Controlling pollution effects on metallic cultural heritage using linear sweep voltammetry

This work demonstrates the potentialities of the linear sweep voltammetry (LSV) for monitoring the composition of the tarnishing layers formed on silver and on the silver-copper alloys exposed to atmospheres contaminated with pollutants, such as H2S and chloride ions, among others. A collection of silver and sterling silver coupons exposed during periods of 1 and 12 months, at the Holy Altar of the Chapel and at the Treasure Room of the Museum, both of the Porto Cathedral (Portugal), with exposures started in march 2010 and ending in march 2011, have been analysed by LSV. The LSV spectra of blank polished samples as well as samples covered with thin films of silver sulphide and of silver chloride, formed under controlled conditions, respectively: (i) H2S, 1000 ppm, RH= 53% ± 2, T= 21˚C ± 1, over periods of 24, 48 and 72 h and (ii) 3.5% of NaCl, RH=41%, T= 43˚C, periods of 5 h, have been used as references. The influence of the atmosphere (Chapel and Museum), exposure time (1 and 12 months) and season, in which the exposures were started, (spring, summer, autumn and winter) have been analysed on the LSVs of the coupons exposed to the various conditions. For the 1 month exposures started in spring the peaks corresponding to the silver sulphide and silver chloride were, as expected, higher on the samples exposed in the Chapel. For the 12 months exposures both peaks have increased in size with the peak assigned to chloride being much higher in the case of the Chapel and the reverse observed in the case of the Museum. The seasonal influence, even for the 1 month exposures was particularly notable on those started in winter with well visible effects on the sulphide and chloride peaks respectively, in the Museum and Chapel exposures

Galvanic corrosion of two non noble dental alloys

Artigo licenciado sob uma Licença Creative Commons: https://creativecommons.org/licenses/by/4.0/"This study aims to evaluate the corrosion resistance of two nonnoble dental alloys, namely, the Wiron®88 (Ni–Cr–Mo) and the Remanium 2000+ (Co–Cr–Mo–W). A noble alloy, the V-Gnathos® Plus (AuPt) previously studied was also considered for the purpose of comparison. The study was conducted in artificial saliva, pH 7.1, at 37 °C, by cyclic and linear sweep voltammetry, electrochemical impedance spectroscopy and chronoamperometry. The Rp value of the alloy of high contents of Ni, the Wiron®88, was 26.2±0.2 kΩ cm2 and of the one with high contents of Co, the Remanium 2000+, was 22.5±0.6 kΩ cm2. Data from linear polarization resistance and electrochemical impedance spectroscopy lead to the same order for the resistance against corrosion. The order from the less to the more reactive alloy is: Wiron®88 → Remanium 2000+. The galvanic cell obtained by coupling the two nonnoble alloys presents very low cell potential (a few mV, -18 mV), while the galvanic cell between one noble alloy (the V-Gnathos® Plus) and the Wiron®88 showed a higher cell potential (-104 mV). Both galvanic couples, under short circuit, have lead to the release of cations, namely, Co2+, in the case of the Wiron®88|Remanium 2000+ and Ni2+ for the Wiron®88|V-Gnathos® Plus, galvanic couples, respectively, with the ionic concentrations reaching values of 12.15 and 7.30 μg L-1 (7.30 ppb), respectively. SEM micrographs obtained after 25 days immersion in artificial saliva, at 37 °C, showed the formation of well-defined pits on the surface of the two non-noble alloys.

Conformal invariance: from Weyl to SO(2,d)

The present work deals with two different but subtilely related kinds of conformal mappings: Weyl rescaling in $d>2$ dimensional spaces and SO(2,d) transformations. We express how the difference between the two can be compensated by diffeomorphic transformations. This is well known in the framework of String Theory but in the particular case of $d=2$ spaces. Indeed, the Polyakov formalism describes world-sheets in terms of two-dimensional conformal field theory. On the other hand, B. Zumino had shown that a classical four-dimensional Weyl-invariant field theory restricted to live in Minkowski space leads to an SO(2,4)-invariant field theory. We extend Zumino's result to relate Weyl and SO(2,d) symmetries in arbitrary conformally flat spaces (CFS). This allows us to assert that a classical $SO(2,d)$-invariant field does not distinguish, at least locally, between two different $d$-dimensional CFSs.Comment: 5 pages, no figures. There are slight modifications to match with the published versio

Anomalous quantum confined Stark effects in stacked InAs/GaAs self-assembled quantum dots

Vertically stacked and coupled InAs/GaAs self-assembled quantum dots (SADs) are predicted to exhibit a strong non-parabolic dependence of the interband transition energy on the electric field, which is not encountered in single SAD structures nor in other types of quantum structures. Our study based on an eight-band strain-dependent ${\bf k}\cdot{\bf p}$ Hamiltonian indicates that this anomalous quantum confined Stark effect is caused by the three-dimensional strain field distribution which influences drastically the hole states in the stacked SAD structures.Comment: 4 pages, 4 figure

Entangled-State Lithography: Tailoring any Pattern with a Single State

We demonstrate a systematic approach to Heisenberg-limited lithographic image formation using four-mode reciprocal binominal states. By controlling the exposure pattern with a simple bank of birefringent plates, any pixel pattern on a $(N+1) \times (N+1)$ grid, occupying a square with the side half a wavelength long, can be generated from a $2 N$-photon state.Comment: 4 pages, 4 figure

Surface tension in the dilute Ising model. The Wulff construction

We study the surface tension and the phenomenon of phase coexistence for the Ising model on \mathbbm{Z}^d ($d \geqslant 2$) with ferromagnetic but random couplings. We prove the convergence in probability (with respect to random couplings) of surface tension and analyze its large deviations : upper deviations occur at volume order while lower deviations occur at surface order. We study the asymptotics of surface tension at low temperatures and relate the quenched value $\tau^q$ of surface tension to maximal flows (first passage times if $d = 2$). For a broad class of distributions of the couplings we show that the inequality $\tau^a \leqslant \tau^q$ -- where $\tau^a$ is the surface tension under the averaged Gibbs measure -- is strict at low temperatures. We also describe the phenomenon of phase coexistence in the dilute Ising model and discuss some of the consequences of the media randomness. All of our results hold as well for the dilute Potts and random cluster models

Survey of charge symmetry breaking operators for dd -> alpha pi0

The charge-symmetry-breaking amplitudes for the recently observed d d -> alpha pi0 reaction are investigated. Chiral perturbation theory is used to classify and identify the leading-order terms. Specific forms of the related one- and two-body tree level diagrams are derived. As a first step toward a full calculation, a few tree-level two-body diagrams are evaluated at each considered order, using a simplified set of d and alpha wave functions and a plane-wave approximation for the initial dd state. The leading-order pion-exchange term is shown to be suppressed in this model because of poor overlap of the initial and final states. The higher-order one-body and short-range (heavy-meson-exchange) amplitudes provide better matching between the initial and final states and therefore contribute significantly and coherently to the cross section. The consequences this might have for a full calculation, with realistic wave functions and a more complete set of amplitudes, are discussed.Comment: REVTeX 4, 35 pages, 8 eps figures, submitted to PR

A Review of ENSO Influence on the North Atlantic. A Non-Stationary Signal

ReviewThe atmospheric seasonal cycle of the North Atlantic region is dominated by meridional movements of the circulation systems: from the tropics, where the West African Monsoon and extreme tropical weather events take place, to the extratropics, where the circulation is dominated by seasonal changes in the jetstream and extratropical cyclones. Climate variability over the North Atlantic is controlled by various mechanisms. Atmospheric internal variability plays a crucial role in the mid-latitudes. However, El Niño-Southern Oscillation (ENSO) is still the main source of predictability in this region situated far away from the Pacific. Although the ENSO influence over tropical and extra-tropical areas is related to different physical mechanisms, in both regions this teleconnection seems to be non-stationary in time and modulated by multidecadal changes of the mean flow. Nowadays, long observational records (greater than 100 years) and modeling projects (e.g., CMIP) permit detecting non-stationarities in the influence of ENSO over the Atlantic basin, and further analyzing its potential mechanisms. The present article reviews the ENSO influence over the Atlantic region, paying special attention to the stability of this teleconnection over time and the possible modulators. Evidence is given that the ENSO–Atlantic teleconnection is weak over the North Atlantic. In this regard, the multidecadal ocean variability seems to modulate the presence of teleconnections, which can lead to important impacts of ENSO and to open windows of opportunity for seasonal predictability.We thank the Climatic Research Unit (CRU), the National Centers for Environmental Prediction (NCEP), the Met Office Hadley Centre and the US National Hurricane Center (NHC) for the Land Precipitation, reanalysis, SST and HURDAT2 datasets, respectively. Belen Rodríguez-Fonseca, Roberto Suárez-Moreno, Jorge López-Parages, Iñigo Gómara, Elsa Mohino, Teresa Losada and Antonio Castaño-Tierno are supported by the research projects PREFACE (EUFP7/2007-2013 Grant Agreement 603521) and MULCLIVAR (CGL2012-38923-C02-01-Spanish Ministry of Economy and Competitiveness). Blanca Ayarzagüena is supported by the Natural Environment Research Council (grant number NE/M006123/1). Julián Villamayor is granted through a scholarship from the MICINN—Spanish government (BES-2013-063821

Haldane-gap chains in a magnetic field

We consider quasi one dimensional spin-1 Heisenberg chains with crystal field anisotropy in a uniform magnetic field. We determine the dynamical structure factor in various limits and obtain a fairly complete qualitative picture of how it changes with the applied field. In particular, we discuss how the width of the higher energy single magnon modes depends on the field. We consider the effects of a weak interchain coupling. We discuss the relevance of our results for recent neutron scattering experiments on the quasi-1D Haldane-gap compound NDMAP.Comment: 34 pages, 7 figure