341 research outputs found

    Cu/cuo composite track-etched membranes for catalytic decomposition of nitrophenols and removal of as(III)

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    One of the promising applications of nanomaterials is to use them as catalysts and sorbents to remove toxic pollutants such as nitroaromatic compounds and heavy metal ions for environmental protection. This work reports the synthesis of Cu/CuO-deposited composite track-etched membranes through low-temperature annealing and their application in catalysis and sorption. The synthesized Cu/CuO/poly(ethylene terephthalate) (PET) composites presented efficient catalytic activity with high conversion yield in the reduction of nitro aryl compounds to their corresponding amino derivatives. It has been found that increasing the time of annealing raises the ratio of the copper(II) oxide (CuO) tenorite phase in the structure, which leads to a significant increase in the catalytic activity of the composites. The samples presented maximum catalytic activity after 5 h of annealing, where the ratio of CuO phase and the degree of crystallinity were 64.3% and 62.7%, respectively. The catalytic activity of pristine and annealed composites was tested in the reduction of 4-nitroaniline and was shown to remain practically unchanged for five consecutive test cycles. Composites annealed at 140 °C were also tested for their capacity to absorb arsenic(III) ions in cross-flow mode. It was observed that the sorption capacity of composite membranes increased by 48.7% compared to the pristine sample and reached its maximum after 10 h of annealing, then gradually decreased by 24% with further annealing. © 2020 by the authors. Licensee MDPI, Basel, Switzerland.Ministry of Education and Science of the Republic of Kazakhstan: AP05130797Funding: A.M. gratefully acknowledges the funding of the Ministry of Education and Science of the Republic of Kazakhstan (Project AP05130797)

    Composition of γ-ray induced triethoxyvinylsilane-methyl methacrylate copolymers determined by XPS

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    Methyl methacrylate (MMA) was copolymerized with triethoxyvinylsilane (TEVS) using 60Co-γ radiation at varying masses of the liquid monomers in the feed. Their homopolymers PMMA and PTEVS were also prepared by the same method. Thin copolymer and homopolymer blend films were prepared by dissolving the polymers in tetrahydrofuran and casting on clean Teflon or glass substrates. Analysis of the surface composition of these films using XPS indicated that the surfaces of the blend films were completely covered by PTEVS after 10% composition by weight. Similar analysis on the copolymer films, however, revealed that the surfaces of the copolymers contain comparable amounts of PMMA and PTEVS in agreement with the bulk analysis using infrared spectrometry. Hence, use of PMMA/PTEVS copolymers for stone preservation seems feasible by radiation induced polymerization. © 1998 Elsevier Science Ltd. All rights reserved

    (1,0) superconformal theories in six dimensions and Killing spinor equations

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    We solve the Killing spinor equations of 6-dimensional (1,0) superconformal theories in all cases. In particular, we derive the conditions on the fields imposed by the Killing spinor equations and demonstrate that these depend on the isotropy group of the Killing spinors. We focus on the models proposed by Samtleben et al in \cite{ssw} and find that there are solutions preserving 1,2, 4 and 8 supersymmetries. We also explore the solutions which preserve 4 supersymmetries and find that many models admit string and 3-brane solitons as expected from the M-brane intersection rules. The string solitons are smooth regulated by the moduli of instanton configurations.Comment: 26 page

    Aquifer thermal energy storage: An attempt to counter free thermal convection

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    This is the published version. Copyright 1983 American Geophysical UnionIn previous Aquifer Thermal Energy Storage (ATES) experiments, appreciable free thermal convection was observed. In an attempt to counter the detrimental effects of convection, a dual recovery well system was constructed at the Mobile site and a third injection-storage-recovery cycle performed. Using a partially penetrating well, cycle 3-3 injection began on April 7, 1982. A total of 56,680 m3 of 79°C water were injected. After 57 days of storage, production began with a dual recovery well system. Due to the dominating effect of nonhomogeneities, the dual well system did not work particularly well, and a recovery factor of 0.42 was achieved. The degree of aquifer heterogeneity at the location of the present experiments was not apparent during previous experiments at a location only 109 m away, although pumping tests indicated similar values of transmissivity. Therefore aquifers with the same transmissivity can behave quite differently in a thermal sense. Heat conduction to the upper aquitard was a major energy loss mechanism. Water sample analyses indicated that there were no important changes in the chemical constituents during the third set of experiments. There was a 19% increase in total dissolved solids. At the end of injection, the land surface near the injection well had risen 1.39 cm with respect to bench marks located 70 m away

    Couplings of self-dual tensor multiplet in six dimensions

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    The (1,0) supersymmetry in six dimensions admits a tensor multiplet which contains a second-rank antisymmetric tensor field with a self-dual field strength and a dilaton. We describe the fully supersymmetric coupling of this multiplet to Yang-Mills multiplet, in the absence of supergravity. The self-duality equation for the tensor field involves a Chern-Simons modified field strength, the gauge fermions, and an arbitrary dimensionful parameter.Comment: 17 pages, latex, no figure

    Penrose limits, supergravity and brane dynamics

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    We investigate the Penrose limits of classical string and M-theory backgrounds. We prove that the number of (super)symmetries of a supergravity background never decreases in the limit. We classify all the possible Penrose limits of AdS x S spacetimes and of supergravity brane solutions. We also present the Penrose limits of various other solutions: intersecting branes, supersymmetric black holes and strings in diverse dimensions, and cosmological models. We explore the Penrose limit of an isometrically embedded spacetime and find a generalisation to spaces with more than one time. Finally, we show that the Penrose limit is a large tension limit for all branes including those with fields of Born--Infeld type.Comment: 67 page

    Isometric Embedding of BPS Branes in Flat Spaces with Two Times

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    We show how non-near horizon p-brane theories can be obtained from two embedding constraints in a flat higher dimensional space with 2 time directions. In particular this includes the construction of D3 branes from a flat 12-dimensional action, and M2 and M5 branes from 13 dimensions. The worldvolume actions are determined by constant forms in the higher dimension, reduced to the usual expressions by Lagrange multipliers. The formulation affords insight in the global aspects of the spacetime geometries and makes contact with recent work on two-time physics.Comment: 29 pages, 10 figures, Latex using epsf.sty and here.sty; v2: reference added and some small correction

    The current polarization rectification of the integer quantized Hall effect

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    We report on our theoretical investigation considering the widths of quantized Hall plateaus (QHPs) depending on the density asymmetry induced by the large current within the out-of-linear response regime. We solve the Schrodinger equation within the Hartree type mean field approximation using Thomas Fermi Poisson nonlinear screening theory. We observe that the two dimensional electron system splits into compressible and incompressible regions for certain magnetic field intervals, where the Hall resistance is quantized and the longitudinal resistance vanishes, if an external current is imposed. We found that the strong current imposed, induces an asymmetry on the IS width depending linearly on the current intensity.Comment: 5 pages, 2 figur
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