Fe-isotope fractionation in magmatic-hydrothermal mineral deposits: a case study from the Renison Sn-W deposit, Tasmania

We present 50 new iron isotopic analyses of source granite and mineral separates from the Renison tin deposit in western Tasmania. The aim of the study is to characterise the composition of minerals within a tin deposit associated with a reduced, S-type magma. We have analysed bulk samples of granite, and separates of pyrrhotite, pyrite, arsenopyrite, magnetite, chalcopyrite and siderite by multi-collector inductively coupled mass spectrometry. The isotopic compositions of mineral separates are consistent with theoretical predictions of equilibrium fractionation based on Mössbauer spectroscopy and other parametric calculations. Mineral-mineral pairs yield temperatures of formation that are in agreement with prior detailed fluid inclusion studies, but are spatially inconsistent with declining fluid temperatures with distance from the causative intrusion, limiting the use of Fe isotopes as a potential geothermometer, at least in this case. Comparison of our data with published data from other deposits clearly demonstrates that pyrite, magnetite and chalcopyrite from the hottest ore fluids (>300-400. °C) at Renison are isotopically heavier than minerals sampled from a deposit formed at similar temperatures, but associated with a more oxidised and less differentiated intrusion.Christine M. Wawryk, John D. Fode

The timing and duration of the Delamerian orogeny: Correlation with the Ross Orogen and implications for Gondwana assembly

Copyright © 2006 by the University of Chicago PressThe Antarctic Ross and the Australian Delamerian orogenies are the consequence of stress transfer to the outboard trailing edge of the newly assembled Gondwana supercontinent. This tectonic reorganization occurred in the Early to Middle Cambrian on completion of Pan-African deformation and subduction along the sutures between eastern and western Gondwanan continental fragments. Before this, Neoproterozoic to Early Cambrian rocks in eastern Australia were formed in a passive margin and record dispersion of Rodinia with consequent opening of the proto-Pacific. Our new U-Pb and Rb-Sr geochronology shows that in the South Australian (Adelaide Fold Belt) domain of the Delamerian Orogen, contractional orogenesis commenced at 514 ± 3 Ma and persisted for ∼24 m.yr. until 490 ± 3 Ma, terminated by rapid uplift, cooling, and extension in association with posttectonic magmatism. Integration of new and published U-Pb and 40Ar-39Ar geochronology from the entire Ross-Delamerian belt shows that although both the Delamerian and Ross have a synchronous late magmatic and terminal cooling history, the Ross commenced its convergent orogenic history at ∼540 Ma. This was 25 m.yr. before Delamerian deformation began. During the Early Cambrian, eastern Australia was still in a state of extension (or transtension), with opening of the Kanmantoo Basin and associated anorogenic, largely mafic magmatism. This basin received sediment from the already exposed Ross Orogen to the south. The simultaneous first occurrence of strain fabrics and subduction-related magmatism (including boninite, granite, and andesite lavas) at ∼514 Ma in New Zealand, Victoria, South Australia, New South Wales, and Tasmania implies that the Delamerian Orogeny was driven by ridge-push forces transmitted on the initiation of westward-dipping subduction. Subsequent eastward slab rollback at 490 Ma may have occurred when the new slab had reached the transition zone at 650-km depth, resulting in upper plate extension and anorogenic Basin and Range–style magmatism in South Australia and Tasmania (Mount Read belt). The delayed onset of subduction in the Australian sector of the margin implies that westward motion of the Australian portion of eastern Gondwana continued to be accommodated during the late Early Cambrian by subduction or deformation along either the Mozambique Suture or at the northern end of the South Prince Charles Mountains–Prydz Bay suture.John Foden, Marlina A. Elburg, Jon Dougherty-Page, and Andrew Burt

Distinct mechanisms of Drosophila CRYPTOCHROME-mediated light-evoked membrane depolarization and in vivo clock resetting.

Drosophila CRYPTOCHROME (dCRY) mediates electrophysiological depolarization and circadian clock resetting in response to blue or ultraviolet (UV) light. These light-evoked biological responses operate at different timescales and possibly through different mechanisms. Whether electron transfer down a conserved chain of tryptophan residues underlies biological responses following dCRY light activation has been controversial. To examine these issues in in vivo and in ex vivo whole-brain preparations, we generated transgenic flies expressing tryptophan mutant dCRYs in the conserved electron transfer chain and then measured neuronal electrophysiological phototransduction and behavioral responses to light. Electrophysiological-evoked potential analysis shows that dCRY mediates UV and blue-light-evoked depolarizations that are long lasting, persisting for nearly a minute. Surprisingly, dCRY appears to mediate red-light-evoked depolarization in wild-type flies, absent in both cry-null flies, and following acute treatment with the flavin-specific inhibitor diphenyleneiodonium in wild-type flies. This suggests a previously unsuspected functional signaling role for a neutral semiquinone flavin state (FADH•) for dCRY. The W420 tryptophan residue located closest to the FAD-dCRY interaction site is critical for blue- and UV-light-evoked electrophysiological responses, while other tryptophan residues within electron transfer distance to W420 do not appear to be required for light-evoked electrophysiological responses. Mutation of the dCRY tryptophan residue W342, more distant from the FAD interaction site, mimics the cry-null behavioral light response to constant light exposure. These data indicate that light-evoked dCRY electrical depolarization and clock resetting are mediated by distinct mechanisms

Snake orbits and related magnetic edge states

We study the electron motion near magnetic field steps at which the strength and/or sign of the magnetic field changes. The energy spectrum for such systems is found and the electron states (bound and scattered) are compared with their corresponding classical paths. Several classical properties as the velocity parallel to the edge, the oscillation frequency perpendicular to the edge and the extent of the states are compared with their quantum mechanical counterpart. A class of magnetic edge states is found which do not have a classical counterpart.Comment: 8 pages, 10 figure

Water surface height determination with a GPS wave glider: a demonstration in Loch Ness, Scotland

A geodetic GPS receiver has been installed on a Wave Glider, an unmanned water surface vehicle. Using kinematic precise point positioning (PPP) GPS, which operates globally without directly requiring reference stations, surface heights are measured with ~0.05-m precision. The GPS Wave Glider was tested in Loch Ness, Scotland, by measuring the gradient of the loch’s surface height. The experiment took place under mild weather, with virtually no wind setup along the loch and a wave field made mostly of ripples and wavelets. Under these conditions, the loch’s surface height gradient should be approximately equal to the geoid slope. The PPP surface height gradient and that of the Earth Gravitational Model 2008 geoid heights do indeed agree on average along the loch (0.03 m km−1). Also detected are 1) ~0.05-m-sized height changes due to daily water pumping for hydroelectricity generation and 2) high-frequency (0.25–0.5 Hz) oscillations caused by surface waves. The PPP heights compare favorably (~0.02-m standard deviation) with relative carrier phase–based GPS processing. This suggests that GPS Wave Gliders have the potential to autonomously determine centimeter-precise water surface heights globally for lake modeling, and also for applications such as ocean modeling and geoid/mean dynamic topography determination, at least for benign surface states such as those encountered during the reported experiment

Zircon geochemical and geochronological constraints on contaminated and enriched mantle sources beneath the Arabian Shield, Saudi Arabia

Arabian Shield granitic zircon geochemistry provides insight into the petrogenetic processes involved in generating one of the planet’s largest tracts of juvenile Neoproterozoic crust. New zircon geochemistry supports previous U-Pb and whole-rock data that defined four magmatic groups: (1) ∼870-675 Ma island arc and synorogenic I-type granitoids (IA1Syn), (2) ∼640-585 Ma I-and A-type granitoids from the Nabitah and Halaban Suture (NHSG), (3) ∼610-600 Ma postorogenic perthitic (hypersolvus) A-type granitoids (POPG), and (4) <600 Ma anorogenic aegirine-bearing perthitic (hypersolvus) A-type granitoids (AAPG). The low Nb (∼1-300 ppm) and intrasuite rare earth element variation in IA1Syn and NHSG zircons indicates that these suites are derivatives of contaminated mantle followed by fractionation. AAPG suites, however, have higher Nb content (∼10-400 ppm) and are derived from limited crust-enriched mantle interaction. Each of the IA, Syn, and NHSG suites have discrete granite subsuites distinguished using zircon morphology and geo-chemistry whose U-Pb ages in each case form three groups. The IA subgroups are ∼867, ∼847, and ∼829 Ma; the Syn subgroups are ∼730, 716, and 696 Ma; and the NHSG subgroups are ∼636, ∼610, and ∼594 Ma. This apparent subevent repetition suggests some form of magmatic pulsing in the Arabian Shield. It is suggested that IA1Syn suites reflect typical volcanic arc granite settings and incremental subduction/accretion of eastward-migrating oceanic fragments of the East African Orogen. The appearance of ∼636 Ma A-type magmatism within suture zones (NHSG) is possibly derived from a long-lived (∼50 m.yr.) melting, assimilation, storage, and homogenization (MASH) zone resulting from an ∼640 Ma slab tear. These A-types are distinguished from more-enriched anorogenic (<600 Ma) A-types, possibly associated with lithospheric delamination.F. A. Robinson, J. D. Foden, and A. S. Collin

Fano resonances in a three-terminal nanodevice

The electron transport through a quantum sphere with three one-dimensional wires attached to it is investigated. An explicit form for the transmission coefficient as a function of the electron energy is found from the first principles. The asymmetric Fano resonances are detected in transmission of the system. The collapse of the resonances is shown to appear under certain conditions. A two-terminal nanodevice with an additional gate lead is studied using the developed approach. Additional resonances and minima of transmission are indicated in the device.Comment: 11 pages, 5 figures, 2 equations are added, misprints in 5 equations are removed, published in Journal of Physics: Condensed Matte

Dimeric CRISPR RNA-guided FokI nucleases for highly specific genome editing

Monomeric CRISPR-Cas9 nucleases are widely used for targeted genome editing but can induce unwanted off-target mutations with high frequencies. Here we describe dimeric RNA-guided FokI Nucleases (RFNs) that recognize extended sequences and can edit endogenous genes with high efficiencies in human cells. The cleavage activity of an RFN depends strictly on the binding of two guide RNAs (gRNAs) to DNA with a defined spacing and orientation and therefore show improved specificities relative to wild-type Cas9 monomers. Importantly, direct comparisons show that RFNs guided by a single gRNA generally induce lower levels of unwanted mutations than matched monomeric Cas9 nickases. In addition, we describe a simple method for expressing multiple gRNAs bearing any 5′ end nucleotide, which gives dimeric RFNs a broad targeting range. RFNs combine the ease of RNA-based targeting with the specificity enhancement inherent to dimerization and are likely to be useful in applications that require highly precise genome editing