Coexistence of Paramagnetic-Charge-Ordered and Ferromagnetic-Metallic Phases in La0.5Ca0.5MnO3 evidenced by ESR

Throughout a complete Electron Spin Resonance (ESR) and magnetization study of La0.5Ca0.5MnO3, we discuss about the nature of the complex phase-segregated state established in this compound below T~210 K. Between TN<T<TC, the ESR spectra shows two lines characteristic of two different magnetic phases. From the resonance field (Hr) derived for each line we argue that the incommensurate-charge-ordering phase (ICO) which coexists with ferromagnetic-metallic (FMM) clusters in this temperature interval, is mainly paramagnetic and not antiferromagnetic. The FMM/ICO ratio can be tuned with a relatively small field, which suggests that the internal energy associated with those phases is very similar. Below TN, there is an appreciable FM contribution to the magnetization and the ESR spectra indicates the presence of FM clusters in an antiferromagnetic matrix (canted). Our results show that ESR could be a very useful tool to investigate the nature of the phase-separated state now believed to play a fundamental role in the physics of mixed valent manganites.Comment: 6 pages, 6 figure

HfO2 based memory devices with rectifying capabilities

We report on the fabrication and characterization of metal/insulator/metal capacitor like devices, with both rectifying and hysteretic features. Devices are formed by two junctions, Ti/HfO2 and Co/HfO2. Each junction exhibits highly repetitive hysteretic I-V curves with a sharp transition from a high to a low resistance state (3–4 orders of magnitude jump). The opposite transition (from low to high) is induced by polarity reversal. The rectifying non-crossing characteristics of the I-V branches denote their potential use as a multifunctional device, acting as a built-in rectifier and memory cell in a single device. Based on the phenomenological model description by Zazpe et al. [Appl. Phys. Lett. 103, 073114 (2013)], we propose a circuital equivalent representation supported on switchable rectifying junctions. By exploring different electrode connections, we disentangle the role of the bulk transport in HfO2 devices.Fil: Quinteros, Cynthia Paula. Comisión Nacional de Energía Atómica. Gerencia del Área Investigaciones y Aplicaciones no Nucleares; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; ArgentinaFil: Zaspe, R.. CIC nanoGUNE; EspañaFil: Marlasca, F. G.. Comisión Nacional de Energía Atómica. Gerencia del Área Investigaciones y Aplicaciones no Nucleares; ArgentinaFil: Golmar, Federico. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentina. Instituto Nacional de Tecnología Industrial; Argentina. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; ArgentinaFil: Casanova, F.. CIC nanoGUNE; España. Fundación Vasca para la Ciencia; EspañaFil: Stoliar, Pablo Alberto. Universidad Nacional de San Martín. Escuela de Ciencia y Tecnología; Argentina. Centre National de la Recherche Scientifique; Francia. Universite de Nantes; FranciaFil: Hueso, L.. Fundación Vasca para la Ciencia; España. CIC nanoGUNE; EspañaFil: Levy, Pablo Eduardo. Comisión Nacional de Energía Atómica. Gerencia del Área Investigaciones y Aplicaciones no Nucleares; Argentina. Consejo Nacional de Investigaciones Científicas y Técnicas; Argentin

Stationary waves and slowly moving features in the night upper clouds of Venus

At the cloud top level of Venus (65-70 km altitude) the atmosphere rotates 60 times faster than the underlying surface, a phenomenon known as superrotation. Whereas on Venus's dayside the cloud top motions are well determined and Venus general circulation models predict a mean zonal flow at the upper clouds similar on both day and nightside, the nightside circulation remains poorly studied except for the polar region. Here we report global measurements of the nightside circulation at the upper cloud level. We tracked individual features in thermal emission images at 3.8 and 5.0 $\mathrm{\mu m}$ obtained between 2006 and 2008 by the Visible and Infrared Thermal Imaging Spectrometer (VIRTIS-M) onboard Venus Express and in 2015 by ground-based measurements with the Medium-Resolution 0.8-5.5 Micron Spectrograph and Imager (SpeX) at the National Aeronautics and Space Administration Infrared Telescope Facility (NASA/IRTF). The zonal motions range from -110 to -60 m s$^{-1}$, consistent with those found for the dayside but with larger dispersion. Slow motions (-50 to -20 m s$^{-1}$) were also found and remain unexplained. In addition, abundant stationary wave patterns with zonal speeds from -10 to +10 m s$^{-1}$ dominate the night upper clouds and concentrate over the regions of higher surface elevation.Comment: 15 pages, 4 figures, 6 supplementary figure

Facile production of stable silicon nanoparticles: laser chemistry coupled to in situ stabilization via room temperature hydrosilylation

Stable, alkyl-terminated, light-emitting silicon nanoparticles have been synthesized in a continuous process by laser pyrolysis of a liquid trialkyl-silane precursor selected as a safer alternative to gas silane (SiH4). Stabilization was achieved by in situ reaction using a liquid collection system instead of the usual solid state filtration. The alkene contained in the collection liquid (1-dodecene) reacted with the newly formed silicon nanoparticles in an unusual room-temperature hydrosilylation process. It was achieved by the presence of fluoride species, also produced during laser pyrolysis from the decomposition of sulfur hexafluoride (SF6) selected as a laser sensitizer. This process directly rendered alkyl-passivated silicon nanoparticles with consistent morphology and size (<3 nm), avoiding the use of costly post-synthetic treatments

A chaotic long-lived vortex at Venus southern pole

Polar vortices are common in the atmospheres of rapidly rotating planets [1-4]. On Earth and Mars they are tied to the surface and their existence follows the seasonal insolation cycle [1-3]. Venus is a slowly rotating planet but it is also known to have vortices at both poles at the edge of a superrotating atmosphere [5-8]. However, their nature and long-term properties have not been constrained so far impeding precise modeling. Here we report cloud motions at two altitude levels (about 42 km and 63 km above the surface) using infrared images from the VIRTIS instrument onboard Venus Express that show that the south polar vortex is a permanent but erratic and unpredictable feature. We find that the centers of rotation of the vortex at these levels rarely coincide and both wander erratically around the pole with speeds of up to 16 m s-1. The cloud morphology and vorticity patches are uncorrelated and change continuously developing transient areas of small vertical motions. Venus south polar vortex is a continuously evolving structure immersed in a baroclinic environment laying at altitude levels that have variable vertical and meridional wind shears, extending at least 20 km in height through a quasi-convective turbulent region

Computational assessment of non-axisymmetric separate-jet exhausts on test rig configurations

The next generation of civil turbofan engines are likely to have increased bypass ratios and lower fan pressure ratios to improve propulsive efficiency and to reduce specific fuel consumption. However, the larger size of these engines may result in increased overall aircraft drag partially that could offset the fuel consumption benefits. Non-axisymmetric exhaust configurations can contribute to the mitigation of these effects through an improved alignment of the thrust vector relative to the drag axis. However, there is a lack of knowledge on how to experimentally test non-axisymmetric exhaust designs. To address this, the study develops a non-axisymmetric configuration of the Dual Stream-Flow Reference Nozzle (DSFRN) and assesses it with computational fluid dynamics in various configurations and conditions. The objective is to establish a baseline approach for testing non-axisymmetric exhausts. Overall, it is recommended to test non-axisymmetric exhausts with the ambient wind-on effects included and to evaluate the three-dimensional exhaust characteristics using thrust vector angles, in addition to overall velocity and discharge coefficients. Moreover, the interaction between a swept wing and the non-axisymmetric exhaust was found not to have a notable impact on the exhaust characteristics.Innovate UK and Rolls-Royce plc

Laser-driven direct synthesis of carbon nanodots and application as sensitizers for visible-light photocatalysis

We present the first successful synthesis of monodisperse carbon nanodots (CNDs) with tunable photoluminescence (PL) carried out by laser pyrolysis of two common volatile organic precursors such as toluene and pyridine. Remarkably, the initial chemical composition of the precursor determines the formation of undoped or N-doped CNDs and their corresponding absorption response in the visible range (expanded for the latter). We demonstrate the control and versatility of this synthesis method to tune the final outcome and its potential to explore a great number of potential solvent candidates. Furthermore, we have successfully exploited these CNDs (both undoped and N-doped) as effective sensitizers of TiO2 nanoparticles in the visible-light driven photo-degradation of a cationic dye selected as model organic pollutant

The impact of a large object with Jupiter in July 2009

On 2009 July 19, we observed a single, large impact on Jupiter at a planetocentric latitude of 55^{\circ}S. This and the Shoemaker-Levy 9 (SL9) impacts on Jupiter in 1994 are the only planetary-scale impacts ever observed. The 2009 impact had an entry trajectory opposite and with a lower incidence angle than that of SL9. Comparison of the initial aerosol cloud debris properties, spanning 4,800 km east-west and 2,500 km north-south, with those produced by the SL9 fragments, and dynamical calculations of pre-impact orbit, indicate that the impactor was most probably an icy body with a size of 0.5-1 km. The collision rate of events of this magnitude may be five to ten times more frequent than previously thought. The search for unpredicted impacts, such as the current one, could be best performed in 890-nm and K (2.03-2.36 {\mu}m) filters in strong gaseous absorption, where the high-altitude aerosols are more reflective than Jupiter's primary cloud.Comment: 15 pages, 5 figure