Influence of polysaccharides on cement hydration

4 pagesInternational audienceThis paper is about the influence of polysaccharides on cement hydration. Three polysaccharides were studied: a cellulose ether (CE), a starch ether (SE) and a dextrin (YD). In a concentrated media as well as in a dilute media, admixture CE only revealed a slight effect on cement hydration. Portlandite and ettringite formation and gypsum consumption were slowed down by SE adjunction. Admixture YD induced an acceleration of ettringite formation as well as gypsum consumption whereas portiandite formation was blocked by this compound

Environmental characterisation of retification process by-products (liquid and gaseous wastes)

6th International Symposium “Environment and Wood Preservation” Cannes-Mandelieu, France 7-8 February 2005 14 pagesIn order to reduce environmental risks during the service life of the treated wood and to find new alternative developments on the durability of wood, some research and technology development have been made on thermal treatment. The retification process is one of these processes. The retification process induces chemical modification of the lignin and cellulosic components and modifies the intrinsic properties of wood : efficient increases the durability against fungi and insects, increases of the dimensional stability, decrease of the mechanical properties. The interest of this process is to reduce the environmental impact during the service life. In order to confirm the high interest of this process for the reduction of the environmental impact, an environmental characterisation of wastes on pilot plant have been carried out. Chemical analysis on gaseous and liquid effluents have been performed. An energetic assessment has been realised. The results indicate the high interest of this process in terms of possible biodegradable wastes and chemical valorisation interest, interest on energetic consumption in comparison with other wood processing treatment, interest on using retification treated wood in flooring according to indoor air quality requirements

The impact of surgical delay on resectability of colorectal cancer: An international prospective cohort study

AIM: The SARS-CoV-2 pandemic has provided a unique opportunity to explore the impact of surgical delays on cancer resectability. This study aimed to compare resectability for colorectal cancer patients undergoing delayed versus non-delayed surgery. METHODS: This was an international prospective cohort study of consecutive colorectal cancer patients with a decision for curative surgery (January-April 2020). Surgical delay was defined as an operation taking place more than 4 weeks after treatment decision, in a patient who did not receive neoadjuvant therapy. A subgroup analysis explored the effects of delay in elective patients only. The impact of longer delays was explored in a sensitivity analysis. The primary outcome was complete resection, defined as curative resection with an R0 margin. RESULTS: Overall, 5453 patients from 304 hospitals in 47 countries were included, of whom 6.6% (358/5453) did not receive their planned operation. Of the 4304 operated patients without neoadjuvant therapy, 40.5% (1744/4304) were delayed beyond 4 weeks. Delayed patients were more likely to be older, men, more comorbid, have higher body mass index and have rectal cancer and early stage disease. Delayed patients had higher unadjusted rates of complete resection (93.7% vs. 91.9%, P = 0.032) and lower rates of emergency surgery (4.5% vs. 22.5%, P < 0.001). After adjustment, delay was not associated with a lower rate of complete resection (OR 1.18, 95% CI 0.90-1.55, P = 0.224), which was consistent in elective patients only (OR 0.94, 95% CI 0.69-1.27, P = 0.672). Longer delays were not associated with poorer outcomes. CONCLUSION: One in 15 colorectal cancer patients did not receive their planned operation during the first wave of COVID-19. Surgical delay did not appear to compromise resectability, raising the hypothesis that any reduction in long-term survival attributable to delays is likely to be due to micro-metastatic disease

Obtention de films plastiques hydrophobes à partir de polysaccharides contenus dans des co-produits agricoles

TOULOUSE3-BU Sciences (315552104) / SudocST ETIENNE-ENS des Mines (422182304) / SudocSudocFranceF

Evaluation of axial impregnation as an alternative to classical wood vacuum pressure impregnation method

The evolution of laws on the use of biocide products has led to important changes in the field of wood preservation leading to an increasing interest for non “biocidal treatments” like thermal or chemical modifications. While thermal modifications become more and more common on industrial scale,development of chemical modifications progresses slowly. One reason for the challenges encountered is probably the difficulty to use actual vacuum pressure plant to impregnate wood with solutions of reactive chemicals aimed to react with or within the wood. In this context, the presented research focuses on a new alternative called axial impregnation, derived from Boucherie process, for impregnation of treatable non durable hardwood species. This process consists of low-pressure impregnation of green wood logs through its lower extremity with treatment solution transiting via natural pathways of vessels. In order to evaluate the feasibility of the method, logs of different hardwood species were impregnated with a copper based preservative solution and the distribution of copper within the wood was determined. Results indicated that treatable wood species like beech, hornbeam and birch can be easily and homogeneously treated using axial impregnation method, while ash known for its weak impregnability remained untreated

New insights into wood and cement interaction

26 pagesInternational audienceThis work deals with the influence of poplar extractives and poplar alkaline degradation products on the hydration of cement. The wood chemical composition was characterized to determine the impact of soft alkaline conditions on wood fiber. Some of the constituents were hydrolyzed and converted into carboxylic acids, which were identified and quantified. Monitoring by electrical conductivity clearly showed that wood extractives are less effective than wood alkaline degradation products in inhibiting the hydration of cemen

Evaluation of axial impregnation as an alternative to classical wood vacuum pressure impregnation method

International audienceThe evolution of laws on the use of biocide products has led to important changes in the field of wood preservation leading to an increasing interest for non ``biocidal treatments'' like thermal or chemical modifications. While thermal modifications become more and more common on industrial scale, development of chemical modifications progresses slowly. One reason for the challenges encountered is probably the difficulty to use actual vacuum pressure plant to impregnate wood with solutions of reactive chemicals aimed to react with or within the wood. In this context, the presented research focuses on a new alternative called axial impregnation, derived from Boucherie process, for impregnation of treatable non durable hardwood species. This process consists of low-pressure impregnation of green wood logs through its lower extremity with treatment solution transiting via natural pathways of vessels. In order to evaluate the feasibility of the method, logs of different hardwood species were impregnated with a copper based preservative solution and the distribution of copper within the wood was determined. Results indicated that treatable wood species like beech, hornbeam and birch can be easily and homogeneously treated using axial impregnation method, while ash known for its weak impregnability remained untreated