Detecting alcohol vapors using two-dimensional copper-based Ruddlesden-Popper perovskites

The detection of alcohol vapors has many important applications, such as measuring the breath ethanol content to prevent drug-impaired driving. A medical application is the detection of 1-propanol because this compound was found to be a potential marker for lung cancer screening. This work reports an alcohol sensor using the two-dimensional Ruddlesden-Popper perovskite bis(phenethylammonium) tetrachlorocuprate-(PEA)(2)CuCl4, also known as phenethylammonium copper chloride-as the sensing material. The device is based on a change in conductance upon exposure to alcohol vapors. A comparison between pristine (PEA)(2)CuCl4 and (PEA)(2)CuCl4 after a treatment with ultraviolet light shows that the latter has a higher conductance. Devices made with this UV-converted material show a strong response to 1-propanol vapors, starting from a concentration around 2000 parts per million (ppm). Additionally, these devices demonstrate stable behavior in a nitrogen atmosphere. During the stabilization of the 1-propanol flow rate, the concentration fluctuates. These fluctuations were detected by monitoring the current of the device over time, down to steps in 100ppm around a concentration of 8000ppm. The conductance of the devices decreases in contact with air. However, this process can be reversed by additional ultraviolet illumination, thereby making the devices reusable

Detection and mapping of illicit drugs and their metabolites in fingermarks by MALDI MS and compatibility with forensic techniques

Despite the proven capabilities of Matrix Assisted Laser Desorption Ionisation Mass Spectrometry (MALDI MS) in laboratory settings, research is still needed to integrate this technique into current forensic fingerprinting practice. Optimised protocols enabling the compatible application of MALDI to developed fingermarks will allow additional intelligence to be gathered around a suspect’s lifestyle and activities prior to the deposition of their fingermarks while committing a crime. The detection and mapping of illicit drugs and metabolites in latent fingermarks would provide intelligence that is beneficial for both police investigations and court cases. This study investigated MALDI MS detection and mapping capabilities for a large range of drugs of abuse and their metabolites in fingermarks; the detection and mapping of a mixture of these drugs in marks, with and without prior development with cyanoacrylate fuming or Vacuum Metal Deposition, was also examined. Our findings indicate the versatility of MALDI technology and its ability to retrieve chemical intelligence either by detecting the compounds investigated or by using their ion signals to reconstruct 2D maps of fingermark ridge details

Towards Uniform Gene Bank Documentation In Europe – The Experience From The EFABISnet Project

In the EFABISnet project, a collaborative effort of EAAP, FAO and partners from 14 European countries, in cooperation with the European Regional Focal Point for Animal Genetic Resources (ERFP), national information systems for monitoring the animal genetic resources on breed level were established in Austria, Cyprus, Estonia, Georgia, Iceland, Ireland, Italy, Netherlands, Slovakia, Slovenia, Switzerland, and United Kingdom. The network was soon extended beyond the project plans, with the establishment of EFABIS databases in Finland, Greece, and Hungary. The network was then complemented by a set of inventories of national gene bank collections to strengthen the documentation of ex situ conservation programmes. These documentation systems were established by the National Focal Points for management of farm animal genetic resources. Here we present the experience gained in establishment of these national inventories of gene banks and their relevance to the Strategic Priority Areas of the Global Plan of Action which could be useful for other areas in the world

Renormalization Group Study of the soliton mass on the (lambda Phi^4)_{1+1} lattice model

We compute, on the $(\lambda \Phi^4)_{1+1}$ model on the lattice, the soliton mass by means of two very different numerical methods. First, we make use of a ``creation operator'' formalism, measuring the decay of a certain correlation function. On the other hand we measure the shift of the vacuum energy between the symmetric and the antiperiodic systems. The obtained results are fully compatible. We compute the continuum limit of the mass from the perturbative Renormalization Group equations. Special attention is paid to ensure that we are working on the scaling region, where physical quantities remain unchanged along any Renormalization Group Trajectory. We compare the continuum value of the soliton mass with its perturbative value up to one loop calculation. Both quantities show a quite satisfactory agreement. The first is slightly bigger than the perturbative one; this may be due to the contributions of higher order corrections.Comment: 19 pages, preprint DFTUZ/93/0

Symmetry breaking from Scherk-Schwarz compactification

We analyze the classical stable configurations of an extra-dimensional gauge theory, in which the extra dimensions are compactified on a torus. Depending on the particular choice of gauge group and the number of extra dimensions, the classical vacua compatible with four-dimensional Poincar\'e invariance and zero instanton number may have zero energy. For SU(N) on a two-dimensional torus, we find and catalogue all possible degenerate zero-energy stable configurations in terms of continuous or discrete parameters, for the case of trivial or non-trivial 't Hooft non-abelian flux, respectively. We then describe the residual symmetries of each vacua.Comment: 24 pages, 1 figure, Section 4 modifie

SO(3) vortices as a mechanism for generating a mass gap in the 2d SU(2) principal chiral model

We propose a mechanism that can create a mass gap in the SU(2) chiral spin model at arbitrarily small temperatures. We give a sufficient condition for the mass gap to be non-zero in terms of the behaviour of an external Z(2) flux introduced by twisted boundary conditions. This condition in turn is transformed into an effective dual Ising model with an external magnetic field generated by SO(3) vortices. We show that having a nonzero magnetic field in the effective Ising model is sufficient for the SU(2) system to have a mass gap. We also show that certain vortex correlation inequalities, if satisfied, would imply a nonzero effective magnetic field. Finally we give some plausibility arguments and Monte Carlo evidence for the required correlation inequalities.Comment: 33 pages, LaTeX2e, all figures included in LaTeX forma

Determinants of Outcome in Non-Septic Critically Ill Patients with Acute Kidney Injury on Continuous Venovenous Hemofiltration

Background/Aims: In view of ongoing controversy, we wished to study whether patient characteristics and/or continuous venovenous hemofiltration (CVVH) characteristics contribute to the outcome of non-septic critically ill patients with acute kidney injury (AKI). Methods: We retrospectively studied 102 consecutive patients in the intensive care unit (ICU) with non-septic AKI needing CVVH. Patient and CVVH characteristics were evaluated. Primary outcome was mortality up to day 28 after CVVH initiation. Results: Forty-four patients (43%) died during the 28-day period after the start of CVVH. In univariate analyses, non-survivors had more often a cardiovascular reason for ICU admission, greater disease acuity/severity and organ failure, lower initial creatinine levels, less use of heparin and more use of bicarbonate-based substitution fluid. The latter two can be attributed to high lactate levels and bleeding tendency in non-survivors necessitating withholding lactate-buffered fluid and heparin, respectively, according to our clinical protocol. In multivariate analyses, mortality was predicted by disease severity, use of bicarbonate-based fluids and lack of heparin, while initial creatinine and CVVH dose did not contribute. Conclusion: The outcome of non-septic AKI in need of CVVH is more likely to be determined by underlying or concurrent, acute and severe disease rather than by CVVH characteristics, including timing and dose

Free energy of an SU(2) monopole-antimonopole pair

We present a high-statistic numerical study of the free energy of a monopole-antimonopole pair in pure SU(2) theory. We find that the monopole-antimonopole interaction potential exhibits a screened behavior, as one would expect in presence of a monopole condensate. Screening occurs both in the low-temperature, confining phase of the theory, and in the high-temperature deconfined phase, with no evidence of a discontinuity of the screening mass across the transition. The mass of the object responsible for the screening at low temperature is approximately twice the established value for the lightest glueball, indicating a prevalent coupling to glueball excitations. At high temperature, the screening mass increases. We contrast the behavior of the quantum system with that of the corresponding classical system, where the monopole-antimonopole potential is of the Coulomb type.Comment: Latex, 22 pages, 8 figures. A mistake in the computer program implementing the multihistogram method has been corrected and all the affected numerical data have been revised. The main conclusions of the paper are unchanged, but the screening masses turn out somehow larger. (We thank Philippe de Forcrand for correspondence which helped us find the error.