Removal of terrestrial DOC in aquatic ecosystems of a temperate river network

Surface waters play a potentially important role in the global carbon balance. Dissolved organic carbon (DOC) fluxes are a major transfer of terrestrial carbon to river systems, and the fate of DOC in aquatic systems is poorly constrained. We used a unique combination of spatially distributed sampling of three DOC fractions throughout a river network and modeling to quantify the net removal of terrestrial DOC during a summer base flow period. We found that aquatic reactivity of terrestrial DOC leading to net loss is low, closer to conservative chloride than to reactive nitrogen. Net removal occurred mainly from the hydrophobic organic acid fraction, while hydrophilic and transphilic acids showed no net change, indicating that partitioning of bulk DOC into different fractions is critical for understanding terrestrial DOC removal. These findings suggest that river systems may have only a modest ability to alter the amounts of terrestrial DOC delivered to coastal zones

Plasma efavirenz concentration inversely correlates with increased risk of cytomegalovirus infection in HIV-infected pregnant women

Background. Effective combination antiretroviral therapy (cART) has tremendously reduced HIV-associated morbidity, mortality and mother-to-child transmission. However, the benefits of cART are threatened by comorbidities, adverse drug reactions and virus resistance to existing treatment regimens. One of the most occurring comorbidities is cytomegalovirus (CMV) infection. Objectives. To investigate the effects of cART on the occurrence of CMV infection among pregnant women. Methods. Using a cross-sectional study design, 175 HIV-infected pregnant women were recruited, and data were obtained from their clinical records. Blood samples were collected for host DNA, CMV DNA and plasma efavirenz (EFV) measurement. CMV DNA was measured using real-time polymerase chain reaction (PCR). CYP2B6 c.516G>T and CYP2B6 c.983T>C single nucleotide polymorphisms were characterised using PCR/restriction fragment length polymorphism and TaqMan assays, respectively. Plasma EFV concentrations were determined using high-performance liquid chromatography.Results. There was an inverse association between plasma EFV concentration and CMV DNA. Participants with lower plasma EFV concentrations were significantly (p<0.001) more likely to be CMV DNA positive than those with higher plasma concentrations. This result is also supported by the observation that carriers of CYP2B6 poor-metaboliser genotypes (CYP2B6 c.516T/T and CYP2B6 c.983T/C) were less likely to be positive for CMV DNA. Furthermore, poor metabolism as denoted by CYP2B6 c.516T/T and CYP2B6 c.983T/C genotypes was significantly associated with lower CMV viral load. Conclusions. HIV treatment disrupts the balance between host and co-infecting microbes. Reduced or subtherapeutic levels of antiretroviral drugs, which could be exacerbated by genetic polymorphisms in drug metabolism genes and non-adherence, predispose infected individuals to an increased risk of CMV infection in pregnancy.

Renormalized one-loop theory of correlations in polymer blends

The renormalized one-loop theory is a coarse-grained theory of corrections to the self-consistent field theory (SCFT) of polymer liquids, and to the random phase approximation (RPA) theory of composition fluctuations. We present predictions of corrections to the RPA for the structure function $S(k)$ and to the random walk model of single-chain statics in binary homopolymer blends. We consider an apparent interaction parameter $\chi_{a}$ that is defined by applying the RPA to the small $k$ limit of $S(k)$. The predicted deviation of $\chi_{a}$ from its long chain limit is proportional to $N^{-1/2}$, where $N$ is chain length. This deviation is positive (i.e., destabilizing) for weakly non-ideal mixtures, with \chi_{a} N \alt 1, but negative (stabilizing) near the critical point. The positive correction to $\chi_{a}$ for low values of $\chi_{a} N$ is a result of the fact that monomers in mixtures of shorter chains are slightly less strongly shielded from intermolecular contacts. The depression in $\chi_{a}$ near the critical point is a result of long-wavelength composition fluctuations. The one-loop theory predicts a shift in the critical temperature of ${\cal O}(N^{-1/2})$, which is much greater than the predicted ${\cal O}(N^{-1})$ width of the Ginzburg region. Chain dimensions deviate slightly from those of a random walk even in a one-component melt, and contract slightly with increasing $\chi_{e}$. Predictions for $S(k)$ and single-chain properties are compared to published lattice Monte Carlo simulations.Comment: submitted to J. Chem. Phy

Monte Carlo simulations of fluid vesicles with in plane orientational ordering

We present a method for simulating fluid vesicles with in-plane orientational ordering. The method involves computation of local curvature tensor and parallel transport of the orientational field on a randomly triangulated surface. It is shown that the model reproduces the known equilibrium conformation of fluid membranes and work well for a large range of bending rigidities. Introduction of nematic ordering leads to stiffening of the membrane. Nematic ordering can also result in anisotropic rigidity on the surface leading to formation of membrane tubes.Comment: 11 Pages, 12 Figures, To appear in Phys. Rev.

The [O III] Veil: Astropause of Eta Carinae's Wind?

We present narrowband images of eta Carinae in the light of [O III] 5007 obtained with HST/WFPC2, as well as a ground-based image in the same emission line with a larger field of view. These images show a thin veil of [O III] emission around eta Car and its ejecta, confirming the existence of an oxygen-bearing ``cocoon'' inferred from spectra. This [O III] veil may be the remnant of the pre-outburst wind of eta Car, and its outer edge probably marks the interface where eta Car's ejecta meet the stellar wind of the nearby O4 V((f)) star HD303308 or other ambient material -- i.e., it marks the ``astropause'' in eta Car's wind. This veil is part of a more extensive [O III] shell that appears to be shaped and ionized by HD303308. A pair of HST images with a 10 yr baseline shows no proper motion, limiting the expansion speed away from eta Car to 12pm13 km/s, or an expansion age of a few times 10^4 yr. Thus, this is probably the decelerated pre-outburst LBV wind of eta Car. The [O III] morphology is very different from that seen in [N II], which traces young knots of CNO-processed material; this represents a dramatic shift in the chemical makeup of material recently ejected by eta Car. This change in the chemical abundances may have resulted from the sudden removal of the star's outer envelope during eta Car's 19th century outburst or an earlier but similar event.Comment: 11 pages, 4 figs. Figs 1 and 3 in color. Accepted to AJ, October 200

Regularization of the Coulomb scattering problem

Exact solutions of the Schr\"odinger equation for the Coulomb potential are used in the scope of both stationary and time-dependent scattering theories in order to find the parameters which define regularization of the Rutherford cross-section when the scattering angle tends to zero but the distance r from the center remains fixed. Angular distribution of the particles scattered in the Coulomb field is investigated on the rather large but finite distance r from the center. It is shown that the standard asymptotic representation of the wave functions is not available in the case when small scattering angles are considered. Unitary property of the scattering matrix is analyzed and the "optical" theorem for this case is discussed. The total and transport cross-sections for scattering of the particle by the Coulomb center proved to be finite values and are calculated in the analytical form. It is shown that the considered effects can be essential for the observed characteristics of the transport processes in semiconductors which are defined by the electron and hole scattering in the fields of the charged impurity centers.Comment: 20 pages, 6 figure

Total Angular Momentum Waves for Scalar, Vector, and Tensor Fields

Most calculations in cosmological perturbation theorydecompose those perturbations into plane waves (Fourier modes). However, for some calculations, particularly those involving observations performed on a spherical sky, a decomposition into waves of fixed total angular momentum (TAM) may be more appropriate. Here we introduce TAM waves, solutions of fixed total angular momentum to the Helmholtz equation, for three-dimensional scalar, vector, and tensor fields. The vector TAM waves of given total angular momentum can be decomposed further into a set of three basis functions of fixed orbital angular momentum (OAM), a set of fixed helicity, or a basis consisting of a longitudinal (L) and two transverse (E and B) TAM waves. The symmetric traceless rank-2 tensor TAM waves can be similarly decomposed into a basis of fixed OAM or fixed helicity, or a basis that consists of a longitudinal (L), two vector (VE and VB, of opposite parity), and two tensor (TE and TB, of opposite parity) waves. We show how all of the vector and tensor TAM waves can be obtained by applying derivative operators to scalar TAM waves. This operator approach then allows one to decompose a vector field into three covariant scalar fields for the L, E, and B components and symmetric-traceless-tensor fields into five covariant scalar fields for the L, VE, VB, TE, and TB components. We provide projections of the vector and tensor TAM waves onto vector and tensor spherical harmonics. We provide calculational detail to facilitate the assimilation of this formalism into cosmological calculations. As an example, we calculate the power spectra of the deflection angle for gravitational lensing by density perturbations and by gravitational waves. We comment on an alternative approach to CMB fluctuations based on TAM waves. Our work may have applications elsewhere in field theory and in general relativity.Comment: 32 pages, Published version in PR

Orientational phase transitions in the hexagonal phase of a diblock copolymer melt under shear flow

We generalize the earlier theory by Fredrickson [J. Rheol. v.38, 1045 (1994)] to study the orientational behaviour of the hexagonal phase of diblock copolymer melt subjected to steady shear flow. We use symmetry arguments to show that the orientational ordering in the hexagonal phase is a much weaker effect than in the lamellae. We predict the parallel orientation to be stable at low and the perpendicular orientation at high shear rates. Our analysis reproduces the experimental results by Tepe et al. [Macromolecules v.28, 3008 (1995)] and explains the difficulties in experimental observation of the different orientations in the hexagonal phase.Comment: 21 pages, 6 eps figures, submitted to Physical Review

Multipole structure and coordinate systems

Multipole expansions depend on the coordinate system, so that coefficients of multipole moments can be set equal to zero by an appropriate choice of coordinates. Therefore, it is meaningless to say that a physical system has a nonvanishing quadrupole moment, say, without specifying which coordinate system is used. (Except if this moment is the lowest non-vanishing one.) This result is demonstrated for the case of two equal like electric charges. Specifically, an adapted coordinate system in which the potential is given by a monopole term only is explicitly found, the coefficients of all higher multipoles vanish identically. It is suggested that this result can be generalized to other potential problems, by making equal coordinate surfaces coincide with the potential problem's equipotential surfaces.Comment: 2 figure

The Emergence of the Modern Universe: Tracing the Cosmic Web

This is the report of the Ultraviolet-Optical Working Group (UVOWG) commissioned by NASA to study the scientific rationale for new missions in ultraviolet/optical space astronomy approximately ten years from now, when the Hubble Space Telescope (HST) is de-orbited. The UVOWG focused on a scientific theme, The Emergence of the Modern Universe, the period from redshifts z = 3 to 0, occupying over 80% of cosmic time and beginning after the first galaxies, quasars, and stars emerged into their present form. We considered high-throughput UV spectroscopy (10-50x throughput of HST/COS) and wide-field optical imaging (at least 10 arcmin square). The exciting science to be addressed in the post-HST era includes studies of dark matter and baryons, the origin and evolution of the elements, and the major construction phase of galaxies and quasars. Key unanswered questions include: Where is the rest of the unseen universe? What is the interplay of the dark and luminous universe? How did the IGM collapse to form the galaxies and clusters? When were galaxies, clusters, and stellar populations assembled into their current form? What is the history of star formation and chemical evolution? Are massive black holes a natural part of most galaxies? A large-aperture UV/O telescope in space (ST-2010) will provide a major facility in the 21st century for solving these scientific problems. The UVOWG recommends that the first mission be a 4m aperture, SIRTF-class mission that focuses on UV spectroscopy and wide-field imaging. In the coming decade, NASA should investigate the feasibility of an 8m telescope, by 2010, with deployable optics similar to NGST. No high-throughput UV/Optical mission will be possible without significant NASA investments in technology, including UV detectors, gratings, mirrors, and imagers.Comment: Report of UV/O Working Group to NASA, 72 pages, 13 figures, Full document with postscript figures available at http://casa.colorado.edu/~uvconf/UVOWG.htm