2,463 research outputs found
Array-based iterative measurements of SmKS travel times and their constraints on outermost core structure
Vigorous convection in Earth's outer core led to the suggestion that it is chemically homogeneous. However, there is increasing seismic evidence for structural complexities close to the outer core's upper and lower boundaries. Both body waves and normal mode data have been used to estimate a P wave velocity, V_p, at the top of the outer core (the Eâ layer), which is lower than that in the Preliminary Reference Earth Model. However, these low V_p models do not agree on the form of this velocity anomaly. One reason for this is the difficulty in retrieving and measuring SmKS arrival times. To address this issue, we propose a novel approach using data from seismic arrays to iteratively measure SmKS-SKKS-differential travel times. This approach extracts individual SmKS signal from mixed waveforms of the SmKS series, allowing us to reliably measure differential travel times. We successfully use this method to measure SmKS time delays from earthquakes in the FijiâTonga and Vanuatu subduction zones. SmKS time delays are measured by waveform cross correlation between SmKS and SKKS, and the crossâcorrelation coefficient allows us to access measurement quality. We also apply this iterative scheme to synthetic SmKS seismograms to investigate the 3âD mantle structure's effects. The mantle structure corrections are not negligible for our data, and neglecting them could bias the V_p estimation of uppermost outer core. After mantle structure corrections, we can still see substantial time delays of S3KS, S4KS, and S5KS, supporting a low V_p at the top of Earth's outer core
Improving efficiency of electrostatic spray-assisted vapor deposited Cu2ZnSn(S,Se)4 solar cells by modification of Mo/absorber interface
Electrostatic spray-assisted vapor deposition (ESAVD) is a non-vacuum, low cost and eco-friendly method to produce
Cu(In,Ga)Se2 and Cu2ZnSn(S,Se)4 (CZTSSe) absorbers for thin film solar cells, and it is a very promising
method for industrialization due to it is high deposition speed and close to unity deposition efficiency. In this
work, in order to improve the efficiency of ESAVD deposited CZTSSe solar cells, an ultrathin ZnO (circa 10 nm) layer was employed as an intermediate layer between CZTSSe and Mo back contact to avoid the direct contact
between Mo and CZTSSe and reduce the decomposition of CZTSSe during annealing process. XRF and EDX were used to characterize the chemical composition of CZTSSe before and after selenization respectively. SEM and Raman results showed the improved absorber morphology and the reduced direct interfacial reaction between CZTSSe and Mo. The improvement of the CZTSSe/Mo interface due to the intermediate layer was also reflected in the quality of the derived photovoltaic devices, leading to an improved efficiency of ESAVDdeposited kesterite solar cells from 3.25% to 4.03%
Machine Learning Approach for Predicting the Discharging Capacities of Doped lithium Nickel- Cobalt-Manganese Cathode Materials in Li-ion Batteries
Understanding the governing dopant feature for cyclic discharge capacity is vital for the design and discovery of new doped lithium nickelâcobaltâmanganese (NCM) oxide cathodes for lithium-ion battery applications. We herein apply six machine-learning regression algorithms to study the correlations of the structural, elemental features of 168 distinct doped NCM systems with their respective initial discharge capacity (IC) and 50th cycle discharge capacity (EC). First, a Pearson correlation coefficient study suggests that the lithium content ratio is highly correlated to both discharge capacity variables. Among all six regression algorithms, gradient boosting models have demonstrated the best prediction power for both IC and EC, with the root-mean-square errors calculated to be 16.66 mAhgâ1 and 18.59 mAhgâ1, respectively, against a hold-out test set. Furthermore, a game-theory-based variable-importance analysis reveals that doped NCM materials with higher lithium content, smaller dopant content, and lower-electronegativity atoms as the dopant are more likely to possess higher IC and EC. This study has demonstrated the exciting potentials of applying cutting-edge machine-learning techniques to accurately capture the complex structureâproperty relationship of doped NCM systems, and the models can be used as fast screening tools for new doped NCM structures with more superior electrochemical discharging properties
Electrokinetic behavior of two touching inhomogeneous biological cells and colloidal particles: Effects of multipolar interactions
We present a theory to investigate electro-kinetic behavior, namely,
electrorotation and dielectrophoresis under alternating current (AC) applied
fields for a pair of touching inhomogeneous colloidal particles and biological
cells. These inhomogeneous particles are treated as graded ones with physically
motivated model dielectric and conductivity profiles. The mutual polarization
interaction between the particles yields a change in their respective dipole
moments, and hence in the AC electrokinetic spectra. The multipolar
interactions between polarized particles are accurately captured by the
multiple images method. In the point-dipole limit, our theory reproduces the
known results. We find that the multipolar interactions as well as the spatial
fluctuations inside the particles can affect the AC electrokinetic spectra
significantly.Comment: Revised version with minor changes: References added and discussion
extende
NMR studies of Successive Phase Transitions in Na0.5CoO2 and K0.5CoO2
59Co- and 23Na-NMR measurements have been carried out on polycrystalline and
c-axis aligned samples of Na0.5CoO2, which exhibits successive transitions at
temperatures T = 87 K (= Tc1) and T = 53 K (= Tc2). 59Co-NMR has also been
carried out on c-axis aligned crystallites of K0.5CoO2 with similar successive
transitions at Tc1 ~ 60 K and Tc2 ~ 20 K. For Na0.5CoO2, two sets of three NMR
lines of 23Na nuclei explained by considering the quadrupolar frequencies nuQ
~1.32 and 1.40 MHz have been observed above Tc1, as is expected from the
crystalline structure. Rather complicated but characteristic variation of the
23Na-NMR spectra has been observed with varying T through the transition
temperatures, and the internal fields at two crystallographically distinct Na
sites are discussed on the basis of the magnetic structures reported
previously. The internal fields at two distinct Co sites observed below Tc1 and
the 591/T1-T curves of Na0.5CoO2 and K0.5CoO2 are also discussed in a
comparative way.Comment: 7 pages, 10 figures, submitted to J. Phys. Soc. Jpn, correction is
made in right colum of p6 (35th line) as K0.5CoO2-->Na0.5CoO
Electric field-induced transformations in bismuth sodium titanate-based materials
Electric field-induced transformations occur in a myriad of systems with a variegated phenomenology and have attracted widespread scientific interest due to their importance in many applications. The present review focuses on the electric field-induced transformations occurring in bismuth sodium titanate (BNT)-based materials, which are considered an important family of lead-free perovskites and represent possible alternatives to lead-based compounds for several applications. BNT-based systems are generally classified as relaxor ferroelectrics and are characterized by complex structures undergoing various electric field-driven phenomena. In this review, changes in crystal structure symmetry, domain configuration and macroscopic properties are discussed in relation to composition, temperature and electrical loading characteristics, including amplitude, frequency and DC biases. The coupling mechanisms between octahedral tilting with polarization and strain, and other microstructural features are identified as important factors mediating the local and overall electric field-induced response. The role of field-induced transformations on electrical fatigue is discussed by highlighting the effects of ergodicity on domain evolution and fatigue resistance in bipolar and unipolar cycles. The relevance of field-induced transformations in key applications, including energy storage capacitors, actuators, electrocaloric systems and photoluminescent devices is comprehensively discussed to identify materials design criteria. The review is concluded with an outlook for future research
Effect of Iodine Doping on BiSrCaCuO: Charge Transfer or Interlayer Coupling?
A comparative study has been made of iodine-intercalated
BiSrCaCuO single crystal and 1 atm O
annealed BiSrCaCuO single crystal using AC
susceptibility measurement, X-ray photoemission (XPS) and angle-resolved
ultraviolet photoemission spectroscopy (ARUPS). AC susceptibility measurement
indicates that O-doped samples studied have T of 84 K,
whereas T of Iodine-doped samples studied are 80 K. XPS Cu 2p core
level data establish that the hole concentration in the CuO planes are
essentially the same for these two kinds of samples. ARUPS measurements show
that electronic structure of the normal states near the Fermi level has been
strongly affected by iodine intercalation. We conclude that the dominant effect
of iodine doping is to alter the interlayer coupling.Comment: LBL 9 pages, APS_Revtex. 5 Figures, available upon request.
UW-Madison preprin
Nonlinear ER effects in an ac applied field
The electric field used in most electrorheological (ER) experiments is
usually quite high, and nonlinear ER effects have been theoretically predicted
and experimentally measured recently. A direct method of measuring the
nonlinear ER effects is to examine the frequency dependence of the same
effects. For a sinusoidal applied field, we calculate the ac response which
generally includes higher harmonics. In is work, we develop a multiple image
formula, and calculate the total dipole moments of a pair of dielectric
spheres, embedded in a nonlinear host. The higher harmonics due to the
nonlinearity are calculated systematically.Comment: Presented at Conference on Computational Physics (CCP2000), held at
Gold Coast, Australia from 3-8, December 200
A Note on Encodings of Phylogenetic Networks of Bounded Level
Driven by the need for better models that allow one to shed light into the
question how life's diversity has evolved, phylogenetic networks have now
joined phylogenetic trees in the center of phylogenetics research. Like
phylogenetic trees, such networks canonically induce collections of
phylogenetic trees, clusters, and triplets, respectively. Thus it is not
surprising that many network approaches aim to reconstruct a phylogenetic
network from such collections. Related to the well-studied perfect phylogeny
problem, the following question is of fundamental importance in this context:
When does one of the above collections encode (i.e. uniquely describe) the
network that induces it? In this note, we present a complete answer to this
question for the special case of a level-1 (phylogenetic) network by
characterizing those level-1 networks for which an encoding in terms of one (or
equivalently all) of the above collections exists. Given that this type of
network forms the first layer of the rich hierarchy of level-k networks, k a
non-negative integer, it is natural to wonder whether our arguments could be
extended to members of that hierarchy for higher values for k. By giving
examples, we show that this is not the case
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