Religious Leadership and Critical Junctures in the 2022 Russian Invasion of Ukraine: 104 War Days of Metropolitan Hilarion

The chairman of the Department for External Church Relations (DECR) of the Russian Orthodox Church (ROC) Metropolitan Hilarion (Alfeyev) was dismissed from his office on the 104th day (June 7, 2022) of the Russian invasion of Ukraine. Was Hilarion dismissed because of his ‘silence’ on the Russian invasion? We study the 104 ‘war days’ of Metropolitan Hilarion from four dimensions: leadership as position; leadership as process; leadership as result; and leadership as person. Our findings are multivocal: the Russian invasion of Ukraine did become a leadership challenge for Hilarion the way that previous military interventions (in Ukraine and Syria) and thorough broadening of the collaboration between the Church and the military in Russia during his 13 years as the Chairman of the DECR did not; Hilarion refrained from the rhetoric (religious demonization of the adversaries) and narratives (e.g. ‘spiritual brothers cannot be in conflict,’ labelling the conflict ‘an internecine strife’) used by Patriarch Kirill, but Hilarion still opted to leave his position of professor in Fribourg University instead of condemning (delegitimizing) the Russian invasion of Ukraine; Hilarion had contributed to Patriarch Kirill’s doctrine of the ‘Russian world’ since 2009 and did not revoke any of his related positions during the 104 days of war. As the ‘religious’ concept of the “Russian world” is the key narrative whereby religious leaders of the ROC have legitimated Russian imperialism over the territory and population of Ukraine, the key indicator for Hilarion’s assumed ‘silence’ should be the rejection of the Russian world doctrine, not his commitment to the principle “war is not a conflict solution method.” Finally, we observe his successor (Metropolitan Anthony) to be even less vocal than Hilarion on religious and geopolitical issues related to Ukraine. This period studied started with a secular critical juncture (start of invasion) and ended with a critical juncture in religious relations on Ukrainian territories occupied by the Russian Federation, when with the June 7, 2022, decision of the Holy Synod of the ROC to relocate dioceses of the Orthodox Church in Crimea into direct subordination to the Moscow Patriarchate, the latter initiated cuius regio, eius religio paradigm in its relations with the Ukrainian Orthodox Church (of Moscow Patriarchate)

Edad y origen de la fluorita del yacimiento de la Nueva (Cabalango, Córdoba, Argentina) en base a geoquímica de isótopos radiogénicos (Nd y Sr)

The fluorite mineralization from the La Nueva Mine, has a Sm-Nd age of 130 ± 19 Ma, and thus must be related to the Lower Cretaceous late-Gondwanic extensional and magmatic event that affected the Sierras Pampeanas Basement of Argentina. Hydrothermal fluids involved in the formation of fluorite were probably derived by mixing of two fluids, an ascending high 87Sr/86Sr one, probably equilibrated with basement metamorphics, as suggested by the very negative ENd(130) values, and a second, "descending", with a low 87Sr/86Sr value

K-bentonites in the Argentine Precordillera contemporaneous with rhyolite volcanism in the Famatinian Arc

New U–Pb radiometric dates for K-bentonite horizons within the Lower Cambrian to Middle Ordovician platform carbonates from the Precordillera terrane of NWArgentina provide further constraints on models for the allochthonous or parautochthonous accretion of this terrane. Two K-bentonite layers from the Talacasto section yield indistinguishable sensitive high-resolution ion microprobe (SHRIMP) U–Pb zircon dates of 469.5 3.2 Ma and 470.1 3.3 Ma respectively. These are within uncertainty of the U–Pb SHRIMP zircon date of 468.3 3.4 Ma for a porphyritic rhyolite from the Famatinian magmatic arc, Sierra de las Planchadas, near Rio Chaschuil. Geochemical and isotope data also demonstrate the similarity of the Kbentonite and Chaschuil rhyolite parent magmas. Thus, it is highly probable that the Famatinian arc volcanoes provided the ash for the K-bentonite horizons, suggesting proximity to the Precordillera terrane during the deposition of the Lower Cambrian to Middle Ordovician platform carbonates. This implication supports a mid-Ordovician collision model, but could also be compatible with a parautochthonous model for docking of the Precordillera terrane, by movement along the Pacific margin of Gondwana, rather than across the Iapetus Ocean

Sr, C and O isotope composition of marbles from the Sierra de de Ancasti, Eastern Sierras Pampeanas, Argentina: age and constraints for the Neoproterozoic–Lower Paleozoic evolution of the proto-Gondwana margin

The Sierra Brava Complex on the eastern flank of the Sierra de Ancasti consists of marbles, metabasites, calc-silicate rocks, psammo-pelitic schists and gneisses. In the central part of this sierra a thick succession of banded schists (Ancasti Formation) crops out. Regional metamorphism of these rocks is attributed to the Famatinian orogeny (Ordovician), metamorphic grade increasing westwards and southwards and culminating in a migmatite complex on the western side of the Sierra. The meta-carbonate rocks are subdivided into a northeastern group (low-grade calcite marbles), and a southeastern group (high-grade calcite and calcite-dolomite marbles). Twenty-three marble samples were analysed for Sr isotope composition and Rb, Mn, Mg and Ca contents, and six for C and O isotope composition. An Ediacaran depositional age of 570 –590Ma is inferred by reference to the trend of 87Sr/86Sr in Neoproterozoic seawater. Thus the metacarbonates are probably slightly older than the Ancasti Formation (equivalent to the Puncoviscana Formation of northern Argentina), which has a maximum sedimentation age of ca. 570Ma. Ediacaran depositional ages have also been reported for metacarbonates elsewhere in Argentina, Uruguay and Brazil. We propose that the Sierra de Ancasti carbonates on one hand, and those in the Western Sierras Pampeanas (Difunta Correa Sequence) and –tentativelythe Corumbá Group of Brazil on the other, represent platforms on opposite margins of the extinct Clymene Ocean, whereas Neoproterozoic carbonate successions such as the Loma Negra Formation (Tandilia, southern Argentina) and the Arroyo del Soldado Group (Uruguay) were deposited on the eastern side (present coordinates) of the Rio de la Plata craton, which at the time occupied a position farther to the north.Peer reviewe

Granate con alto contenido de tierras raras pesadas (HREE) y elevada relación Sm/Nd, en pegmatitas de la Sierra de Valle Fértil (Sierras Pampeanas, Argentina).

2 p.El trabajo se realizó en el marco de lso proyectos PB97-1246 (MEC) y BTE2001-1486 (MCYT) y PICT98-4189 (Argentina

The effect of green waste composting on the concentration and composition of ambient bioaerosols

The emission and dispersal of bioaerosols from commercial composting facilities has become an issue of increasing concern over the past decade, as historical evidence links bioaerosol exposure to negative human health impacts. As a result, recommended concentrations and risk assessment limits were imposed in 2001. However, more recent research has suggested that these limits may be exceeded under certain circumstances. For example, underestimation of bioaerosol concentrations may occur through „snapshot‟ sampling, and the use of methods that may reduce culturability of bioaerosols. This study aimed to address several gaps in knowledge, including quantification of bioaerosol concentrations downwind from sites, analysis of the effect that operational and environmental influences have on emission and downwind concentrations, and investigation of methods for the enumeration of non-culturable bioaerosols. The concentrations of bioaerosols upwind, on-site and downwind from two open-air green waste windrow composting facilities were enumerated in extensive detail, producing the first detailed and validated database of bioaerosol concentrations at green-waste composting facilities. The effects of composting processing activities, season, and meteorological conditions on concentrations were also investigated utilising this dataset. Results from these studies suggested that bioaerosols are able to disperse in elevated concentrations to distances beyond the 250 m risk assessment limit. Downwind peaks in concentration were directly linked to compost processing activities on-site, with the risk of sensitive receptor exposure to bioaerosols during non-operational hours minimal. Further, it was found that patterns in downwind concentrations of bioaerosols are likely to be governed by buoyancy effects, as a second peak in concentrations was found at 100-150m downwind. This finding was further supported through the use of a novel direct counting method. Finally, molecular methods allowed the composition of bioaerosols emitted from composting to be determined and showed that composting significantly alters the aerobiotic community at distances downwind. The methods investigated provide the potential for detailed, continuous measurements of bioaerosols, alongside identification of potentially pathogenic microorganisms, and could ultimately lead to source apportionment of bioaerosols.EThOS - Electronic Theses Online ServiceGBUnited Kingdo

Involvement of the Argentine Precordillera terrane in the Famatinian mobile belt: U-Pb SHRIMP and metamorphic evidence from the Sierra de Pie de Palo

New data suggest that the eastern margin of the Argentine Precordillera terrane comprises Grenvillian basement and a sedimentary cover derived from it that were together affected by Middle Ordovician deformation and metamorphism during accretion to the Gondwana margin. The basement first underwent low pressure/temperature (P/T) type metamorphism, reaching high-grade migmatitic conditions in places (686 6 40 MPa, 790 6 17 8C), comparable to the Grenvillian M2 metamorphism of the supposed Laurentian counterpart of the terrane. The second metamorphism, recognized in the cover sequence, is of Famatinian age and took place under higher P/T conditions, following a clockwise P-T path (baric peak: 1300 6 100 Mpa, 600 6 50 8C). Low-U zircon overgrew detrital Grenvillian cores as pressure fell from its peak, and yields U-Pb SHRIMP ages of ca. 460 Ma. This is interpreted as the age of ductile thrusting coincident with early uplift; initial accretion to Gondwana must have occurred before this. The absence of late Neoproterozoic detrital zircons is consistent with a Laurentian origin of the Argentine Precordillera terrane