372 research outputs found
Nothing moves a surface: vacancy mediated surface diffusion
We report scanning tunneling microscopy observations, which imply that all
atoms in a close-packed copper surface move frequently, even at room
temperature. Using a low density of embedded indium `tracer' atoms, we
visualize the diffusive motion of surface atoms. Surprisingly, the indium atoms
seem to make concerted, long jumps. Responsible for this motion is an ultra-low
density of surface vacancies, diffusing rapidly within the surface. This
interpretation is supported by a detailed analysis of the displacement
distribution of the indium atoms, which reveals a shape characteristic for the
vacancy mediated diffusion mechanism that we propose.Comment: 4 pages; for associated movie, see
http://www-lion.leidenuniv.nl/sections/cm/groups/interface/projects/therm
Mapping Patent Classifications: Portfolio and Statistical Analysis, and the Comparison of Strengths and Weaknesses
The Cooperative Patent Classifications (CPC) jointly developed by the
European and US Patent Offices provide a new basis for mapping and portfolio
analysis. This update provides an occasion for rethinking the parameter
choices. The new maps are significantly different from previous ones, although
this may not always be obvious on visual inspection. Since these maps are
statistical constructs based on index terms, their quality--as different from
utility--can only be controlled discursively. We provide nested maps online and
a routine for portfolio overlays and further statistical analysis. We add a new
tool for "difference maps" which is illustrated by comparing the portfolios of
patents granted to Novartis and MSD in 2016.Comment: Scientometrics 112(3) (2017) 1573-1591;
http://link.springer.com/article/10.1007/s11192-017-2449-
World citation and collaboration networks: uncovering the role of geography in science
Modern information and communication technologies, especially the Internet,
have diminished the role of spatial distances and territorial boundaries on the
access and transmissibility of information. This has enabled scientists for
closer collaboration and internationalization. Nevertheless, geography remains
an important factor affecting the dynamics of science. Here we present a
systematic analysis of citation and collaboration networks between cities and
countries, by assigning papers to the geographic locations of their authors'
affiliations. The citation flows as well as the collaboration strengths between
cities decrease with the distance between them and follow gravity laws. In
addition, the total research impact of a country grows linearly with the amount
of national funding for research & development. However, the average impact
reveals a peculiar threshold effect: the scientific output of a country may
reach an impact larger than the world average only if the country invests more
than about 100,000 USD per researcher annually.Comment: Published version. 9 pages, 5 figures + Appendix, The world citation
and collaboration networks at both city and country level are available at
http://becs.aalto.fi/~rajkp/datasets.htm
Communities and patterns of scientific collaboration in Business and Management
This is the author's accepted version of this article deposited at arXiv (arXiv:1006.1788v2 [physics.soc-ph]) and subsequently published in Scientometrics October 2011, Volume 89, Issue 1, pp 381-396. The final publication is available at link.springer.com http://link.springer.com/article/10.1007%2Fs11192-011-0439-1Author's note: 17 pages. To appear in special edition of Scientometrics. Abstract on arXiv meta-data a shorter version of abstract on actual paper (both in journal and arXiv full pape
Deep learning-based post-processing of real-time MRI to assess and quantify dynamic wrist movement in health and disease
While morphologic magnetic resonance imaging (MRI) is the imaging modality of choice for the evaluation of ligamentous wrist injuries, it is merely static and incapable of diagnosing dynamic wrist instability. Based on real-time MRI and algorithm-based image post-processing in terms of convolutional neural networks (CNNs), this study aims to develop and validate an automatic technique to quantify wrist movement. A total of 56 bilateral wrists (28 healthy volunteers) were imaged during continuous and alternating maximum ulnar and radial abduction. Following CNN-based automatic segmentations of carpal bone contours, scapholunate and lunotriquetral gap widths were quantified based on dedicated algorithms and as a function of wrist position. Automatic segmentations were in excellent agreement with manual reference segmentations performed by two radiologists as indicated by Dice similarity coefficients of 0.96 ± 0.02 and consistent and unskewed Bland–Altman plots. Clinical applicability of the framework was assessed in a patient with diagnosed scapholunate ligament injury. Considerable increases in scapholunate gap widths across the range-of-motion were found. In conclusion, the combination of real-time wrist MRI and the present framework provides a powerful diagnostic tool for dynamic assessment of wrist function and, if confirmed in clinical trials, dynamic carpal instability that may elude static assessment using clinical-standard imaging modalities
Temperature dependent surface relaxations of Ag(111)
The temperature dependent surface relaxation of Ag(111) is calculated by
density-functional theory. At a given temperature, the equilibrium geometry is
determined by minimizing the Helmholtz free energy within the quasiharmonic
approximation. To this end, phonon dispersions all over the Brillouin zone are
determined from density-functional perturbation theory. We find that the
top-layer relaxation of Ag(111) changes from an inward contraction (-0.8 %) to
an outward expansion (+6.3%) as the temperature increases from T=0 K to 1150 K,
in agreement with experimental findings. Also the calculated surface phonon
dispersion curves at room temperature are in good agreement with helium
scattering measurements. The mechanism driving this surface expansion is
analyzed.Comment: 6 pages, 7 figures, submitted to Phys. Rev. B (May 1998). Other
related publications can be found at
http://www.rz-berlin.mpg.de/th/paper.htm
Community structure and patterns of scientific collaboration in Business and Management
This is the author's accepted version of this article deposited at arXiv (arXiv:1006.1788v2 [physics.soc-ph]) and subsequently published in Scientometrics October 2011, Volume 89, Issue 1, pp 381-396. The final publication is available at link.springer.com http://link.springer.com/article/10.1007%2Fs11192-011-0439-1Author's note: 17 pages. To appear in special edition of Scientometrics. Abstract on arXiv meta-data a shorter version of abstract on actual paper (both in journal and arXiv full pape
Spatial interactions in agent-based modeling
Agent Based Modeling (ABM) has become a widespread approach to model complex
interactions. In this chapter after briefly summarizing some features of ABM
the different approaches in modeling spatial interactions are discussed.
It is stressed that agents can interact either indirectly through a shared
environment and/or directly with each other. In such an approach, higher-order
variables such as commodity prices, population dynamics or even institutions,
are not exogenously specified but instead are seen as the results of
interactions. It is highlighted in the chapter that the understanding of
patterns emerging from such spatial interaction between agents is a key problem
as much as their description through analytical or simulation means.
The chapter reviews different approaches for modeling agents' behavior,
taking into account either explicit spatial (lattice based) structures or
networks. Some emphasis is placed on recent ABM as applied to the description
of the dynamics of the geographical distribution of economic activities, - out
of equilibrium. The Eurace@Unibi Model, an agent-based macroeconomic model with
spatial structure, is used to illustrate the potential of such an approach for
spatial policy analysis.Comment: 26 pages, 5 figures, 105 references; a chapter prepared for the book
"Complexity and Geographical Economics - Topics and Tools", P. Commendatore,
S.S. Kayam and I. Kubin, Eds. (Springer, in press, 2014
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