914 research outputs found
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Blockchain adoption in the maritime supply chain: Examining barriers and salient stakeholders in containerized international trade
YesThis study aimed to investigate the relationships between blockchain adoption barriers and identified the salient stakeholders for blockchain adoption in containerized international trade. The interpretative structural modelling and Cross-Impact Matrix Multiplication Applied to Classification analyses indicated that the most impactful among the eight barriers are lack of support from influential stakeholders, lack of understanding regarding blockchain, and lack of government regulations. The stakeholder mapping analysis demonstrated that the high salient stakeholders among 11 legitimate stakeholders are container lines, ports, beneficial cargo owners, freight forwarders/third party logistics, and customs authorities. The study is original and contributes to theory and practice as it uncovers both impactful barriers and critical stakeholders by adopting a stakeholder theory perspective and offers significant implications to practice, policy, and theory by combining these two analyses
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Social media engagement of stakeholders: A decision tree approach in container shipping
YesSocial media provides a significant avenue for stakeholder engagement which is crucial to ensure loyalty and satisfaction of stakeholders who possess valuable resources that can influence the business outcomes. Container lines – imperative members of global supply chains and facilitators of international trade – utilize social media to engage their stakeholders due to environmental and commercial complexity of their business. However, not all social media posts generate the same amount of stakeholder engagement. This study aims to identify and examine the social media post characteristics that lead to higher stakeholder engagement in the container shipping market. The study applies Chi-Squared Automatic Interaction Detection method to categorize social media posts based on their engagement levels. The analysis is conducted on the tweets of four global container lines which are posted between 1 September 2018 and 31 January 2019. The results demonstrate that social media posts of container lines have varying effects on engagement level. We found that fluency of tweets, tangibility of company resources in the tweet, vividness level, content type, existence of a link, and existence of a call-to-action significantly influence the container lines’ stakeholder engagement rate. This study is the first that finds out social media post classes based on the interaction between their characteristics and engagement rates by employing a decision tree methodology. The results are expected to help container lines in their social media management and stakeholder engagement policies
Graph-based Features for Automatic Online Abuse Detection
While online communities have become increasingly important over the years,
the moderation of user-generated content is still performed mostly manually.
Automating this task is an important step in reducing the financial cost
associated with moderation, but the majority of automated approaches strictly
based on message content are highly vulnerable to intentional obfuscation. In
this paper, we discuss methods for extracting conversational networks based on
raw multi-participant chat logs, and we study the contribution of graph
features to a classification system that aims to determine if a given message
is abusive. The conversational graph-based system yields unexpectedly high
performance , with results comparable to those previously obtained with a
content-based approach
Evolution of Superconductivity in Electron-Doped Cuprates: Magneto-Raman Spectroscopy
The electron-doped cuprates Pr_{2-x}Ce_xCuO_4 and Nd_{2-x}Ce_xCuO_4 have been
studied by electronic Raman spectroscopy across the entire region of the
superconducting (SC) phase diagram. The SC pairing strength is found to be
consistent with a weak-coupling regime except in the under-doped region where
we observe an in-gap collective mode at 4.5 k_{B}T_c while the maximum
amplitude of the SC gap is ~8 k_{B}T_{c}. In the normal state, doped carriers
divide into coherent quasi-particles (QPs) and carriers that remain incoherent.
The coherent QPs mainly reside in the vicinity of (\pi/2, \pi/2) regions of the
Brillouin zone (BZ). We find that only coherent QPs contribute to the
superfluid density in the B_{2g} channel. The persistence of SC coherence peaks
in the B_{2g} channel for all dopings implies that superconductivity is mainly
governed by interactions between the hole-like coherent QPs in the vicinity of
(\pi/2, \pi/2) regions of the BZ. We establish that superconductivity in the
electron-doped cuprates occurs primarily due to pairing and condensation of
hole-like carriers. We have also studied the excitations across the SC gap by
Raman spectroscopy as a function of temperature (T) and magnetic field (H) for
several different cerium dopings (x). Effective upper critical field lines
H*_{c2}(T, x) at which the superfluid stiffness vanishes and
H^{2\Delta}_{c2}(T, x) at which the SC gap amplitude is suppressed by field
have been determined; H^{2\Delta}_{c2}(T, x) is larger than H*_{c2}(T, x) for
all doping concentrations. The difference between the two quantities suggests
the presence of phase fluctuations that increase for x< 0.15. It is found that
the magnetic field suppresses the magnitude of the SC gap linearly at
surprisingly small fields.Comment: 13 pages, 8 figures; submitted to Phys. Rev.
A METHODOLOGY FOR VALIDATING MULTIVARIATE RESPONSE SIMULATION MODELS BY USING SIMULTANEOUS CONFIDENCE INTERVALS
This paper deals with the substantiation that a multivariate response self- or trace-driven simulation model, within its domain of applicability, possesses a satisfactory range of accuracy consistent with the intended application of the model.
A methodology is developed by using simultaneous confidence intervals to do this substantiation with respect to the mean behavior of a simulation model that represents an observable system. A trade off analysis can be performed and judgement decisions can be made as to what data collection budget to allocate, what data collection method to use, how many observations to collect on each of the model and system response variables, and what confidence level to choose for producing the range of accuracy with satisfactory lengths. The methodology is illustrated for self-driven steady-state and trace-driven terminating simulations
VALIDATION OF MULTIVARIATE RESPONSE SIMULATION MODELS BY USING HOTELLING'S TWO-SAMPLE T^2 TEST
A procedure is developed by using Hotelling's two-sample T^2 test
to test the validity of a multivariate response simulation model that
represents an observable system. The validity of the simulation model
is tested with respect to the mean behavior under a given experimental
frame.
A trade-off analysis can be performed and judgement decisions can
be made as to what data collection budget to allocate, what data
collection method to use, how many observations to collect on each of
the model and system response variables, and what model builder's risk
to choose for testing the validity under a satisfactory model user's
risk.
The procedure for validation is illustrated for a simulation model
that represents an M/M/l queueing system with two performance measures
of interest
Tunable Plexcitonic Nanoparticles: A Model System for Studying Plasmon-Exciton Interaction from the Weak to the Ultrastrong Coupling Regime
Controlling the number of dye molecules on metallic nanoparticles, which in turn affects the magnitude of Rabi splitting energy, is crucial for obtaining hybrid metal core-organic shell nanoparticles with tunable optical properties in the visible spectrum since the magnitude of the Rabi splitting energy directly determines the strength of the coupling between plasmonic nanoparticles and dye molecules. In this work, we present a new method for the synthesis of plexcitonic nanoparticles, and thus we are able to control the number of dye molecules self-assembled on Ag nanoprisms (Ag NPs) by adjusting the concentration of dye molecules used in the synthesis. Indeed, individual dye molecules self-assemble into J-aggregates on Ag NPs. Thus, in the finite-element simulations and experimental data of the hybrid metal organic nanoparticles, we observed a transition from weak coupling to the ultrastrong coupling regime. Besides, ultrafast energy transfer between plasmonic nanoparticles and excitonic aggregated dye molecules has been extensively studied as a function of Rabi splitting energy. We observe that the lifetime of the polariton states increases with the coupling strength and the upper polaritons are short-lived, whereas the lower polaritons are long-lived. Hybrid metal-organic nanoparticles presented in this study (i) have tunable Rabi splitting energies, (ii) are easy to prepare in large quantities in aqueous medium, (iii) can be uniformly assembled on solid substrates, (iv) have resonance frequencies in the visible spectrum, and (v) have small mode volume, thus making them an excellent model system for studying light-matter interaction at nanoscale dimensions from the weak to ultrastrong coupling regime. © 2016 American Chemical Society
Probing ultrafast energy transfer between excitons and plasmons in the ultrastrong coupling regime
Cataloged from PDF version of article.We investigate ultrafast energy transfer between excitons and plasmons in ensembles of core-shell type nanoparticles consisting of metal core covered with a concentric thin J-aggregate (JA) shell. The high electric field localization by the Ag nanoprisms and the high oscillator strength of the JAs allow us to probe this interaction in the ultrastrong plasmon-exciton coupling regime. Linear and nonlinear optical properties of the coupled system have been measured using transient absorption spectroscopy revealing that the hybrid system shows half-plasmonic and half-excitonic properties. The tunability of the nanoprism plasmon resonance provides a flexible platform to study the dynamics of the hybrid state in a broad range of wavelengths. (C) 2014 AIP Publishing LLC
Inhomogeneous electronic structure probed by spin-echo experiments in the electron doped high-Tc superconductor Pr_{1.85}Ce_{0.15}CuO_{4-y}
63Cu nuclear magnetic resonance (NMR) spin-echo decay rate (T_2^{-1})
measurements are reported for the normal and superconducting states of a single
crystal of Pr_{1.85}Ce_{0.15}CuO_{4-y} (PCCO) in a magnetic field B_0=9T over
the temperature range 2K<T<200K. The spin-echo decay rate is
temperature-dependent for T<55K, and has a substantial dependence on the radio
frequency (rf) pulse parameters below T~25K. This dependence indicates that
T_2^{-1} is strongly effected by a local magnetic field distribution that can
be modified by the rf pulses, including ones that are not at the nuclear Larmor
frequency. The low-temperature results are consistent with the formation of a
static inhomogeneous electronic structure that couples to the rf fields of the
pulses.Comment: 4 pages, 4 figure
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