13 research outputs found

    La vie de Garnisson

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    Obras completas de Buffon

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    Son 341 h. de lam. col. y 2 h. de lam. plegContiene : Discursos preliminares y Teoria de la tierra (6 v.) -- Épocas de la naturaleza (2 v.) -- Historia de los animales (3 v.) -- Historia del hombre (5 v.) -- Cuadrúpedos (14 v.) -- Aves (19 v.) -- Mineralogía (3 v.) -- Suplemento de Cuvier (6 v.) -- Tablas e índice

    Successive light-induced two electron transfers in a Ru–Fe supramolecular assembly: from Ru–Fe(II)–OH2 to Ru–Fe(IV)–oxo

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    International audienceIn the present work we describe the synthesis and study of a RuII–FeII chromophore–catalyst assembly designed to perform the light-induced activation of an iron bound water molecule and subsequent photo-driven oxidation of a substrate. Using a series of spectroscopic techniques, we demonstrate that excitation of the chromophore unit with 450 nm light, in the presence of a sacrificial electron acceptor, triggers a cascade of electron transfers leading to the formation of a high valent iron(IV)–oxo center from an iron(II)-bound water molecule. The activity of this catalytic center is illustrated by the oxidation of triphenyl phosphine
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