Exploring teacher pedagogy, stages of concern and accessibility as determinants of technology adoption

© 2017 Association for Information Technology in Teacher Education. This research examines how the pedagogical orientations of teachers affect technology adoption in the classroom. At the same time, the authors account for the stage of concern that teachers are experiencing regarding the use of the technology, their access to the technology and the level of schooling at which they teach.The authors’ investigation of these factors occurs in the context of a contemporary technology, the interactive whiteboard (IWB), in Australian schools. A structural equation model was estimated using a reflective measure of technology usage with antecedents in the form of pedagogical-oriented beliefs and best–worst scaling derived scores for a teacher’s stage of concern regarding IWBs. Teachers with constructivist-oriented pedagogical beliefs were significantly more likely to use IWBs than transmission-oriented teachers. However, the strongest determinant of usage was whether the technology is immediately accessible or not

Looking for imprints of the first stellar generations in metal-poor bulge field stars

© 2016 ESO. Context. Efforts to look for signatures of the first stars have concentrated on metal-poor halo objects. However, the low end of the bulge metallicity distribution has been shown to host some of the oldest objects in the Milky Way and hence this Galactic component potentially offers interesting targets to look at imprints of the first stellar generations. As a pilot project, we selected bulge field stars already identified in the ARGOS survey as having [Fe/H] 1 and oversolar [α/Fe] ratios, and we used FLAMES-UVES to obtain detailed abundances of key elements that are believed to reveal imprints of the first stellar generations. Aims. The main purpose of this study is to analyse selected ARGOS stars using new high-resolution (R ∼ 45 000) and high-signal-tonoise (S=N > 100) spectra. We aim to derive their stellar parameters and elemental ratios, in particular the abundances of C, N, the α-elements O, Mg, Si, Ca, and Ti, the odd-Z elements Na and Al, the neutron-capture s-process dominated elements Y, Zr, La, and Ba, and the r-element Eu. Methods. High-resolution spectra of five field giant stars were obtained at the 8 m VLT UT2-Kueyen telescope with the UVES spectrograph in FLAMES-UVES configuration. Spectroscopic parameters were derived based on the excitation and ionization equilibrium of Fe i and Fe ii. The abundance analysis was performed with a MARCS LTE spherical model atmosphere grid and the Turbospectrum spectrum synthesis code. Results.We confirm that the analysed stars are moderately metal-poor (-1:04≤[Fe/H]≤-0:43), non-carbon-enhanced (non-CEMP) with [C/Fe] ≤+0:2, and α-enhanced.We find that our three most metal-poor stars are nitrogen enhanced. The α-enhancement suggests that these stars were formed from a gas enriched by core-collapse supernovae, and that the values are in agreement with results in the literature for bulge stars in the same metallicity range. No abundance anomalies (Na-O, Al-O, Al-Mg anti-correlations) were detected in our sample. The heavy elements Y, Zr, Ba, La, and Eu also exhibit oversolar abundances. Three out of the five stars analysed here show slightly enhanced [Y/Ba] ratios similar to those found in other metal-poor bulge globular clusters (NGC 6522 and M 62). Conclusions. This sample shows enhancement in the first-to-second peak abundance ratios of heavy elements, as well as dominantly s-process element excesses. This can be explained by different nucleosynthesis scenarios: (a) the main r-process plus extra mechanisms, such as the weak r-process; (b) mass transfer from asymptotic giant branch stars in binary systems; (c) an early generation of fast-rotating massive stars. Larger samples of moderately metal-poor bulge stars, with detailed chemical abundances, are needed to better constrain the source of dominantly s-process elements in the early Universe

Informal Action—Adjudication—Rule Making: Some Recent Developments in Federal Administrative Law

Direct energy consumption of ICT hardware is only “half the story.” In order to get the “whole story,” energy consumption during the entire life cycle has to be taken into account. This chapter is a first step toward a more comprehensive picture, showing the “grey energy” (i.e., the overall energy requirements) as well as the releases (into air, water, and soil) during the entire life cycle of exemplary ICT hardware devices by applying the life cycle assessment method. The examples calculated show that a focus on direct energy consumption alone fails to take account of relevant parts of the total energy consumption of ICT hardware as well as the relevance of the production phase. As a general tendency, the production phase is more and more important the smaller (and the more energy-efficient) the devices are. When in use, a tablet computer is much more energy-efficient than a desktop computer system with its various components, so its production phase has a much greater relative importance. Accordingly, the impacts due to data transfer when using Internet services are also increasingly relevant the smaller the end-user device is, reaching up to more than 90 % of the overall impact when using a tablet computer.QC 20140825</p

Buildings LCA and digitalization: Designers\u27 toolbox based on a survey

In a context of digitalization and increasing quality requirements, the building sector is facing an increasing level of complexity regarding its design process. This results in a growing number of involved actors from different domains, a multitude of tasks to be completed and a higher degree of needed expertise. New buildings are also required to reach higher performances in terms of environmental quality. To that regard, the exploitation of the full potential of digital tools can facilitate the integration of environmental aspects in the planning process, limit productivity shortcomings and reduce environmental impacts, which can result from an unaware decision making. Building environmental assessment can be performed through several Life Cycle Assessment (LCA)-based tools. “Pure calculation” tools quantify final buildings\u27 environmental potential, while “complex tools” additionally support decision making during the planning process. It is often difficult to choose the best suitable tool, which strongly depends on the user\u27s needs. Within the IEA EBC Annex 72, a survey was realized with the main objective of creating a comprehensive overview of the existing tools dedicated to buildings LCA. The questionnaire included the usability, functionality, compliance, data reliability and interoperability of the analysed tools. Lastly, based on the survey outcomes and their critical assessment, a procedure for the identification and selection of a tool has been proposed based on user\u27s needs. As a result, this work outlines main features of currently available building LCA tools, for which there is a harmonized status in terms of usability and overall applied LCA methodology. Despite the need for more automatized workflows, tools\u27 embedding is mostly not yet applicable in system chains or limited to a restricted number of tools

Final report : LDRD project 79824 carbon nanotube sorting via DNA-directed self-assembly.

Single-wall carbon nanotubes (SWNTs) have shown great promise in novel applications in molecular electronics, biohazard detection, and composite materials. Commercially synthesized nanotubes exhibit a wide dispersion of geometries and conductivities, and tend to aggregate. Hence the key to using these materials is the ability to solubilize and sort carbon nanotubes according to their geometric/electronic properties. One of the most effective dispersants is single-stranded DNA (ssDNA), but there are many outstanding questions regarding the interaction between nucleic acids and SWNTs. In this work we focus on the interactions of SWNTs with single monomers of nucleic acids, as a first step to answering these outstanding questions. We use atomistic molecular dynamics simulations to calculate the binding energy of six different nucleotide monophosphates (NMPs) to a (6,0) single-wall carbon nanotube in aqueous solution. We find that the binding energies are generally favorable, of the order of a few kcal/mol. The binding energies of the different NMPs were very similar in salt solution, whereas we found a range of binding energies for NMPs in pure water. The binding energies are sensitive to the details of the association of the sodium ions with the phosphate groups and also to the average conformations of the nucleotides. We use electronic structure (Density Functional Theory (DFT) and Moller-Plesset second order perturbation to uncorrelated Hartree Fock theory (MP2)) methods to complement the classical force field study. With judicious choices of DFT exchange correlation functionals, we find that DFT, MP2, and classical force field predictions are in qualitative and even quantitative agreement; all three methods should give reliable and valid predictions. However, in one important case, the interactions between ions and metallic carbon nanotubes--the SWNT polarization-induced affinity for ions, neglected in most classical force field studies, is found to be extremely large (on the order of electron volts) and may have important consequences for various SWNT applications. Finally, the adsorption of NMPs onto single-walled carbon nanotubes were studied experimentally. The nanotubes were sonicated in the presence of the nucleotides at various weight fractions and centrifuged before examining the ultraviolet absorbance of the resulting supernatant. A distinct Langmuir adsorption isotherm was obtained for each nucleotide. All of the nucleotides differ in their saturation value as well as their initial slope, which we attribute to differences both in nucleotide structure and in the binding ability of different types or clusters of tubes. Results from this simple system provide insights toward development of dispersion and separation methods for nanotubes: strongly binding nucleotides are likely to help disperse, whereas weaker ones may provide selectivity that may be beneficial to a separation process

Vertebral osteomyelitis with <i>Campylobacter jejuni</i> – a case report and review of the literature of a very rare disease

Infections with Campylobacter species mainly cause gastrointestinal disease and are usually self-limiting. Systemic complications such as bacteremia and osteoarticular infections are rare. Here we report a very rare case of a vertebral osteomyelitis due to C. jejuni, and we reviewed the literature for similar cases, identifying six other cases. Therapy should be guided on resistance testing if available due to emerging resistance rates, especially to fluoroquinolones. Azithromycin may be a treatment option for C. jejuni spondylodiscitis.</p

Abundances of carbon-enhanced metal-poor stars as constraints on their formation

Reproduced with permission from Astronomy & Astrophysics. © 2018 ESO.Context. An increasing fraction of carbon-enhanced metal-poor (CEMP) stars is found as their iron abundance, [Fe/H], decreases below [Fe/H] =−2.0. The CEMP-s stars have the highest absolute carbon abundances, [C/H], and are thought to owe their enrichment in carbon and the slow neutron-capture (s-process) elements to mass transfer from a former asymptotic giant branch (AGB) binary companion. The most Fe-poor CEMP stars are normally single, exhibit somewhat lower [C/H] than CEMP-s stars, but show no s-process element enhancement (CEMP-no stars). Abundance determinations of CNO offer clues to their formation sites. Aims. Our aim is to use the medium-resolution spectrograph X-Shooter/VLT to determine stellar parameters and abundances for C, N, Sr, and Ba in several classes of CEMP stars in order to further classify and constrain the astrophysical formation sites of these stars. Methods. Atmospheric parameters for our programme stars were estimated from a combination of V−K photometry, model isochrone fits, and estimates from a modified version of the SDSS/SEGUE spectroscopic pipeline. We then used X-Shooter spectra in conjunction with the 1D local thermodynamic equilibrium spectrum synthesis code MOOG, 1D ATLAS9 atmosphere models to derive stellar abundances, and, where possible, isotopic 12C/13C ratios. Results. Abundances (or limits) of C, N, Sr, and Ba are derived for a sample of 27 faint metal-poor stars for which the X-Shooter spectra have sufficient signal-to-noise ratios (S/N). These moderate resolution, low S/N (~10−40) spectra prove sufficient to perform limited chemical tagging and enable assignment of these stars into the CEMP subclasses (CEMP-s and CEMP-no). According to the derived abundances, 17 of our sample stars are CEMP-s and 3 are CEMP-no, while the remaining 7 are carbon-normal. For four CEMP stars, the subclassification remains uncertain, and two of them may be pulsating AGB stars. Conclusions. The derived stellar abundances trace the formation processes and sites of our sample stars. The [C/N] abundance ratio is useful for identifying stars with chemical compositions unaffected by internal mixing, and the [Sr/Ba] abundance ratio allows us to distinguish between CEMP-s stars with AGB progenitors and the CEMP-no stars. Suggested formation sites for the latter include faint supernovae with mixing and fallback and/or primordial, rapidly-rotating, massive stars (spinstars). X-Shooter spectra have thus proved to be valuable tools in the continued search for their origin.Peer reviewe

Curved Tails in Polymerization-Based Bacterial Motility

The curved actin ``comet-tail'' of the bacterium Listeria monocytogenes is a visually striking signature of actin polymerization-based motility. Similar actin tails are associated with Shigella flexneri, spotted-fever Rickettsiae, the Vaccinia virus, and vesicles and microspheres in related in vitro systems. We show that the torque required to produce the curvature in the tail can arise from randomly placed actin filaments pushing the bacterium or particle. We find that the curvature magnitude determines the number of actively pushing filaments, independent of viscosity and of the molecular details of force generation. The variation of the curvature with time can be used to infer the dynamics of actin filaments at the bacterial surface.Comment: 8 pages, 2 figures, Latex2

A Gamma-Herpesvirus Glycoprotein Complex Manipulates Actin to Promote Viral Spread

Viruses lack self-propulsion. To move in multi-cellular hosts they must therefore manipulate infected cells. Herpesviruses provide an archetype for many aspects of host manipulation, but only for alpha-herpesviruses in is there much information about they move. Other herpesviruses are not necessarily the same. Here we show that Murine gamma-herpesvirus-68 (MHV-68) induces the outgrowth of long, branched plasma membrane fronds to create an intercellular network for virion traffic. The fronds were actin-based and RhoA-dependent. Time-lapse imaging showed that the infected cell surface became highly motile and that virions moved on the fronds. This plasma membrane remodelling was driven by the cytoplasmic tail of gp48, a MHV-68 glycoprotein previously implicated in intercellular viral spread. The MHV-68 ORF58 was also required, but its role was simply transporting gp48 to the plasma membrane, since a gp48 mutant exported without ORF58 did not require ORF58 to form membrane fronds either. Together, gp48/ORF58 were sufficient to induce fronds in transfected cells, as were the homologous BDLF2/BMRF2 of Epstein-Barr virus. Gp48/ORF58 therefore represents a conserved module by which gamma-herpesviruses rearrange cellular actin to increase intercellular contacts and thereby promote their spread

The 20Ne(d,p)21Ne transfer reaction in relation to the s-process abundances

A study of the 20Ne(d,p)21Ne transfer reaction was performed using the Quadrupole Dipole Dipole Dipole (Q3D) magnetic spectrograph in Garching, Germany. The experiment probed excitation energies in 21Ne ranging from 6.9 MeV to 8.5 MeV. The aim was to investigate the spectroscopic information of 21Ne within the Gamow window of core helium burning in massive stars. Further information in this region will help reduce the uncertainties on the extrapolation down to Gamow window cross sections of the 17O(α,γ)21Ne reaction. In low metallicity stars, this reaction has a direct impact on s-process abundances by determining the fate of 16O as either a neutron poison or a neutron absorber. The experiment used a 22-MeV deuteron beam, with intensities varying from 0.5-1 μA, and an implanted target of 20Ne of 7 μg/cm2 in 40 μg/cm2 carbon foils. Sixteen 21Ne peaks have been identified in the Ex = 6.9-8.5 MeV range, of which only thirteen peaks correspond to known states. Only the previously-known Ex = 7.960 MeV state was observed within the Gamow window