Spectroscopy of Stardust from 200nm to 16µM (with a gap in the middle)

UV/Vis and IR spectroscopy are complementary, non-destructive techniques that can be used to identify the presence of a range of organic and inorganic, hydrated and anhydrous minerals within micron-sized grains. We look forward to applying these techniques to the Stardust materials

Büchwald-Hartwig reaction applied to synthesis of new luminescent liquid crystal triarylamines derived from isoxazoles

© 2015 Taylor & Francis Group, LLC. The present work describes the synthesis and characterization of novel series of triarylamines isoxazoles (TAA) addressed to the organic photovoltaic materials. Diarylisoxazoles were synthesized by sequential [3+2] 1,3-dipolar cycloaddition reaction between arylnitrile oxides and selected arylalkenes followed by MnO2-oxidation. Isoxazoles were coupled to diarylamines by Büchwald-Hartwig reaction to afford desired compounds 6a-k. Some TAA display liquid-crystalline behaviour and UV-Vis absorption and fluorescence emission were analysed for all samples of TAA 6a-k

Impacts of in vivo and in vitro exposures to tamoxifen: comparative effects on human cells and marine organisms

Tamoxifen (TAM) is a first generation-SERM administered for hormone receptor-positive (HER+) breast cancer in both pre- and post-menopausal patients and may undergo metabolic activation in organisms that share similar receptors and thus face comparable mechanisms of response. The present study aimed to assess whether environmental trace concentrations of TAM are bioavailable to the filter feeder M. galloprovincialis (100 ng L-1) and to the deposit feeder N. diversicolor (0.5, 10, 25 and 100 ng L-1) after 14 days of exposure. Behavioural impairment (burrowing kinetic), neurotoxicity (AChE activity), endocrine disruption by alkali-labile phosphate (ALP) content, oxidative stress (SOD, CAT, GPXs activities), biotransformation (GST activity), oxidative damage (LPO) and genotoxicity (DNA damage) were assessed. Moreover, this study also pertained to compare TAM cytotoxicity effects to mussels and targeted human (i.e. immortalized retinal pigment epithelium - RPE; and human transformed endothelial cells - HeLa) cell lines, in a range of concentrations from 0.5 ng L-1 to 50 μg L-1. In polychaetes N. diversicolor, TAM exerted remarkable oxidative stress and damage at the lowest concentration (0.5 ng L-1), whereas significant genotoxicity was reported at the highest exposure level (100 ng L-1). In mussels M. galloprovincialis, 100 ng L-1 TAM caused endocrine disruption in males, neurotoxicity, and an induction in GST activity and LPO byproducts in gills, corroborating in genotoxicity over the exposure days. Although cytotoxicity assays conducted with mussel haemocytes following in vivo exposure was not effective, in vitro exposure showed to be a feasible alternative, with comparable sensitivity to human cell line (HeLa).info:eu-repo/semantics/publishedVersio

Observation of an orbital interaction-induced Feshbach resonance in 173-Yb

We report on the experimental observation of a novel inter-orbital Feshbach resonance in ultracold 173-Yb atoms, which opens the possibility of tuning the interactions between the 1S0 and 3P0 metastable state, both possessing vanishing total electronic angular momentum. The resonance is observed at experimentally accessible magnetic field strengths and occurs universally for all hyperfine state combinations. We characterize the resonance in the bulk via inter-orbital cross-thermalization as well as in a three-dimensional lattice using high-resolution clock-line spectroscopy.Comment: 5 pages, 4 figure

Experimental Demonstration of a Structured Material with Extreme Effective Parameters at Microwaves

Following our recent theoretical studies [M. G. Silveirinha, C. A. Fernandes, Phys. Rev. B, 78, 033108, 2008], it is experimentally verified that an array of crossed metallic wires may behave as a nonresonant material with extremely large index of refraction at microwaves, and may enable the realization of ultra-subwavelength waveguides.Comment: accepted for publication in Applied Physics Letters (in press). Applied Physics Letters (in press) (2008

Complex critical exponents for percolation transitions in Josephson-junction arrays, antiferromagnets, and interacting bosons

We show that the critical behavior of quantum systems undergoing a percolation transition is dramatically affected by their topological Berry phase $2\pi\rho$. For irrational $\rho$, we demonstrate that the low-energy excitations of diluted Josephson-junctions arrays, quantum antiferromagnets, and interacting bosons are spinless fermions with fractal spectrum. As a result, critical properties not captured by the usual Ginzburg-Landau-Wilson description of phase transitions emerge, such as complex critical exponents, log-periodic oscillations and dynamically broken scale-invariance.Comment: revised version accepted for publication in Phys. Rev. Let

Foreign capital and gender differences in promotions: Evidence from large Brazilian manufacturing firms

This paper examines whether there exists obstacles hindering women's ascension in the largest firms of the Brazilian manufacturing industry. In particular, we check whether gender matters in the time it takes to get a promotion to a managerial position. Once we control for covariate-dependent censoring, we find significant evidence that foreign-owned firms feature less gender differences in promotions than domestic firms. The same applies in other dimensions of career progress, namely, wage growth and promotion likelihood. It turns out that wage gains after promotion contribute to generating wage differential between males and females only within domestic firms. This is consistent with statistical discrimination and with the self-selection that results from employees optimally choosing which jobs to apply for. Jobs in domestic firms offer more flexibility in terms of hours per week, whereas multinationals compete for the most career-concerned workers

Património geológico do Parque Nacional da Peneda-Gerês, valorização e divulgação para o ensino das geociências

Direcção Regional de Ensino do AlgarveComissão Nacional da UNESCO PortugalAutoridade Florestal Nacional (AFN)Ano Internacional das Florestas 201