Temperature independent diffuse scattering and elastic lattice deformations in relaxor PbMg1/3Nb2/3O3

The results of diffuse neutron scattering experiment on PbMg1/3Nb2/3O3 single crystal above the Burns temperature are reported. It is shown that the high temperature elastic diffuse component is highly anisotropic in low-symmetry Brillouin zones and this anisotropy can be described using Huang scattering formalism assuming that the scattering originates from mesoscopic lattice deformations due to elastic defects. The qualitative agreement between this model and the experimental data is achieved with simple isotropic defects. It is demonstrated that weak satellite maxima near the Bragg reflections can be interpreted as the finite resolution effect.Comment: 7 pages, 7 figure

Spurious trend switching phenomena in financial markets

The observation of power laws in the time to extrema of volatility, volume and intertrade times, from milliseconds to years, are shown to result straightforwardly from the selection of biased statistical subsets of realizations in otherwise featureless processes such as random walks. The bias stems from the selection of price peaks that imposes a condition on the statistics of price change and of trade volumes that skew their distributions. For the intertrade times, the extrema and power laws results from the format of transaction data

Transverse Pressure and Strangeness Dynamics in Relativistic Heavy Ion Reactions

Transverse hadron spectra from proton-proton, proton-nucleus and nucleus-nucleus collisions from 2 AGeV to 21.3 ATeV are investigated within two independent transport approaches (HSD and UrQMD). For central Au+Au (Pb+Pb) collisions at energies above $E_{\rm lab}\sim$ 5 AGeV, the measured $K^{\pm}$ transverse mass spectra have a larger inverse slope parameter than expected from the default calculations. The additional pressure - as suggested by lattice QCD calculations at finite quark chemical potential $\mu_q$ and temperature $T$ - might be generated by strong interactions in the early pre-hadronic/partonic phase of central Au+Au (Pb+Pb) collisions. This is supported by a non-monotonic energy dependence of $v_2/$ in the present transport model.Comment: Proceedings of Strange Quark Matter 200

A new look at acid catalyzed deacetylation of carbohydrates : A regioselective synthesis and reactivity of 2-O-acetyl aryl glycopyranosides

Abstract In the present work we report that acetyl groups of per – acetylated aryl glycosides have different reactivity during the acidic deacetylation using HCl/EtOH in CHCl3, which leads to preferential deacetylation at O-3, O-4 and O-6. Thereby, the one-step preparation of 2-O-acetyl aryl glycosides with simple aglycon was accomplished for the first time. It was proved that the found reagent is to be general and unique for the preparation of series of 2-О-acetyl aryl glycosides. We have determined the influence of both carbohydrate moiety and the aglycon on the selectivity of deacetylation reaction by kinetic experiments. Using DFT/B3LYP/6-31G(d,p) and semi-empirical АМ1 methods we have found that the highest activation barrier is for 2-О-acetyl group. This completely explains the least reactivity of 2-О-acetyl group.Peer reviewe

Jets as a Probe of Dense Matter at RHIC

Jet quenching in the matter created in high energy nucleus-nucleus collisions provides a tomographic tool to probe the medium properties. Recent experimental results on jet production at the Relativistic Heavy-Ion Collider (RHIC) are reviewed. Jet properties in p+p and d+Au collisions have been measured, establishing the baseline for studying jet modification in heavy-ion collisions. Current progress on detailed studies of high transverse momentum production in Au+Au collisions is discussed, with an emphasis on dihadron correlation measurements.Comment: 8 pages, 9 figures. Plenary talk given at 17th International Conference on Ultra Relativistic Nucleus-Nucleus Collisions (Quark Matter 2004), Oakland, California, 11-17 Jan 2004. Submitted to J.Phys.

Adatom diffusion on vicinal surfaces with permeable steps

We study the behavior of single atoms on an infinite vicinal surface assuming certain degree of step permeability. Assuming complete lack of re-evaporation an ruling out nucleation the atoms will inevitably join kink sites at the steps but can do many attempts before that. Increasing the probability of step permeability or the kink spacing lead to increase of the number of steps crossed before incorporation of the atoms into kink sites. The asymmetry of the attachment-detachment kinetics (Ehrlich-Schwoebel effect) suppresses the step permeability and completely eliminates it in the extreme case of infinite Ehrlich-Schwoebel barrier. The average number of permeability events per atom scales with the average kink spacing. A negligibly small drift of the adatoms in a direction perpendicular to the steps leads to a significant asymmetry of the distribution of the permeability events the atoms thus visiting more distant steps in the direction of the drift.Comment: 12 pages, 6 figure

Structural heterogeneity and diffuse scattering in morphotropic lead zirconate-titanate single crystals

Complementary diffuse and inelastic synchrotron X-ray scattering measurements of lead zirconate-titanate single crystals with composition near the morphotropic phase boundary (x=0.475) are reported. In the temperature range 293 K < T < 400 K a highly anisotropic quasielastic diffuse scattering is observed. Above 400 K this scattering disappears. Its main features can be reproduced by model of inhomogeneous lattice deformations caused by inclusions of a tetragonal phase into a rhombohedral or monoclinic phase. This observation supports the idea that PZT at its morphotropic phase boundary is essentially structurally inhomogeneous.Comment: 4 pages, 4 figure