877 research outputs found
Chiral probe development for circularly polarised luminescence: comparative study of structural factors determining the degree of induced CPL with four heptacoordinate europium(III) complexes
A series of bright, europium(III) complexes has been prepared based on an achiral heptadentate triazacyclononane ligand bearing two strongly absorbing, coordinated aralkynyl pyridyl moieties. The binding of chiral carboxylates, including α-hydroxy acids such as lactate and mandelate, has been monitored by emission spectroscopy and is signalled by the switching on of strong circularly polarised emission. In each case, an R-chiral carboxylate gave rise to emission typical of a Î complex, most clearly shown in the form of the ÎJ = 4 transition manifold around 700 nm. Variations in the sign and magnitude of the CPL allow the enantiomeric purity and absolute configuration of the acid to be assessed in a sample. Analysis of the relative energies of the parent aqua complexes and their stereoisomeric adducts has been aided by lifetime measurements and density functional theory calculations
Naturalness and Higgs Decays in the MSSM with a Singlet
The simplest extension of the supersymmetric standard model - the addition of
one singlet superfield - can have a profound impact on the Higgs and its
decays. We perform a general operator analysis of this scenario, focusing on
the phenomenologically distinct scenarios that can arise, and not restricting
the scope to the narrow framework of the NMSSM. We reexamine decays to four b
quarks and four tau's, finding that they are still generally viable, but at the
edge of LEP limits. We find a broad set of Higgs decay modes, some new,
including those with four gluon final states, as well as more general six and
eight parton final states. We find the phenomenology of these scenarios is
dramatically impacted by operators typically ignored, specifically those
arising from D-terms in the hidden sector, and those arising from weak-scale
colored fields. In addition to sensitivity of m_Z, there are potential tunings
of other aspects of the spectrum. In spite of this, these models can be very
natural, with light stops and a Higgs as light as 82 GeV. These scenarios
motivate further analyses of LEP data as well as studies of the detection
capabilities of future colliders to the new decay channels presented.Comment: 3 figures, 1 appendix; version to appear in JHEP; typos fixed and
additional references and acknowledgements adde
What are communities of practice? A comparative review of four seminal works
This paper is a comparative review of four seminal works on communities of practice. It is argued that the ambiguities of the terms community and practice are a source of the concept's reusability allowing it to be reappropriated for different purposes, academic and practical. However, it is potentially confusing that the works differ so markedly in their conceptualizations of community, learning, power and change, diversity and informality. The three earlier works are underpinned by a common epistemological view, but Lave and Wenger's 1991 short monograph is often read as primarily about the socialization of newcomers into knowledge by a form of apprenticeship, while the focus in Brown and Duguid's article of the same year is, in contrast, on improvising new knowledge in an interstitial group that forms in resistance to management. Wenger's 1998 book treats communities of practice as the informal relations and understandings that develop in mutual engagement on an appropriated joint enterprise, but his focus is the impact on individual identity. The applicability of the concept to the heavily individualized and tightly managed work of the twenty-first century is questionable. The most recent work by Wenger â this time with McDermott and Snyder as coauthors â marks a distinct shift towards a managerialist stance. The proposition that managers should foster informal horizontal groups across organizational boundaries is in fact a fundamental redefinition of the concept. However it does identify a plausible, if limited, knowledge management (KM) tool. This paper discusses different interpretations of the idea of 'co-ordinating' communities of practice as a management ideology of empowerment
Uplifted supersymmetric Higgs region
We show that the parameter space of the Minimal Supersymmetric Standard Model
includes a region where the down-type fermion masses are generated by the
loop-induced couplings to the up-type Higgs doublet. In this region the
down-type Higgs doublet does not acquire a vacuum expectation value at tree
level, and has sizable couplings in the superpotential to the tau leptons and
bottom quarks. Besides a light standard-like Higgs boson, the Higgs spectrum
includes the nearly degenerate states of a heavy spin-0 doublet which can be
produced through their couplings to the quark and decay predominantly into
\tau^+\tau^- or \tau\nu.Comment: 14 pages; Signs in Eqns. (3.1) and (4.2) corrected, appendix include
'Support our networking and help us belong!': listening to beginning secondary school science teachers
This study, drawing on the voice of beginning teachers, seeks to illuminate their experiences of building professional relationships as they become part of the teaching profession. A networking perspective was taken to expose and explore the use of others during the first three years of a teacherâs workplace experience. Three case studies, set within a wider sample of 11 secondary school science teachers leaving one UK universityâs PostGraduate Certificate in Education, were studied. The project set out to determine the nature of the networks used by teachers in terms of both how they were being used for their own professional development and perceptions of how they were being used by others in school. Affordances and barriers to networking were explored using notions of identity formation through social participation. The focus of the paper is on how the teachers used others to help shape their sense of belonging to this, their new workplace. The paper develops ideas from network theories to argue that membership of the communities are a subset of the professional interârelationships teachers utilise for their professional development. During their first year of teaching, eight teachers were interviewed, completing 13 semiâstructured interviews. This was supplemented in Year 2 by a questionnaire survey of their experiences. In the third year of the programme, 11 teachers (including the original sample of eight) were surveyed using a network mapping tool in which they represented their communications with people, groups and resources. Finally, three of the teachers (common to both samples) were then interviewed specifically about their networking practices and experiences using the generation of their network map as a stimulated recall focus. The implications of the analysis of these accounts are that these beginning teachers did not perceive of themselves wholly as novices and that their personal aspirations to increase participation in practical science, develop a career or work for pupils holistically did not always sit comfortably with the school communities into which they were being accommodated. While highlighting the importance of trust and respect in establishing relationships, these teachersâ accounts highlight the importance of finding âpeersâ from whom they can find support and with whom they can reflect and potentially collaborate towards developing practice. They also raise questions about who these âpeersâ might be and where they might be found
Using statistical and artificial neural networks to predict the permeability of loosely packed granular materials
Well-known analytical equations for predicting permeability are generally reported to overestimate this important property of porous media. In this work, more robust models developed from statistical (multivariable regression) and Artificial Neural Network (ANN) methods utilised additional particle characteristics [âfines ratioâ (x50/x10) and particle shape] that are not found in traditional analytical equations. Using data from experiments and literature, model performance analyses with average absolute error (AAE) showed error of ~40% for the analytical models (KozenyâCarman and HappelâBrenner). This error reduces to 9% with ANN model. This work establishes superiority of the new models, using experiments and mathematical techniques
Persuasion as a form of inter-agent negotiation
Agents in a multi-agent environment must often cooperate to achieve their objectives. In this paper an agent, B, cooperates with another agent, A, if B adopts a goal that furthers A's objectives in the environment. If agents are independent and motivated by their own interests, cooperation cannot be relied upon and it may be necessary for A to persuade B to adopt a cooperative goal. This paper is concerned with the organisation and construction of persuasive argument, and examines how a rational agent comes to hold a belief, and thus, how new beliefs might be engendered and existing beliefs altered, through the process of argumentation. Argument represents an opportunity for an agent to convince a possibly sceptical or resistant audience of the veracity of its own beliefs. This ability is a vital component of rich communication, facilitating explanation, instruction, cooperation and conflict resolution. An architecture is described in which a hierarchical planner is used to develop discourse plans which can be realised in natural language using the LOLITA system. Planning is concerned with the intentional, contextual and pragmatic aspects of discourse structure as well as with the logical form of the argument and its stylistic organisation. In this paper attention is restricted to the planning of persuasive discourse, or monologue
Performance of a lab-scale bio-electrochemical assisted septic tank for the anaerobic treatment of black water
Origins of the Ambient Solar Wind: Implications for Space Weather
The Sun's outer atmosphere is heated to temperatures of millions of degrees,
and solar plasma flows out into interplanetary space at supersonic speeds. This
paper reviews our current understanding of these interrelated problems: coronal
heating and the acceleration of the ambient solar wind. We also discuss where
the community stands in its ability to forecast how variations in the solar
wind (i.e., fast and slow wind streams) impact the Earth. Although the last few
decades have seen significant progress in observations and modeling, we still
do not have a complete understanding of the relevant physical processes, nor do
we have a quantitatively precise census of which coronal structures contribute
to specific types of solar wind. Fast streams are known to be connected to the
central regions of large coronal holes. Slow streams, however, appear to come
from a wide range of sources, including streamers, pseudostreamers, coronal
loops, active regions, and coronal hole boundaries. Complicating our
understanding even more is the fact that processes such as turbulence,
stream-stream interactions, and Coulomb collisions can make it difficult to
unambiguously map a parcel measured at 1 AU back down to its coronal source. We
also review recent progress -- in theoretical modeling, observational data
analysis, and forecasting techniques that sit at the interface between data and
theory -- that gives us hope that the above problems are indeed solvable.Comment: Accepted for publication in Space Science Reviews. Special issue
connected with a 2016 ISSI workshop on "The Scientific Foundations of Space
Weather." 44 pages, 9 figure
Scaling and universality in the phase diagram of the 2D Blume-Capel model
We review the pertinent features of the phase diagram of the zero-field
Blume-Capel model, focusing on the aspects of transition order, finite-size
scaling and universality. In particular, we employ a range of Monte Carlo
simulation methods to study the 2D spin-1 Blume-Capel model on the square
lattice to investigate the behavior in the vicinity of the first-order and
second-order regimes of the ferromagnet-paramagnet phase boundary,
respectively. To achieve high-precision results, we utilize a combination of
(i) a parallel version of the multicanonical algorithm and (ii) a hybrid
updating scheme combining Metropolis and generalized Wolff cluster moves. These
techniques are combined to study for the first time the correlation length of
the model, using its scaling in the regime of second-order transitions to
illustrate universality through the observed identity of the limiting value of
with the exactly known result for the Ising universality class.Comment: 16 pages, 7 figures, 1 table, submitted to Eur. Phys. J. Special
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