The influence of plasma nitriding on the microstructure of X153CrMoV12 and X165CrV12 steels

This study presents the results of research into the influence of the time of the plasma nitriding process on the microstructure of the coatings obtained on cold-work tool steels X153CrMoV12 and X165CrV12. The processes were carried out under industrial conditions using an Ionit system (Oerlikon Metaplas) with variable process times of 2, 4 and 6 hours. Nitriding mixture consisting of 5 % nitrogen and 95 % hydrogen was chosen, which allowed the expected diffusion layer to be obtained without a white layer (composed of iron nitrides). Analysis of relative elemental concentrations indicates that the presence and content of nitride-forming elements influences the formation of alloy additive nitrides in the microstructure of the diffusion layer. Nitrides of alloying additives, present in the diffusion layer, indicating that investigated steels are the most suitable for plasma nitriding

Optical, Dielectric and Magnetic Properties of La1−xNdxFeO3 Powders and Ceramics

Nanocrystalline La1−xNdxFeO3 powders with different concentrations of Nd3+ have been synthesized using a modified Pechini method. Their structures were studied by X-ray powder diffraction (XRD). Furthermore, La1−xNdxFeO3 nanoceramics were prepared using a high pressure sintering technique. The luminescence spectra of the powders were investigated as a function of concentration of active dopant to check the possible energy transfers observed due to Nd3+ concentration changes. The electrical and magnetic properties of the powders and ceramics were investigated to determine the effect of Nd3+ doping on the dielectric permittivity and magnetization in the wide frequency range. © 2018 by the authors. Licensee MDPI, Basel, Switzerland.Funding: This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 778070—TransFerr—H2020-MSCA-RISE-2017. Part of the work was developed within the scope of the project CICECO-Aveiro Institute of Materials, POCI-01-0145-FEDER-007679 (FCT Ref. UID/CTM/50011/2013), financed by national funds through the FCT/MEC and when appropriate co-financed by FEDER under the PT2020 Partnership Agreement

Impact of Alkali Ions Codoping on Magnetic Properties of La(0.9)A(0.1)Mn(0.9)Co(0.1)O(3) (A: Li, K, Na) Powders and Ceramics

The aim of the work was to check how the introduction of alkali and cobalt ions into a manganese structure can affect the structural disorder and, in consequence, lead to the changes (improvements) of magnetic properties. The high-pressure sintering technique was applied to check if the external factor can modify the magnetization of manganites. Nanocrystalline La0.9A0.1Mn0.9Co0.1O3 (where A is Li, K, Na) powders were synthesized by the combustion technique. The respective powders were used for nanoceramics preparation by the high-pressure sintering technique. The structure and morphology of the compounds were studied by X-ray powder diffraction, scanning electron microscopy and energy-dispersive X-ray spectroscopy. Magnetization studies for all compounds were performed in order to check the changes induced by either codoping or the sintering pressure. It was found that the type of the dopant ion and sintering pressure produced significant changes to the magnetic properties of the studied compounds. Alkali ions lead to the stabilization of Co ions in the +2 oxidation state and the formation of positive exchange interactions Mn3+–Mn4+ and Co2+–Mn4+ and the subsequent increase in remanent magnetization. High sintering pressure leads to a decrease in grain size and reduction of long-range ferromagnetic order and lower magnetization. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Skłodowska‐Curie grant agreement No 778070–TransFerr–H2020‐MSCA‐RISE‐ 2017. Part of this work was developed within the scope of the project CICECO‐Aveiro Institute of Materials, UIDB/50011/2020 and UIDP/50011/2020, financed by national funds through the Portuguese Foundation for Science and Technology/MCTES. The equipment of the Ural Center for Shared Use “Modern nanotechnology” UrFU was used. The work has been supported in part by the Ministry of Science and Higher Education of the Russian Federation under Project № FEUZ‐2020‐0054

Nanoscale Ferroelectricity in Pseudo-cubic Sol-gel Derived Barium Titanate - bismuth Ferrite (BaTiO3– BiFeO3) Solid Solutions

Single phase barium titanate–bismuth ferrite ((1-x)BaTiO3-(x)BiFeO3, BTO-BFO) solid solutions were prepared using citric acid and ethylene glycol assisted sol-gel synthesis method. Depending on the dopant content the samples are characterized by tetragonal, tetragonal-pseudocubic, pseudocubic and rhombohedral structure as confirmed by Raman spectroscopy and XRD measurements. An increase of the BFO content leads to a reduction in the cell parameters accompanied by a decrease in polar distortion of the unit cell wherein an average particle size increases from 60 up to 350 nm. Non zero piezoresponse was observed in the compounds with pseudocubic structure while no polar distortion was detected in their crystal structure using X-ray diffraction method. The origin of the observed non-negligible piezoresponse was discussed assuming a coexistence of nanoscale polar and non-polar phases attributed to the solid solutions with high BFO content. A coexistence of the nanoscale regions having polar and non-polar character is considered as a key factor to increase macroscopic piezoresponse in the related compounds due to increased mobility of the domain walls and phase boundaries. © 2020 Elsevier B.V.The work has been done in frame of the project TransFerr. This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No. 778070 . The scanning probe microscopy study was funded by RFBR (grant No. 19-52-04015 ) and BRFFR (grant No. F19RM-008 ). The equipment of the Ural Center for Shared Use “Modern nanotechnology” UrFU was used. Sample structural characterization was funded by RFBR (grant № 18-38-20020 mol_a_ved). M.S. also acknowledges Russian academic excellence project “5–100″ for Sechenov University. This work was developed within the scope of the project CICECO-Aveiro Institute of Materials, refs. UIDB/50011/2020 & UIDP/50011/2020, financed by national funds through the FCT/MEC

Microstructure and Properties of Cu-Nb Wire Composites

Nowadays, there is much activity all over the world in development of Cu-Nb composites for their potential use as conductors in high field magnets. This study was aimed at investigation of microstructure, mechanical and electrical properties of Cu-Nb composite wires. The investigated materials have been processed by vacuum furnace melting and casting, and then hot forging and cold drawing. Initial results of research into Cu-Nb composite material obtained using repeated iterative drawing of niobium wires compacted into copper tube, have been also presented in this article. The ultimate tensile strength versus cold deformation degree has been presented. These changes have been discussed in relation to microstructure evolution. It was assumed that repeated drawing of compacted wires is a promising method for fibrous composite production (more than 823,000 Nb fibres of nanometric diameter) characterized by high mechanical properties and electrical conductivity. Original SPD technique applied for Cu-Nb composite deformation result in initial microstructure refinement and improves effectiveness of wire production process.Aktualnie obserwuje się na świecie intensywny rozwój kompozytów Cu-Nb stosowanych jako przewody nawojowe generatorów silnych pól magnetycznych. Badania miały na celu określenie mikrostruktury oraz właściwości mechanicznych i elektrycznych drutów kompozytowych Cu-Nb. Badane materiały wytworzono przez zastosowanie topienia i odlewania w piecu próżniowym, a następnie kucia na gorąco i ciągnienia. Zaprezentowano także wstępne wyniki badań wytwarzania kompozytu Cu-Nb na drodze iteracyjnego ciągnienia pakietu drutów niobowych w rurze miedzianej. Pokazano wyniki badań wytrzymałości na rozciąganie w zależności od stopnia odkształcenia, w powiązaniu ze zmianami mikrostruktury. Stwierdzono, że wielokrotne ciągnienie pakietu drutów jest obiecująca metoda wytwarzania kompozytów włóknistych (ponad 823000 włókien Nb o przekroju nanometrycznym) o wysokich właściwościach mechanicznych i konduktywności elektrycznej

Mikrostruktura i własności drutów kompozytowych Cu-Nb

Nowadays, there is much activity all over the world in development of Cu-Nb composites for their potential use as conductors in high field magnets. This study was aimed at investigation of microstructure, mechanical and electrical properties of Cu-Nb composite wires. The investigated materials have been processed by vacuum furnace melting and casting, and then hot forging and cold drawing. Initial results of research into Cu-Nb composite material obtained using repeated iterative drawing of niobium wires compacted into copper tube, have been also presented in this article. The ultimate tensile strength versus cold deformation degree has been presented. These changes have been discussed in relation to microstructure evolution. It was assumed that repeated drawing of compacted wires is a promising method for fibrous composite production (more than 823,000 Nb fibres of nanometric diameter) characterized by high mechanical properties and electrical conductivity. Original SPD technique applied for Cu-Nb composite deformation result in initial microstructure refinement and improves effectiveness of wire production process.Aktualnie obserwuje się na świecie intensywny rozwój kompozytów Cu-Nb stosowanych jako przewody nawojowe generatorów silnych pól magnetycznych. Badania miały na celu określenie mikrostruktury oraz właściwości mechanicznych i elektrycznych drutów kompozytowych Cu-Nb. Badane materiały wytworzono przez zastosowanie topienia i odlewania w piecu próżniowym, a następnie kucia na gorąco i ciągnienia. Zaprezentowano także wstępne wyniki badań wytwarzania kompozytu Cu-Nb na drodze iteracyjnego ciągnienia pakietu drutów niobowych w rurze miedzianej. Pokazano wyniki badań wytrzymałości na rozciąganie w zależności od stopnia odkształcenia, w powiązaniu ze zmianami mikrostruktury. Stwierdzono, że wielokrotne ciągnienie pakietu drutów jest obiecująca metoda wytwarzania kompozytów włóknistych (ponad 823000 włókien Nb o przekroju nanometrycznym) o wysokich właściwościach mechanicznych i konduktywności elektrycznej

Influence of the repetitive corrugation on the mechanism occuring during plastic Deformation of CuSn6 alloy

Influence of the repetitive corrugation on the mechanism occuring during plastic Deformation of CuSn6 alloy This paper presents the research results of Cu$n6 alloy strip at semi-hard state, plastically deformed in the process of repetitive corrugation. The influence of process parameters on the mechanical properties and structure of examined alloy were investigated. Examination in high-resolution transmission electron microscopy (HRTEM) confirmed the impact of the repetitive corrugation to obtain the nano-scale structures. It has been found, that the application of repetitive corrugation increases the tensile strength (Rm). yield strength (Rpo:) and elastic limit (Rpo.os) of CuSn6 alloy strips. In the present work it has been confirmed that the repetitive corrugation process is a more efficient method for structure and mechanical properties modification of commercial CuSn6 alloy strip (serni-hard) as compared with the classic rolling process

The influence of plasma nitriding on the microstructure of X153CrMoV12 and X165CrV12 steels

This study presents the results of research into the influence of the time of the plasma nitriding process on the microstructure of the coatings obtained on cold-work tool steels X153CrMoV12 and X165CrV12. The processes were carried out under industrial conditions using an Ionit system (Oerlikon Metaplas) with variable process times of 2, 4 and 6 hours. Nitriding mixture consisting of 5 % nitrogen and 95 % hydrogen was chosen, which allowed the expected diffusion layer to be obtained without a white layer (composed of iron nitrides). Analysis of relative elemental concentrations indicates that the presence and content of nitride-forming elements influences the formation of alloy additive nitrides in the microstructure of the diffusion layer. Nitrides of alloying additives, present in the diffusion layer, indicating that investigated steels are the most suitable for plasma nitriding