw 5.1, 5.5, 5.4, 5.0 in 2017 A.D. (INGV)).We model both the coseismic loading (from historical and palaeoseismic earthquakes) and interseismic loading (derived from Holocene fault slip-rates) using strike-variable fault geometries constrained by fieldwork. The inclusion of the elapsed times from available historical and palaeoseismological earthquakes and on faults enables us to calculate the stress on the faults prior to the beginning of the seismic sequence. We take account the 1316-4155 yr elapsed time on the Mt. Vettore fault (that ruptured during the 2016 A.D. seismic sequence) implied by palaeoseismology, and the 377 and 313 yr elapsed times on the neighbouring Laga and Norcia faults respectively, indicated by the historical record. The stress changes through time are summed to show the state of stress on the Mt. Vettore, Laga and surrounding faults prior to and during the 2016-2017 A.D. sequence. We show that the build up of stress prior to 2016 A.D. on strike-variable fault geometries generated stress heterogeneities that correlate with the limits of the main-shock ruptures. Hence, we suggest that stress barriers appear to have control on the propagation and therefore the magnitudes of the main-shock ruptures

Split crest technique for implant treatment of agenesis of the upper lateral incisors: results of a randomized pilot histological and clinical study at 24-month follow-up

Agenesis of lateral incisors, besides the functional issues, represents a great esthetic drawback. The selection of an appropriate treatment is a complex decision, which should consider the stability of the clinical outcomes over time. The aim of the present study was a histological and clinical comparison of two-stage split crest technique (SCT), with bone chips alone or mixed with porcine bone in patients affected by unilateral and bilateral agenesis of the upper lateral incisors. Eleven patients were enrolled, and randomly assigned to receive a treatment with autologous bone chips (group 1) or autologous bone chips mixed 1:1 to porcine-derived xenogenic bone (group 2). After a 2-month healing period, implants were placed and biopsies harvested for histomorphometrical evaluation. Clinical assessment, according to ICOI PISA health scale, and radiographic marginal bone loss evaluation at 12- and 24-month follow-ups were conducted. The histomorphometry showed significantly greater new bone formation (p > 0.0229) in group 2. At 12- and 24-month follow-ups, all the evaluated implants, regardless of the group they were allocated, could be categorized as "success" in the ICOI Pisa Health Scale for Dental Implants, and did not show significant difference in crestal bone loss. To the best of our knowledge, these are the first histological and clinical outcomes indicating that the use of bone chips mixed 1:1 to porcine bone in SCT could be a promising technique for the rehabilitation of patients with agenesis of the upper lateral incisors, although studies with a larger number of patients and implants, and a longer follow up are needed

EPMA maps unveil the actual chemical variations and crystallisation sequence of pyroxene and plagioclase solidified from a basaltic liquid at variable cooling rates

Crystal-chemical variations of pyroxene (px) and plagioclase (plg) have been analysed by X-ray electron-microprobe (EPMA) mapping to quantify their actual chemical dispersions. These phases were experimentally crystallised from a basaltic liquid (B100, MORB from Iceland) at cooling rates of 1, 7, 60 and 180 °C/h from 1300 °C down to 800 °C. Experiments were run at ambient conditions applying defined temperature paths mirroring characteristic cooling rates from innermost to outermost portions of metre- to centimetre-thick lavas, dikes and bombs emplaced under submarine to subaerial conditions. As the cooling rate increases from 1 to 180 °C/h, the run-products become progressively enriched in pyroxene and depleted in plagioclase, while spinel is invariably low (few area%) and glass is significant only at 180 °C/h. An increase of cooling rate generally leads to enrichment of Al2O3 and depletion of MgO in px, while the opposite behaviour is observed for plg; these trends are mirrored by calculated cations (apfu: atom per formula unit) and components. Average variations as a function of cooling rate are similar to those already observed through classical analysis performed by single point EPMA. However, the actual chemical distributions of CaO versus MgO, Al2O3 and FeOtot oxides unveil the presence of a wider range in pyroxene chemistry. In particular, one px (px-1, CaO-rich, diopsidic type) is present at all the applied cooling rates; a very low CaO-px (px-2, pigeonite or orthopyroxene type) is detected at 1 °C/h; and, finally, once more population of px (px-3, CaO-poor diopsidic type) appears at 60 and 180 °C/h. By contrast, plg analyses yield invariably identical compositions. Textural variations as a function of cooling rate and geothermometric estimations indicate that px-1 crystallised at high-T (or low ΔT), while plg mainly grew in the residual melt produced by the saturation of px. If only textures were evaluated, this order of segregation would like remain unrecognised since px at low cooling rates is smaller than plg. The abundance of phases, their crystal-chemical features, and their order of segregation can be regarded through a theoretical framework of a time-temperature-transformation (TTT) diagram. The most significant chemical variations are displayed by MgO and Al2O3 for both px and plg, which faithfully capture the evolution of cooling conditions. The chemical compositions of px-1 is close to the thermodynamic equilibrium only at 1 °C/h. As the cooling rates increase, the px chemistry indicates disequilibrium conditions. Finally, this study shows that as ΔT/Δt increases, the most abundant px (px-1) and plg are forced towards compositions that become progressively closer to those of the parental liquid

Coseismic Throw Variation Across Along-Strike Bends on Active Normal Faults: Implications for Displacement Versus Length Scaling of Earthquake Ruptures

Fault bends, and associated changes in fault dip, play a key role in explaining the scatter in maximum offset versus surface rupture length fault scaling relationships. Detailed field measurements of the fault geometry and magnitude of slip in the 2016–2017 Central Italy earthquake sequence, alongside three examples from large historical normal-faulting earthquakes in different tectonic settings, provide multiple examples in which coseismic throw increases across bends in fault strike where dip also increases beyond what is necessary to accommodate a uniform slip vector. Coseismic surface ruptures produced by two mainshocks of the 2016–2017 Central Italy earthquake sequence (24 August 2016 Mw 6.0 and 30 October 2016 Mw 6.5) cross a ~0.83-km amplitude along-strike bend, and the coseismic throws for both earthquakes increase by a factor of 2–3, where the strike of the fault changes by ~28o and the dip increases by 20–25o. We present similar examples from historical normal faulting earthquakes (1887, Sonora earthquake, Mw 7.5; 1981, Corinth earthquakes, Mw 6.7–6.4; and 1983, Borah Peak earthquake, Mw 7.3). We demonstrate that it is possible to estimate the expected change in throw across a bend by applying equations that relate strike, dip, and slip vector to horizontal strain conservation along a nonplanar fault for a single earthquake rupture. The calculated slip enhancement in bends can explain much of the scatter in maximum displacement (Dmax) versus surface rupture length scaling relationships. If fault bends are unrecognized, they can introduce variation in Dmax that may lead to erroneous inferences of stress drop variability for earthquakes, and exaggerate maximum earthquake magnitudes derived from vertical offsets in paleoseismic data sets