Effects of Orientations, Aspect Ratios, Pavement Materials and Vegetation Elements on Thermal Stress inside Typical Urban Canyons

The analysis of local climate conditions to test artificial urban boundaries and related climate hazards through modelling tools should become a common practice to inform public authorities about the benefits of planning alternatives. Different finishing materials and sheltering objects within urban canyons (UCs) can be tested, predicted and compared through quantitative and qualitative understanding of the relationships between the microclimatic environment and subjective thermal assessment. This process can work as support planning instrument in the early design phases as has been done in this study that aims to analyze the thermal stress within typical UCs of Bilbao (Spain) in summertime through the evaluation of Physiologically Equivalent Temperature using ENVI-met. The UCs are characterized by different orientations, height-to-width aspect ratios, pavement materials, trees’ dimensions and planting pattern. Firstly, the current situation was analyzed; secondly, the effects of asphalt and red brick stones as streets’ pavement materials were compared; thirdly, the benefits of vegetation elements were tested. The analysis demonstrated that orientation and aspect ratio strongly affect the magnitude and duration of the thermal peaks at pedestrian level; while the vegetation elements improve the thermal comfort up to two thermophysiological assessment classes. The outcomes of this study, were transferred and visualized into green planning recommendations for new and consolidated urban areas in Bilbao.The work leading to these results has received funding from COST Action TU0902, the European Community’s Seventh Framework Programme under Grant Agreement No. 308497, Project RAMSES—Reconciling Adaptation, Mitigation and Sustainable Development for Cities (2012–2017) and Diputación Foral de Bizkaia Exp. 6-12-TK-2010-0027, Project SICURB-ITS- Desarrollo de Sistemas para el análisis de la Contaminación atmosférica en zonas URBanas integrados en ITS (2010–2011)

Antiferromagnetic O(N) models in four dimensions

We study the antiferromagnetic O(N) model in the F_4 lattice. Monte Carlo simulations are applied for investigating the behavior of the transition for N=2,3. The numerical results show a first order nature but with a large correlation length. The $N \to \infty$ limit is also considered with analytical methods.Comment: 14 pages, 3 postscript figure

Halogen bonding stabilizes a cis-azobenzene derivative in the solid state: A crystallographic study

Crystals of trans- and cis-isomers of a fluorinated azobenzene derivative have been prepared and characterized by single-crystal X-ray diffraction. The presence of F atoms on the aromatic core of the azobenzene increases the lifetime of the metastable cis-isomer, allowing single crystals of the cis-azobenzene to be grown. Structural analysis on the cis-azobenzene, complemented with density functional theory calculations, highlights the active role of the halogen-bond contact (N...I synthon) in promoting the stabilization of the cis-isomer. The presence of a long aliphatic chain on the azobenzene unit induces a phase segregation that stabilizes the molecular arrangement for both the trans- and cis-isomers. Due to the rarity of cis-azobenzene crystal structures in the literature, our paper makes a step towards understanding the role of non-covalent interactions in driving the packing of metastable azobenzene isomers. This is expected to be important in the future rational design of solid-state, photoresponsive materials based on halogen bonding. We show by single-crystal X-ray diffraction studies and computational analysis that halogen bonding can stabilize a metastable cis-azobenzene derivative in the solid state

Temperature chaos in 3D Ising Spin Glasses is driven by rare events

Temperature chaos has often been reported in literature as a rare-event driven phenomenon. However, this fact has always been ignored in the data analysis, thus erasing the signal of the chaotic behavior (still rare in the sizes achieved) and leading to an overall picture of a weak and gradual phenomenon. On the contrary, our analysis relies on a large-deviations functional that allows to discuss the size dependencies. In addition, we had at our disposal unprecedentedly large configurations equilibrated at low temperatures, thanks to the Janus computer. According to our results, when temperature chaos occurs its effects are strong and can be felt even at short distances.Comment: 5 pages, 5 figure

Simultaneous analysis of elastic scattering and transfer/breakup channels for the 6He+208Pb reaction at energies near the Coulomb barrier

The elastic and alpha-production channels for the 6He+208Pb reaction are investigated at energies around the Coulomb barrier (E_{lab}=14, 16, 18, 22, and 27 MeV). The effect of the two-neutron transfer channels on the elastic scattering has been studied within the Coupled-Reaction-Channels (CRC) method. We find that the explicit inclusion of these channels allows a simultaneous description of the elastic data and the inclusive alpha cross sections at backward angles. Three-body Continuum-Discretized Coupled-Channels (CDCC) calculations are found to reproduce the elastic data, but not the transfer/breakup data. The trivially-equivalent local polarization potential (TELP) derived from the CRC and CDCC calculations are found to explain the features found in previous phenomenological optical model calculations for this system.Comment: 7 pages, 6 figures (replaced with updated version