Adsorption of hard spheres: structure and effective density according to the potential distribution theorem

We propose a new type of effective densities via the potential distribution theorem. These densities are for the sake of enabling the mapping of the free energy of a uniform fluid onto that of a nonuniform fluid. The potential distribution theorem gives the work required to insert a test particle into the bath molecules under the action of the external (wall) potential. This insertion work W_ins can be obtained from Monte Carlo (MC) simulation (e.g. from Widom's test particle technique) or from an analytical theory. The pseudo-densities are constructed thusly so that when their values are substituted into a uniform-fluid equation of state (e.g. the Carnahan-Starling equation for the hard-sphere chemical potentials), the MC nonuniform insertion work is reproduced. We characterize the pseudo-density behavior for the hard spheres/hard wall system at moderate to high densities (from \rho^*= 0.5745 to 0.9135). We adopt the MC data of Groot et al. for this purpose. The pseudo-densities show oscillatory behavior out of phase (opposite) to that of the singlet densities. We also construct a new closure-based density functional theory (the star-function based density functional theory) that can give accurate description of the MC density profiles and insertion works. A viable theory is established for several cases in hard sphere adsorption.Comment: 15 pages, 10 figure

Motion of a sphere in the presence of a plane interface. Part 2. An exact solution in bipolar co-ordinates

A general solution for Stokes’ equation in bipolar co-ordinates is derived, and then applied to the arbitrary motion of a sphere in the presence of a plane fluid/fluid interface. The drag force and hydrodynamic torque on the sphere are then calculated for four specific motions of the sphere; namely, translation perpendicular and parallel to the interface and rotation about an axis which is perpendicular and parallel, respectively, to the interface. The most significant result of the present work is the comparison between these numerically exact solutions and the approximate solutions from part 1. The latter can be generalized to a variety of particle shapes, and it is thus important to assess their accuracy for this case of spherical particles where an exact solution can be obtained. In addition to comparisons with the approximate solutions, we also examine the predicted changes in the velocity, pressure and vorticity fields due to the presence of the plane interface. One particularly interesting feature of the solutions is the fact that the direction of rotation of a freely suspended sphere moving parallel to the interface can either be the same as for a sphere rolling along the interface (as might be intuitively expected), or opposite depending upon the location of the sphere centre and the ratio of viscosities for the two fluids

An evaluation of multiband photography for rock discrimination

The author has identified the following significant results. With the advent of ERTS and Skylab satellites, multiband imagery and photography have become readily available to geologists. The ability of multiband photography to discriminate sedimentary rocks was examined. More than 8600 in situ measurements of band reflectance of the sedimentary rocks of the Front Range, Colorado, were acquired. Statistical analysis of these measurements showed that: (1) measurements from one site can be used at another site 100 miles away; (2) there is basically only one spectral reflectance curve for these rocks, with constant amplitude differences between the curves; and (3) the natural variation is so large that at least 150 measurements per formation are required to select best filters. These conclusions are supported by subjective tests with aerial multiband photography. The designed multiband photography concept for rock discrimination is not a practical method of improving sedimentary rock discrimination capabilities

Solid rocket booster thermal radiation model, volume 1

A solid rocket booster (SRB) thermal radiation model, capable of defining the influence of the plume flowfield structure on the magnitude and distribution of thermal radiation leaving the plume, was prepared and documented. Radiant heating rates may be calculated for a single SRB plume or for the dual SRB plumes astride the space shuttle. The plumes may be gimbaled in the yaw and pitch planes. Space shuttle surface geometries are simulated with combinations of quadric surfaces. The effect of surface shading is included. The computer program also has the capability to calculate view factors between the SRB plumes and space shuttle surfaces as well as surface-to-surface view factors

IMPORT RULES FOR FMD CONTAMINATED BEEF

Under the new WTO trading rules the United States is obligated to revise its beef import policy and has proposed barriers based on classifying nations according to livestock health risks. This research develops a model which captures the impact of various degrees of FMD risk from imports on setting import barriers. The results show that nations classified as high risk for FMD continue to face prohibitive barriers. As outbreak risk falls so does the level of the barrier levied against that exporter. The barrier levels are also sensitive to the expected social losses as influenced by alternative control strategies.Food Consumption/Nutrition/Food Safety, International Relations/Trade,

The long-term prognostic significance of 6-minute walk test distance in patients with chronic heart failure

Background. The 6-minute walk test (6-MWT) is used to assess patients with chronic heart failure (CHF). The prognostic significance of the 6-MWT distance during long-term followup ( > 5 years) is unclear. Methods. 1,667 patients (median [inter-quartile range, IQR]) (age 72 [65-77] ; 75% males) with heart failure due to left ventricular systolic impairment undertook a 6-MWT as part of their baseline assessment and were followed up for 5 years. Results. At 5 years' followup, those patients who died (n = 959) were older at baseline and had a higher log NT pro-BNP than those who survived to 5 years (n = 708). 6-MWT distance was lower in those who died [163 (153) m versus 269 (160) m; P 360 m. 6-MWT distance was a predictor of all-cause mortality (HR 0.97; 95% CI 0.96-0.97; Chi-square = 184.1; P < 0.0001). Independent predictors of all-cause mortality were decreasing 6-MWT distance, increasing age, increasing NYHA classification, increasing log NT pro-BNP, decreasing diastolic blood pressure, decreasing sodium, and increasing urea. Conclusion. The 6-MWT is an important independent predictor of all-cause mortality following long-term followup in patients with CHF. © 2014 Lee Ingle et al

Getting creative in everyday life: Investigating arts and crafts hobbyists' information behavior

While there has been increasing interest in how creative professionals find information to drive creative outputs, previous information behavior research has largely ignored how arts and crafts hobbyists look for information sources in their everyday lives. To fill this literature gap, we conducted interviews and observations with arts and crafts hobbyists to find out how they conceive potential DIY projects. The findings highlight three themes: the dearth of human sources, the prevalence of domain-specific information, and the use of self-curated information. In addition to empirical results, this work also broadens the understanding of information behavior in an arts and crafts context by studying populations beyond professional artists

The creeping motion of a spherical particle normal to a deformable interface

Numerical results are presented for the approach of a rigid sphere normal to a deformable fluid-fluid interface in the velocity range for which inertial effects may be neglected. Both the case of a sphere moving with constant velocity, and that of a sphere moving under the action of a constant non-hydrodynamic body force are considered for several values of the viscosity ratio, density difference and interfacial tension between the two fluids. Two distinct modes of interface deformation are demonstrated: a film drainage mode in which fluid drains away in front of the sphere leaving an ever-thinning film, and a tailing mode where the sphere passes several radii beyond the plane of the initially undeformed interface, while remaining encapsulated by the original surrounding fluid which is connected with its main body by a thin thread-like tail behind the sphere. We consider the influence of the viscosity ratio, density difference, interfacial tension and starting position of the sphere in deter-mining which of these two modes of deformation will occur

Critical behavior of the three- and ten-state short-range Potts glass: A Monte Carlo study

We study the critical behavior of the short-range p-state Potts spin glass in three and four dimensions using Monte Carlo simulations. In three dimensions, for p = 3, a finite-size scaling analysis of the correlation length shows clear evidence of a transition to a spin-glass phase at T_c = 0.273(5) for a Gaussian distribution of interactions and T_c = 0.377(5) for a bimodal distribution. These results indicate that the lower critical dimension of the 3-state Potts glass is below three. By contrast, the correlation length of the ten-state (p = 10) Potts glass in three dimensions remains small even at very low temperatures and thus shows no sign of a transition. In four dimensions we find that the p = 3 Potts glass with Gaussian interactions has a spin-glass transition at T_c =0.536(3).Comment: 11 pages, 13 figures, 6 table