4,246 research outputs found
Disorder-Driven Pretransitional Tweed in Martensitic Transformations
Defying the conventional wisdom regarding first--order transitions, {\it
solid--solid displacive transformations} are often accompanied by pronounced
pretransitional phenomena. Generally, these phenomena are indicative of some
mesoscopic lattice deformation that ``anticipates'' the upcoming phase
transition. Among these precursive effects is the observation of the so-called
``tweed'' pattern in transmission electron microscopy in a wide variety of
materials. We have investigated the tweed deformation in a two dimensional
model system, and found that it arises because the compositional disorder
intrinsic to any alloy conspires with the natural geometric constraints of the
lattice to produce a frustrated, glassy phase. The predicted phase diagram and
glassy behavior have been verified by numerical simulations, and diffraction
patterns of simulated systems are found to compare well with experimental data.
Analytically comparing to alternative models of strain-disorder coupling, we
show that the present model best accounts for experimental observations.Comment: 43 pages in TeX, plus figures. Most figures supplied separately in
uuencoded format. Three other figures available via anonymous ftp
Electrical spin injection into p-doped quantum dots through a tunnel barrier
We have demonstrated by electroluminescence the injection of spin polarized
electrons through Co/Al2O3/GaAs tunnel barrier into p-doped InAs/GaAs quantum
dots embedded in a PIN GaAs light emitting diode. The spin relaxation processes
in the p-doped quantum dots are characterized independently by optical
measurements (time and polarization resolved photoluminescence). The measured
electroluminescence circular polarization is about 15 % at low temperature in a
2T magnetic field, leading to an estimation of the electrical spin injection
yield of 35%. Moreover, this electroluminescence circular polarization is
stable up to 70 K.Comment: 6 pages, 4 figure
The Effect of Lattice Vibrations on Substitutional Alloy Thermodynamics
A longstanding limitation of first-principles calculations of substitutional
alloy phase diagrams is the difficulty to account for lattice vibrations. A
survey of the theoretical and experimental literature seeking to quantify the
impact of lattice vibrations on phase stability indicates that this effect can
be substantial. Typical vibrational entropy differences between phases are of
the order of 0.1 to 0.2 k_B/atom, which is comparable to the typical values of
configurational entropy differences in binary alloys (at most 0.693 k_B/atom).
This paper describes the basic formalism underlying ab initio phase diagram
calculations, along with the generalization required to account for lattice
vibrations. We overview the various techniques allowing the theoretical
calculation and the experimental determination of phonon dispersion curves and
related thermodynamic quantities, such as vibrational entropy or free energy. A
clear picture of the origin of vibrational entropy differences between phases
in an alloy system is presented that goes beyond the traditional bond counting
and volume change arguments. Vibrational entropy change can be attributed to
the changes in chemical bond stiffness associated with the changes in bond
length that take place during a phase transformation. This so-called ``bond
stiffness vs. bond length'' interpretation both summarizes the key phenomenon
driving vibrational entropy changes and provides a practical tool to model
them.Comment: Submitted to Reviews of Modern Physics 44 pages, 6 figure
Characterization of an Ionization Readout Tile for nEXO
A new design for the anode of a time projection chamber, consisting of a
charge-detecting "tile", is investigated for use in large scale liquid xenon
detectors. The tile is produced by depositing 60 orthogonal metal
charge-collecting strips, 3~mm wide, on a 10~\si{\cm} 10~\si{\cm}
fused-silica wafer. These charge tiles may be employed by large detectors, such
as the proposed tonne-scale nEXO experiment to search for neutrinoless
double-beta decay. Modular by design, an array of tiles can cover a sizable
area. The width of each strip is small compared to the size of the tile, so a
Frisch grid is not required. A grid-less, tiled anode design is beneficial for
an experiment such as nEXO, where a wire tensioning support structure and
Frisch grid might contribute radioactive backgrounds and would have to be
designed to accommodate cycling to cryogenic temperatures. The segmented anode
also reduces some degeneracies in signal reconstruction that arise in
large-area crossed-wire time projection chambers. A prototype tile was tested
in a cell containing liquid xenon. Very good agreement is achieved between the
measured ionization spectrum of a Bi source and simulations that
include the microphysics of recombination in xenon and a detailed modeling of
the electrostatic field of the detector. An energy resolution =5.5\%
is observed at 570~\si{keV}, comparable to the best intrinsic ionization-only
resolution reported in literature for liquid xenon at 936~V/\si{cm}.Comment: 18 pages, 13 figures, as publishe
Sensitivity and discovery potential of the proposed nEXO experiment to neutrinoless double beta decay
The next-generation Enriched Xenon Observatory (nEXO) is a proposed
experiment to search for neutrinoless double beta () decay in
Xe with a target half-life sensitivity of approximately years
using kg of isotopically enriched liquid-xenon in a time
projection chamber. This improvement of two orders of magnitude in sensitivity
over current limits is obtained by a significant increase of the Xe
mass, the monolithic and homogeneous configuration of the active medium, and
the multi-parameter measurements of the interactions enabled by the time
projection chamber. The detector concept and anticipated performance are
presented based upon demonstrated realizable background rates.Comment: v2 as publishe
The Double Star Plasma Electron and Current Experiment
The Double Star Project is a collaboration between Chinese and European space agencies, in which two Chinese magnetospheric research spacecraft, carrying Chinese and European instruments, have been launched into equatorial (on 29 December 2003) and polar (on 25 July 2004) orbits designed to enable complementary studies with the Cluster spacecraft. The two Double Star spacecraft TC-1 and TC-2 each carry a Double Star Plasma Electron and Current Experiment (PEACE) instrument. These two instruments were based on Cluster Flight Spare equipment, but differ from Cluster instruments in two important respects. Firstly, a Double Star PEACE instrument has only a single sensor, which must be operated in a manner not originally envisaged in the Cluster context in order to sample the full range of energies. Secondly, the DPU hardware was modified and major changes of onboard software were implemented, most notably a completely different approach to data compression has been adopted for Double Star, which allows high resolution 3-dimensional distributions to be transmitted almost every spin, a significant improvement over Cluster. This paper describes these instruments, and includes examples of data collected in various magnetospheric regions encountered by the spacecraft which have been chosen to illustrate the power of combined Double Star and Cluster measurements
Ab initio atomistic thermodynamics and statistical mechanics of surface properties and functions
Previous and present "academic" research aiming at atomic scale understanding
is mainly concerned with the study of individual molecular processes possibly
underlying materials science applications. Appealing properties of an
individual process are then frequently discussed in terms of their direct
importance for the envisioned material function, or reciprocally, the function
of materials is somehow believed to be understandable by essentially one
prominent elementary process only. What is often overlooked in this approach is
that in macroscopic systems of technological relevance typically a large number
of distinct atomic scale processes take place. Which of them are decisive for
observable system properties and functions is then not only determined by the
detailed individual properties of each process alone, but in many, if not most
cases also the interplay of all processes, i.e. how they act together, plays a
crucial role. For a "predictive materials science modeling with microscopic
understanding", a description that treats the statistical interplay of a large
number of microscopically well-described elementary processes must therefore be
applied. Modern electronic structure theory methods such as DFT have become a
standard tool for the accurate description of individual molecular processes.
Here, we discuss the present status of emerging methodologies which attempt to
achieve a (hopefully seamless) match of DFT with concepts from statistical
mechanics or thermodynamics, in order to also address the interplay of the
various molecular processes. The new quality of, and the novel insights that
can be gained by, such techniques is illustrated by how they allow the
description of crystal surfaces in contact with realistic gas-phase
environments.Comment: 24 pages including 17 figures, related publications can be found at
http://www.fhi-berlin.mpg.de/th/paper.htm
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