Absolute calibration and beam reconstruction of MITO (a ground-based instrument in the millimetric region)

An efficient sky data reconstruction derives from a precise characterization of the observing instrument. Here we describe the reconstruction of performances of a single-pixel 4-band photometer installed at MITO (Millimeter and Infrared Testagrigia Observatory) focal plane. The strategy of differential sky observations at millimeter wavelengths, by scanning the field of view at constant elevation wobbling the subreflector, induces a good knowledge of beam profile and beam-throw amplitude, allowing efficient data recovery. The problems that arise estimating the detectors throughput by drift scanning on planets are shown. Atmospheric transmission, monitored by skydip technique, is considered for deriving final responsivities for the 4 channels using planets as primary calibrators.Comment: 14 pages, 6 fiugres, accepted for pubblication by New Astronomy (25 March

Rotation in galaxy clusters from MUSIC simulations with the kinetic Sunyaev-Zel'dovich effect

We propose in this work its application for the detection of possible coherent rotational motions in the hot intra-cluster medium. We select a sample of massive, relaxed and rotating galaxy clusters from Marenostrum-mUltidark SImulations of galaxy Clusters (MUSIC), and we produce mock maps of the temperature distortion produced by the kinetic Sunyaev-Zel'dovich effect by exploring six different lines of sight, in the best observational condition. These maps are compared with the expected signal computed from a suitable theoretical model in two cases: (i) focusing only on the contribution from the rotation, and (ii) accounting also for the cluster bulk motion. We find that the parameters of the model assumed for the radial profile of the rotational velocity, averaged over the considered lines of sight, are in agreement within two standard deviations at most with independent estimates from the simulation data, without being significantly affected by the presence of the cluster bulk term. The amplitude of the rotational signal is, on average, of the order of 23 per cent of the total signal accounting also for the cluster bulk motion, and its values are consistent with the literature. The projected bulk velocity of the cluster is also recovered at the different lines of sight, with values in agreement with the simulation dataASB acknowledges funding from Sapienza Università di Roma - Progetti per Avvio alla Ricerca Anno 2017, prot. AR11715C82402BC

Constraining the evolution of the CMB temperature with SZ measurements from Planck data

The CMB temperature-redshift relation, T_CMB(z)=T_0(1+z), is a key prediction of the standard cosmology, but is violated in many non standard models. Constraining possible deviations to this law is an effective way to test the LambdaCDM paradigm and to search for hints of new physics. We have determined T_CMB(z), with a precision up to 3%, for a subsample (104 clusters) of the Planck SZ cluster catalog, at redshift in the range 0.01-- 0.94, using measurements of the spectrum of the Sunyaev Zel'dovich effect obtained from Planck temperature maps at frequencies from 70 to 353 GHz. The method adopted to provide individual determinations of T_CMB(z) at cluster redshift relies on the use of SZ intensity change, Delta I_SZ(nu), at different frequencies, and on a Monte-Carlo Markov Chain approach. By applying this method to the sample of 104 clusters, we limit possible deviations of the form T_CMB(z)=T_0(1+z)^(1-beta) to be beta= 0.022 +/- 0.018, at 1 sigma uncertainty, consistent with the prediction of the standard model. Combining these measurements with previously published results we get beta=0.016+/-0.012.Comment: submitted to JCAP, 21 pages, 8 figure

MITO measurements of the Sunyaev-Zeldovich Effect in the Coma cluster of galaxies

We have measured the Sunyaev-Zeldovich effect towards the Coma cluster (A1656) with the MITO experiment, a 2.6-m telescope equipped with a 4-channel 17 arcminute (FWHM) photometer. Measurements at frequency bands 143+/-15, 214+/-15, 272+/-16 and 353+/-13 GHz, were made during 120 drift scans of Coma. We describe the observations and data analysis that involved extraction of the S-Z signal by employing a spatial and spectral de-correlation scheme to remove a dominant atmospheric component. The deduced values of the thermal S-Z effect in the first three bands are DT_{0} = -179+/-38,-33+/-81,170+/-35 microKelvin in the cluster center. The corresponding optical depth, tau=(4.1+/-0.9) 10^{-3}, is consistent (within errors) with both the value from a previous low frequency S-Z measurement, and the value predicted from the X-ray deduced gas parameters.Comment: Ap.J.Letters accepted, 4 pages, 2 figure

Limitations to the Accuracy of Cosmic Background Radiation Anisotropy Measurements: Atmospheric Fluctuations

We discuss the ultimate limits posed by atmospheric fluctuations to observations of cosmic background anisotropies (CBAs) in ground-based and balloon-borne experiments both in the radio and millimetric regions. We present correlation techniques useful in separating CBAs from atmospheric fluctuations. An experimental procedure is discussed for testing a site in view of possible CBA observations. Four sites with altitudes ranging from 0 up to 3.5 km have been tested

MAD-4-MITO, a Multi Array of Detectors for ground-based mm/submm SZ observations

The last few years have seen a large development of mm technology and ultra-sensitive detectors devoted to microwave astronomy and astrophysics. The possibility to deal with large numbers of these detectors assembled into multi--pixel imaging systems has greatly improved the performance of microwave observations, even from ground--based stations, especially combining the power of multi--band detectors with their new imaging capabilities. Hereafter, we will present the development of a multi--pixel solution devoted to Sunyaev--Zel'dovich observations from ground--based telescopes, that is going to be operated from the Millimetre and Infrared Testagrigia Observatory.Comment: 5 pages, 3 figures, to be published in th eProceedings of the 2K1BC Workshop, July 9-13, 2001 - Breuil-Cervini

Rotation in galaxy clusters from MUSIC simulations with the kinetic Sunyaev-Zel'dovich effect

The Sunyaev-Zel'dovich effect in galaxy clusters is a unique probe for studying astrophysics and cosmology. We propose in this work its application for the detection of possible coherent rotational motions in the hot intra-cluster medium. We select a sample of massive, relaxed and rotating galaxy clusters from Marenostrum-mUltidark SImulations of galaxy Clusters (MUSIC), and we produce mock maps of the temperature distortion produced by the kinetic Sunyaev-Zel'dovich effect by exploring six different lines of sight, in the best observational condition. These maps are compared with the expected signal computed from a suitable theoretical model in two cases: (i) focusing only on the contribution from the rotation, and (ii) accounting also for the cluster bulk motion. We find that the parameters of the model assumed for the radial profile of the rotational velocity, averaged over the considered lines of sight, are in agreement within two standard deviations at most with independent estimates from the simulation data, without being significantly affected by the presence of the cluster bulk term. The amplitude of the rotational signal is, on average, of the order of 23 per cent of the total signal accounting also for the cluster bulk motion, and its values are consistent with the literature. The projected bulk velocity of the cluster is also recovered at the different lines of sight, with values in agreement with the simulation data

Cosmic Microwave Background Temperature at Galaxy Clusters

We have deduced the cosmic microwave background (CMB) temperature in the Coma cluster (A1656, $z=0.0231$), and in A2163 ($z=0.203$) from spectral measurements of the Sunyaev-Zel'dovich (SZ) effect over four passbands at radio and microwave frequencies. The resulting temperatures at these redshifts are $T_{Coma} = 2.789^{+0.080}_{-0.065}$ K and $T_{A2163} = 3.377^{+0.101}_{-0.102}$ K, respectively. These values confirm the expected relation $T(z)=T_{0}(1+z)$, where $T_{0}= 2.725 \pm 0.002$ K is the value measured by the COBE/FIRAS experiment. Alternative scaling relations that are conjectured in non-standard cosmologies can be constrained by the data; for example, if $T(z) = T_{0}(1+z)^{1-a}$ or $T(z)=T_{0}[1+(1+d)z]$, then $a=-0.16^{+0.34}_{-0.32}$ and $d = 0.17 \pm 0.36$ (at 95% confidence). We briefly discuss future prospects for more precise SZ measurements of $T(z)$ at higher redshifts.Comment: 13 pages, 1 figure, ApJL accepted for publicatio

Free N-heterocyclic carbenes from Brønsted acidic ionic liquids: Direct detection by electrospray ionization mass spectrometry

Rationale: The occurrence of N-heterocyclic carbenes in imidazolium-based ionic liquids has long been discussed, but no spectroscopic evidence has been reported yet due to their transient nature. The insertion of an ionizable acid group into the cation scaffold of an ionic liquid which acts as a charge tag allows for the direct detection of free carbenes by mass spectrometry. Methods: Three different Brønsted acidic ionic liquids were synthesized: 1-methyl-3-carboxymethylimidazolium chloride (MAICl), 1-methyl-3-carboxymethylimidazolium acetate (MAIAc) and the corresponding 2-(3-methyl-1H-imidazol-3-ium-1-yl)acetate zwitterion (MAI - H). The speciation of these compounds was then analysed by electrospray ionization ion-trap mass spectrometry in the negative ion mode. Results: The C2-H deprotonation of the imidazolium cation leading to the formation of the corresponding carbene is highly affected by the basic properties of the counter-anion. In the case of MAICl and MAI - H ionic liquids, no charged species corresponding to the free N-heterocyclic carbene was detected. On the contrary, in the presence of a sufficiently basic anion, such as acetate of MAIAc ionic liquid, an intense signal related to the free carbenic species was observed without the addition of an external base. Conclusions: In situ formation of free N-heterocyclic carbenes from Brønsted acidic ionic liquids was demonstrated, highlighting the crucial role of anion basicity in promoting the C2-H proton abstraction from imidazolium cations with a carboxylic side chain.Rationale The occurrence of N-heterocyclic carbenes in imidazolium-based ionic liquids has long been discussed, but no spectroscopic evidence has been reported yet due to their transient nature. The insertion of an ionizable acid group into the cation scaffold of an ionic liquid which acts as a charge tag allows for the direct detection of free carbenes by mass spectrometry. Methods Three different Bronsted acidic ionic liquids were synthesized: 1-methyl-3-carboxymethylimidazolium chloride (MAICl), 1-methyl-3-carboxymethylimidazolium acetate (MAIAc) and the corresponding 2-(3-methyl-1H-imidazol-3-ium-1-yl)acetate zwitterion (MAI - H). The speciation of these compounds was then analysed by electrospray ionization ion-trap mass spectrometry in the negative ion mode. Results The C2-H deprotonation of the imidazolium cation leading to the formation of the corresponding carbene is highly affected by the basic properties of the counter-anion. In the case of MAICl and MAI - H ionic liquids, no charged species corresponding to the free N-heterocyclic carbene was detected. On the contrary, in the presence of a sufficiently basic anion, such as acetate of MAIAc ionic liquid, an intense signal related to the free carbenic species was observed without the addition of an external base. Conclusions In situ formation of free N-heterocyclic carbenes from Bronsted acidic ionic liquids was demonstrated, highlighting the crucial role of anion basicity in promoting the C2-H proton abstraction from imidazolium cations with a carboxylic side chain

Objective and automatic classification of Parkinson disease with Leap Motion controller

Background: The main objective of this paper is to develop and test the ability of the Leap Motion controller (LMC) to assess the motor dysfunction in patients with Parkinson disease (PwPD) based on the MDS-UPDRSIII exercises. Four exercises (thumb forefinger tapping, hand opening/closing, pronation/supination, postural tremor) were used to evaluate the characteristics described in MDS-UPDRSIII. Clinical ratings according to the MDS/UPDRS-section III items were used as target. For that purpose, 16 participants with PD and 12 healthy people were recruited in Ospedale Cisanello, Pisa, Italy. The participants performed standardized hand movements with camera-based marker. Time and frequency domain features related to velocity, angle, amplitude, and frequency were derived from the LMC data. Results: Different machine learning techniques were used to classify the PD and healthy subjects by comparing the subjective scale given by neurologists against the predicted diagnosis from the machine learning classifiers. Feature selection methods were used to choose the most significant features. Logistic regression (LR), naive Bayes (NB), and support vector machine (SVM) were trained with tenfold cross validation with selected features. The maximum obtained classification accuracy with LR was 70.37%; the average area under the ROC curve (AUC) was 0.831. The obtained classification accuracy with NB was 81.4%, with AUC of 0.811. The obtained classification accuracy with SVM was 74.07%, with AUC of 0.675. Conclusions: Results revealed that the system did not return clinically meaningful data for measuring postural tremor in PwPD. In addition, it showed limited potential to measure the forearm pronation/supination. In contrast, for finger tapping and hand opening/closing, the derived parameters showed statistical and clinical significance. Future studies should continue to validate the LMC as updated versions of the software are developed. The obtained results support the fact that most of the set of selected features contributed significantly to classify the PwPD and healthy subjects