Intelligent Resource Use to Deliver Waste Valorisation and Process Resilience in Manufacturing Environments

© 2020 Johnson Matthey Circular economy (CE) thinking has emerged as a route to sustainable manufacture, with related cradle-to-cradle implications requiring implementation from the design stage. The challenge lies in moving manufacturing environments away from the traditional linear economy paradigm, where materials, energy and water have often been designed to move out of the system and into receivership of waste management bodies after use. Recent applications of industrial digital technologies (IDTs: for example internet of things, data-driven modelling, cyber-physical systems, cloud manufacturing, cognitive computing) to manufacturing may be instrumental in transforming manufacturing from linear to circular. However, although IDTs and CE have been the focus of intensive research, there is currently limited research exploring the relationship between IDTs and the CE and how the former may drive the implementation of CE. This article aims to close the knowledge gap by exploring how an IDT (data-driven modelling) may facilitate and advance CE principles within process manufacturing systems, specifically waste valorisation and process resilience. These applications are then demonstrated through two real-world manufacturing case studies: (a) minimising resource consumption of industrial cleaning processes and (b) transforming wastewater treatment plants (WWTPs) into manufacturing centres

Numerical study of the strongly screened vortex glass model in an external field

The vortex glass model for a disordered high-T_c superconductor in an external magnetic field is studied in the strong screening limit. With exact ground state (i.e. T=0) calculations we show that 1) the ground state of the vortex configuration varies drastically with infinitesimal variations of the strength of the external field, 2) the minimum energy of global excitation loops of length scale L do not depend on the strength of the external field, however 3) the excitation loops themself depend sensibly on the field. From 2) we infer the absence of a true superconducting state at any finite temperature independent of the external field.Comment: 6 pages RevTeX, 5 eps-figures include

Comparison between high- and low-intensity eccentric cycling of equal mechanical work for muscle damage and the repeated bout effect

Purpose: We compared high- and low-intensity eccentric cycling (ECC) with the same mechanical work for changes in muscle function and muscle soreness, and examined the changes after subsequent high-intensity ECC. Methods: Twenty men performed either high-intensity ECC (1 min × 5 at 20% of peak power output: PPO) for two bouts separated by 2 weeks (H–H, n = 11), or low-intensity (4 min × 5 at 5% PPO) for the first and high-intensity ECC for the second bout (L–H, n = 9). Changes in indirect muscle damage markers were compared between groups and bouts. Results: At 24 h after the first bout, both groups showed similar decreases in maximal isometric (70° knee angle, − 10.6 ± 11.8%) and isokinetic (− 11.0 ± 8.2%) contraction torque of the knee extensors (KE), squat (− 7.7 ± 10.4%) and counter-movement jump (− 5.9 ± 8.4%) heights (p \u3c 0.05). Changes in KE torque and jump height were smaller after the second than the first bout for both the groups (p \u3c 0.05). Increases in plasma creatine kinase activity were small, and no significant changes in vastus lateralis or intermedius thickness nor ultrasound echo-intensity were observed. KE soreness with palpation was greater (p \u3c 0.01) in H–H (peak: 4.2 ± 1.0) than L–H (1.4 ± 0.6) after the first bout, but greater in L–H (3.6 ± 0.9) than H–H (1.5 ± 0.5) after the second bout. This was also found for muscle soreness with squat, KE stretch and gluteal palpation. Conclusion: The high- and low-intensity ECC with matched mechanical work induced similar decreases in muscle function, but DOMS was greater after high-intensity ECC, which may be due to greater extracellular matrix damage and inflammation. © 2020, Springer-Verlag GmbH Germany, part of Springer Nature

Sodium Intercalation Mechanism of 3.8 v Class Alluaudite Sodium Iron Sulfate

Alluaudite sodium iron sulfate Na$_{2+2x}$Fe$_{2−x}$(SO$_4$)$_3$ is one of the most promising candidates for a Na-ion battery cathode material with earth-abundant elements; it exhibits the highest potential among any Fe$^{3+}$/Fe$^{2+}$ redox reactions (3.8 V vs Na/Na$^+$ ), good cycle performance, and high rate capability. However, the reaction mechanism during electrochemical charging/discharging processes is still not understood. Here, we surveyed the intercalation mechanism via synchrotron X-ray diffraction (XRD), $^{23}$Na nuclear magnetic resonance (NMR), density functional theory (DFT) calculations, X-ray absorption near edge structure (XANES), and Mössbauer spectroscopy. Throughout charging/discharging processes, the structure undergoes a reversible, single-phase (solid solution) reaction based on a Fe$^{3+}$/Fe$^{2+}$ redox reaction with a small volume change of ca. 3.5% after an initial structural rearrangement upon the first charging process, where a small amount of Fe irreversibly migrates from the original site to a Na site. Sodium extraction occurs in a sequential manner at various Na sites in the structure at their specific voltage regions.The present work was financially supported from the Ministry of Education, Culture, Sports, Science and Technology, Japan (MEXT) under the “Element Strategy Initiative for Catalysts & Batteries” (ESICB) project. The synchrotron XRD experiments were performed under KEK-PF User Program (No. 2013G670). Crystal structures and the Fourier difference maps were drawn by VESTA.65 G.O. acknowledges financial support from JSPS Research Fellowships under “Materials Education Program for the Future Leaders in Research, Industry, and Technology” (MERIT) project. This project has received funding from the European Union’s Horizon 2020 research and innovation program under the Marie Sklodowska-Curie grant agreement No. 655444 (O.P.). R.P. gratefully acknowledges financial support through the Marie Curie Actions People Program of the EU’s Seventh Frame work Program (FP7/2007-2013), under the grant agreement n.317127, the ‘pNMR project’. K.J.G. gratefully acknowledges funding from The Winston Churchill Foundation of the United States and the Herchel Smith Scholarship. This work made use of the facilities of the Center for Functional Nanomaterials, Brookhaven National Laboratory, which is supported by the U.S. Department of Energy, Office of Basic Energy Sciences, under Contract No. DE-AC02-98CH10886.This is the final version of the article. It first appeared from American Chemical Society via http://dx.doi.org/10.1021/acs.chemmater.6b0109

Fuel effect on the liquid-phase penetration of an evaporating spray under transient diesel-like conditions

Measurements of the maximum liquid-phase penetration have been performed injecting five different fuels through a single-hole nozzle in an optical engine under a large set of thermodynamic and injection conditions. The focus of this paper is twofold. First, it intends to study fuel physical properties on liquid-phase fuel penetration. The choice made on Fischer-Tropsch diesel (FTD) and biodiesel fuels has been highly motivated by their potential to be, at short or middle term, possible substitutes to the conventional diesel fuel. Extensive characterization of fuel physical and chemical properties under ambient conditions are provided and related to the liquid-phase penetration in order to provide an accessible tool to predict liquid spray behavior based on cheap, off-engine measurements. Fischer-Tropsch fuels appeared to be the easiest to vaporize while biodiesel blends were getting always harder to vaporize as the Rapeseed Methyl Ester (RME) rate was increased. The second objective of this work is to study the time-response of liquid-phase penetration when subjected to density and temperature variations. Injections of 8 ms at three different pressures have been performed in transient diesel-like conditions with density and temperature time derivatives up to 2000 kg m -3 s -1 and 20,000 K s -1. In most cases, the spray appeared to closely follow predictions made from empirical models built out of steady-state ambient conditions, leading to the conclusion of an instantaneous adjustment of the spray to its environment, validating: (1) the hypothesis made in 1D spray models; (2) the use of empirical models in unsteady-state environment when obtained under steady-state conditions.The authors wish to acknowledge the Spanish Ministry of Education and Science for the financial support through the OPTICOMB project (TRA2007-67961-C03-01) and Jean-Guillaume Nerva's Grant (BES-2008-004420). The authors would also like to thank Daniel Lerida for the management of the facility and his assistance in data acquisition.Pastor Soriano, JV.; García Oliver, JM.; Nerva, J.; Giménez, B. (2011). Fuel effect on the liquid-phase penetration of an evaporating spray under transient diesel-like conditions. Fuel. 90(11):3369-3381. https://doi.org/10.1016/j.fuel.2011.05.006S33693381901

From ‘other’ to involved: User involvement in research: An emerging paradigm

This article has been made available through the Brunel Open Access Publishing Fund. Copyright @ 2013 The Author(s). This is an Open Access article. Non-commercial re-use, distribution, and reproduction in any medium, provided the original work is properly attributed, cited, and is not altered, transformed, or built upon in any way, is permitted. The moral rights of the named author(s) have been asserted.This article explores the issue of ‘othering’ service users and the role that involving them, particularly in social policy and social work research may play in reducing this. It takes, as its starting point, the concept of ‘social exclusion’, which has developed in Europe and the marginal role that those who have been included in this construct have played in its development and the damaging effects this may have. The article explores service user involvement in research and is itself written from a service user perspective. It pays particular attention to the ideological, practical, theoretical, ethical and methodological issues that such user involvement may raise for research. It examines problems that both research and user involvement may give rise to and also considers developments internationally to involve service users/subjects of research, highlighting some of the possible implications and gains of engaging service user knowledge in research and the need for this to be evaluated

Stereotypic wheel running decreases cortical activity in mice

Prolonged wakefulness is thought to gradually increase sleep need' and influence subsequent sleep duration and intensity, but the role of specific waking behaviours remains unclear. Here we report the effect of voluntary wheel running during wakefulness on neuronal activity in the motor and somatosensory cortex in mice. We find that stereotypic wheel running is associated with a substantial reduction in firing rates among a large subpopulation of cortical neurons, especially at high speeds. Wheel running also has longer-term effects on spiking activity across periods of wakefulness. Specifically, cortical firing rates are significantly higher towards the end of a spontaneous prolonged waking period. However, this increase is abolished when wakefulness is dominated by running wheel activity. These findings indicate that wake-related changes in firing rates are determined not only by wake duration, but also by specific waking behaviours

The early development of self-injurious behaviour: evaluating the role of social reinforcement

Background: The potential role of social reinforcement in the development of self‐injury has not yet been subjected to empirical analysis. In this 2‐year prospective study, the pattern of social interactions related to the early presentation of self‐injury were examined to identify a potential association with an increase in self‐injury. Methods: The self‐injurious behaviour and social contact with adults of 16 children with intellectual disability (ID) with self‐injury of recent onset were observed at 3‐month intervals over 2 years. Results: Increase in self‐injury over a 2‐year period was positively correlated with a distribution of social contact relative to episodes of self‐injury that is consistent with a mutual social reinforcement paradigm. When this paradigm was operative, self‐injury was evoked under stable antecedent conditions over time but tended to evoke increasing levels of social interaction. Conclusions: These results support the hypothesis that increases in the frequency of early self‐injury in children with ID may be determined by social reinforcement with implications for early intervention and proactive identification of children at risk for increases in self‐injury