A long-term record of early to mid-Paleozoic marine redox change

The extent to which Paleozoic oceans differed from Neoproterozoic oceans and the causal relationship between biological evolution and changing environmental conditions are heavily debated. Here, we report a nearly continuous record of seafloor redox change from the deep-water upper Cambrian to Middle Devonian Road River Group of Yukon, Canada. Bottom waters were largely anoxic in the Richardson trough during the entirety of Road River Group deposition, while independent evidence from iron speciation and Mo/U ratios show that the biogeochemical nature of anoxia changed through time. Both in Yukon and globally, Ordovician through Early Devonian anoxic waters were broadly ferruginous (nonsulfidic), with a transition toward more euxinic (sulfidic) conditions in the mid–Early Devonian (Pragian), coincident with the early diversification of vascular plants and disappearance of graptolites. This ~80-million-year interval of the Paleozoic characterized by widespread ferruginous bottom waters represents a persistence of Neoproterozoic-like marine redox conditions well into the Phanerozoic

Lithogeochemical characterization of the Middle-Upper Devonian Road River Group, Canol and Imperial formations on Trail River, east Richardson Mountains, Yukon: age constraints and a depositional model for fine-grained strata in the Lower Paleozoic Richardson trough

Lithogeochemical characterization of the Road River Group and Canol and Imperial formations as exposed at an outcrop on Trail River, eastern Richardson Mountains, documents the evolution of a Laurentian-margin basin during the latest Eifelian through middle Frasnian stages. δ13Corg stable isotope data correlated to conodont-constrained global isotopic curves indicates deposition of the section from ≥387.7 to ≤376.7Ma. The uppermost Road River Group is latest Eifelian and older in age (≥387.7 Ma) and is primarily calcareous/dolomitic shale and mudstone representing a slope environment below a carbonate platform that experienced cyclical turbidity current deposition. A 2.3m, metalliferous and concretionary unit lies transitionally between the Road River Group and Canol Formation and is herein designated as an informal, conformable, lithologic unit called the Road River - Canol transition zone (RCTZ) which records 4.5Ma of condensed sediment deposition during the Givetian stage (387.7-383.2Ma). The Canol Formation is confined to the latest Givetian to middle Frasnian stages (383.2-376.7Ma) and consists of rhythmically bedded, biogenically sourced, siliceous shale and chert that was deposited in an anoxic (and likely euxinic) to oxic basin that evolved from moderately to strongly hydrographically restricted over time. The lowermost Imperial Formation is a siliciclastic mudstone which documents turbidity current deposition in oxic bottom water conditions in the late Frasnian (≤376.7Ma). Interpretation of lithofacies, whole rock geochemistry, mineralogy, and total organic content enable the section to be grouped into eight lithochemozones that record a 1st order late-stage sea-level transgression (Road River Group and RCTZ), highstand (lower Canol Formation) and early-stage regression (upper Canol Formation) followed by continued falling stage sea-level conditions with strong detrital influence from a continental collision in the high Arctic (Imperial Formation).The accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author

Summary of field activities in the western Liard Basin, British Columbia

International audienceThe second and final year of a regional bedrock mapping program within the Toad River map area (NTS 094N) was completed in 2012. The program will result in three-100 000 scale maps of the northwest, northeast and southeast quadrants of 094N and with four 1:50 000 scale maps covering the southwest quadrant. Surface samples were also collected for Rock Eval™, reflective light thermal maturity and apatite fission-track analysis. Cuttings from several petroleum wells in the map area were also sampled for Rock Eval analysis and vitrinite reflectance. Composite sections of the Besa River Formation were measured in the southern Caribou Range and along the Alaska Highway, south of Stone Mountain. Approximately 170 m of the Besa River Formation were measured in three separate sections in the southern Caribou Range. Lithological, gamma-ray spectrometry and lithogeochemical data are similar to those observed in other sections of the formation, suggesting similar depositional conditions within the western Liard Basin. Changes in abundances of several trace elements, particularly, V, Mo, Ba and P, suggest variations in redox conditions during the deposition of the formation. Radiolarian and conodont fragments from the upper part of the section in the Caribou Range indicate a mid-Tournaisian age. Characteristics of the lower Besa River Formation observed along the Alaska Highway south of Stone Mountain are similar to the Evie member of the Horn River Formation

The Road River Group of northern Yukon, Canada: early Paleozoic deep-water sedimentation within the Great American Carbonate Bank

Cambrian–Devonian sedimentary rocks of the northern Canadian Cordillera record both the establishment and demise of the Great American Carbonate Bank, a widespread carbonate platform system that fringed the ancestral continental margins of North America (Laurentia). Here, we present a new examination of the deep-water Road River Group of the Richardson Mountains, Yukon, Canada, which was deposited in an intra-platformal embayment or seaway within the Great American Carbonate Bank called the Richardson trough. Eleven detailed stratigraphic sections through the Road River Group along the upper canyon of the Peel River are compiled and integrated with geological mapping, facies analysis, carbonate and organic carbon isotope chemostratigraphy, and new biostratigraphic results to formalize four new formations within the type area of the Richardson Mountains (Cronin, Mount Hare, Tetlit, and Vittrekwa). We recognize nine mixed carbonate and siliciclastic deep-water facies associations in the Road River Group and propose these strata were deposited in basin-floor to slope environments. New biostratigraphic data suggest the Road River Group spans the late Cambrian (Furongian) – Middle Devonian (Eifelian), and new chemostratigraphic data record multiple global carbon isotopic events, including the late Cambrian Steptoean positive carbon isotope excursion, the Late Ordovician Guttenberg excursion, the Silurian Aeronian, Valgu, Mulde (mid-Homerian), Ireviken (early Sheinwoodian), and Lau excursions, and the Early Devonian Klonk excursion. Together, these new data not only help clarify nomenclatural debate centered around the Road River Group, but also provide critical new sedimentological, biostratigraphic, and isotopic data for these widely distributed rocks of the northern Canadian Cordillera.The accepted manuscript in pdf format is listed with the files at the bottom of this page. The presentation of the authors' names and (or) special characters in the title of the manuscript may differ slightly between what is listed on this page and what is listed in the pdf file of the accepted manuscript; that in the pdf file of the accepted manuscript is what was submitted by the author

The Sedimentary Geochemistry and Paleoenvironments Project.

Authors thank the donors of The American Chemical Society Petroleum Research Fund for partial support of SGP website development (61017-ND2). EAS is funded by National Science Foundation grant (NSF) EAR-1922966. BGS authors (JE, PW) publish with permission of the Executive Director of the British Geological Survey, UKRI.Publisher PDFPeer reviewe