Shear-Velocity Structure and Dynamics Beneath the Sicily Channel and Surrounding Regions of the Central Mediterranean Inferred From Seismic Surface Waves

The evolution of the Sicily Channel Rift Zone (SCRZ) is thought to accommodate the regional tectonic stresses of the Calabrian subduction system. Much of the observations we have today are either limited to the surface or to the upper crust or deeper from regional seismic tomography, missing important details about the lithospheric structure and dynamics. It is unclear whether the rifting is passive from far-field extensional stresses or active from mantle upwelling beneath. We measure Rayleigh-and Love-wave phase velocities from ambient seismic noise and invert for 3-D shear-velocity and radial anisotropic models. Variations in crustal S-velocities coincide with topographic and tectonic features. The Tyrrhenian Sea has a ∼10 km thin crust, followed by the SCRZ (∼20 km). The thickest crust is beneath the Apennine-Maghrebian Mountains (∼55 km). Areas experiencing extension and intraplate volcanism have positive crustal radial anisotropy (VSH > VSV); areas experiencing compression and subduction-related volcanism have negative anisotropy. The crustal anisotropy across the Channel shows the extent of the extension. Beneath the Tyrrhenian Sea, we find very low sub-Moho S-velocities. In contrast, the SCRZ has a thin mantle lithosphere underlain by a low-velocity zone. The lithosphere-asthenosphere boundary rises from 60 km depth beneath Tunisia to ∼33 km beneath the SCRZ. Negative radial anisotropy in the upper mantle beneath the SCRZ is consistent with vertical mantle flow. We hypothesize a more active mantle upwelling beneath the rift than previously thought from an interplay between poloidal and toroidal fluxes related to the Calabrian slab, which in turn produces uplift at the surface and induces volcanism

Beer-Lambert law along non-linear mean light pathways for the rational analysis of Photoplethysmography

Photoplethysmography (PPG) is a technique that uses light to noninvasively obtain a volumetric measurement of an organ with each cardiac cycle. A PPG-based system emits monochromatic light through the skin and measures the fraction of the light power which is transmitted through a vascular tissue and detected by a photodetector. Part of thereby transmitted light power is modulated by the vascular tissue volume changes due to the blood circulation induced by the heart beating. This modulated light power plotted against time is called the PPG signal. Pulse Oximetry is an empirical technique which allows the arterial blood oxygen saturation (SpO2 – molar fraction) evaluation from the PPG signals. There have been many reports in the literature suggesting that other arterial blood chemical components molar fractions and concentrations can be evaluated from the PPG signals. Most attempts to perform such evaluation on empirical bases have failed, especially for components concentrations. This paper introduces a non-empirical physical model which can be used to analytically investigate the phenomena of PPG signal. Such investigation would result in simplified engineering models, which can be used to design validating experiments and new types of spectroscopic devices with the potential to assess venous and arterial blood chemical composition in both molar fractions and concentrations non-invasively

Magnetic Properties of FePt Nanoparticles Prepared by a Micellar Method

FePt nanoparticles with average size of 9 nm were synthesized using a diblock polymer micellar method combined with plasma treatment. To prevent from oxidation under ambient conditions, immediately after plasma treatment, the FePt nanoparticle arrays were in situ transferred into the film-growth chamber where they were covered by an SiO2 overlayer. A nearly complete transformation of L10 FePt was achieved for samples annealed at temperatures above 700 °C. The well control on the FePt stoichiometry and avoidance from surface oxidation largely enhanced the coercivity, and a value as high as 10 kOe was obtained in this study. An evaluation of magnetic interactions was made using the so-called isothermal remanence (IRM) and dc-demagnetization (DCD) remanence curves and Kelly–Henkel plots (ΔM measurement). The ΔM measurement reveals that the resultant FePt nanoparticles exhibit a rather weak interparticle dipolar coupling, and the absence of interparticle exchange interaction suggests no significant particle agglomeration occurred during the post-annealing. Additionally, a slight parallel magnetic anisotropy was also observed. The results indicate the micellar method has a high potential in preparing FePt nanoparticle arrays used for ultrahigh density recording media

Eur. J. Inorg. Chem.

Arrays of Pt nanoparticles with a high degree of hexagonal short-range order are deposited by means of self-assembly of diblock-copolymers on top of high quality epitaxial Au films and their influence on the electrical properties is studied. The temperature-dependent resistivity of the nanomodulated Au films is surprisingly well described by the classical size effect model of Fuchs–Sondheimer, which is based on a mixture of diffuse and specular surface scattering events. Especially, no specific influence of the interparticle distance of the nanoparticle array could be detected even though it was of the same magnitude as the elastic mean free path of the scattering electrons. Rather, the nanomodulation acts as randomly distributed scatterers leading to an overall decreased probability for specular reflections of conduction electrons at the sample surface

The self-organization of metal loaded micelles - an approach to prepare ordered arrays of metallic nanoislands

The preparation and characterization of hexagonally ordered pure Au nanoparticles is described. Self-assembly of diblock copolymers in solution is the driving force which leads to micellar structures. Starting, for example, with Au-salt loaded inverse micelles, monomicellar arrays exhibiting a significant hexagonal order can be prepared with taylored intermicellar distances and structure heights on top of various substrates. In order to remove the polymer matrix and to finally obtain arrays of pure Au nanoparticles, the micelles are first exposed to an oxygen plasma followed by an annealing process. Special attention is given to the chemical state of the nanoparticles applying photoelectron spectroscopy to control all preparational steps

Shear‐velocity structure and dynamics beneath the Sicily Channel and surrounding regions of the central Mediterranean inferred from seismic surface waves

The evolution of the Sicily Channel Rift Zone (SCRZ) is thought to accommodate the regional tectonic stresses of the Calabrian subduction system. Much of the observations we have today are either limited to the surface or to the upper crust or deeper from regional seismic tomography, missing important details about the lithospheric structure and dynamics. It is unclear whether the rifting is passive from far-field extensional stresses or active from mantle upwelling beneath. We measure Rayleigh-and Love-wave phase velocities from ambient seismic noise and invert for 3-D shear-velocity and radial anisotropic models. Variations in crustal S-velocities coincide with topographic and tectonic features. The Tyrrhenian Sea has a ∼10 km thin crust, followed by the SCRZ (∼20 km). The thickest crust is beneath the Apennine-Maghrebian Mountains (∼55 km). Areas experiencing extension and intraplate volcanism have positive crustal radial anisotropy (VSH > VSV); areas experiencing compression and subduction-related volcanism have negative anisotropy. The crustal anisotropy across the Channel shows the extent of the extension. Beneath the Tyrrhenian Sea, we find very low sub-Moho S-velocities. In contrast, the SCRZ has a thin mantle lithosphere underlain by a low-velocity zone. The lithosphere-asthenosphere boundary rises from 60 km depth beneath Tunisia to ∼33 km beneath the SCRZ. Negative radial anisotropy in the upper mantle beneath the SCRZ is consistent with vertical mantle flow. We hypothesize a more active mantle upwelling beneath the rift than previously thought from an interplay between poloidal and toroidal fluxes related to the Calabrian slab, which in turn produces uplift at the surface and induces volcanism