Disorder effects on the static scattering function of star branched polymers

We present an analysis of the impact of structural disorder on the static scattering function of f-armed star branched polymers in d dimensions. To this end, we consider the model of a star polymer immersed in a good solvent in the presence of structural defects, correlated at large distances r according to a power law \sim r^{-a}. In particular, we are interested in the ratio g(f) of the radii of gyration of star and linear polymers of the same molecular weight, which is a universal experimentally measurable quantity. We apply a direct polymer renormalization approach and evaluate the results within the double \varepsilon=4-d, \delta=4-a-expansion. We find an increase of g(f) with an increasing \delta. Therefore, an increase of disorder correlations leads to an increase of the size measure of a star relative to linear polymers of the same molecular weight.Comment: 17 pages, 7 figure

Shapes of macromolecules in good solvents: field theoretical renormalization group approach

In this paper, we show how the method of field theoretical renormalization group may be used to analyze universal shape properties of long polymer chains in porous environment. So far such analytical calculations were primarily focussed on the scaling exponents that govern conformational properties of polymer macromolecules. However, there are other observables that along with the scaling exponents are universal (i.e. independent of the chemical structure of macromolecules and of the solvent) and may be analyzed within the renormalization group approach. Here, we address the question of shape which is acquired by the long flexible polymer macromolecule when it is immersed in a solvent in the presence of a porous environment. This question is of relevance for understanding of the behavior of macromolecules in colloidal solutions, near microporous membranes, and in cellular environment. To this end, we consider a previously suggested model of polymers in d-dimensions [V. Blavats'ka, C. von Ferber, Yu. Holovatch, Phys. Rev. E, 2001, 64, 041102] in an environment with structural obstacles, characterized by a pair correlation function h(r), that decays with distance r according to a power law: h(r) \sim r-a. We apply the field-theoretical renormalization group approach and estimate the size ratio / and the asphericity ratio \hat{A}_d up to the first order of a double \epsilon=4-d, \delta=4-a expansion.Comment: 20 pages, 5 figure

Scaling in public transport networks

We analyse the statistical properties of public transport networks. These networks are defined by a set of public transport routes (bus lines) and the stations serviced by these. For larger networks these appear to possess a scale-free structure, as it is demonstrated e.g. by the Zipf law distribution of the number of routes servicing a given station or for the distribution of the number of stations which can be visited from the chosen one without changing the means of transport. Moreover, a rather particular feature of the public transport network is that many routes service common subsets of stations. We discuss the possibility of new scaling laws that govern intrinsic features of such subsets.Comment: 9 pages, 4 figure

Entropic equation of state and scaling functions near the critical point in scale-free networks

We analyze the entropic equation of state for a many-particle interacting system in a scale-free network. The analysis is performed in terms of scaling functions which are of fundamental interest in the theory of critical phenomena and have previously been theoretically and experimentally explored in the context of various magnetic, fluid, and superconducting systems in two and three dimensions. Here, we obtain general scaling functions for the entropy, the constant-field heat capacity, and the isothermal magnetocaloric coefficient near the critical point in scale-free networks, where the node-degree distribution exponent $\lambda$ appears to be a global variable and plays a crucial role, similar to the dimensionality $d$ for systems on lattices. This extends the principle of universality to systems on scale-free networks and allows quantification of the impact of fluctuations in the network structure on critical behavior.Comment: 8 pages, 4 figure

Network Harness: Metropolis Public Transport

We analyze the public transport networks (PTNs) of a number of major cities of the world. While the primary network topology is defined by a set of routes each servicing an ordered series of given stations, a number of different neighborhood relations may be defined both for the routes and the stations. The networks defined in this way display distinguishing properties, the most striking being that often several routes proceed in parallel for a sequence of stations. Other networks with real-world links like cables or neurons embedded in two or three dimensions often show the same feature - we use the car engineering term "harness" for such networks. Geographical data for the routes reveal surprising self-avoiding walk (SAW) properties. We propose and simulate an evolutionary model of PTNs based on effectively interacting SAWs that reproduces the key features.Comment: 5 pages, 4 figure

Star polymers in correlated disorder

We analyze the impact of a porous medium (structural disorder) on the scaling of the partition function of a star polymer immersed in a good solvent. We show that corresponding scaling exponents change if the disorder is long-range-correlated and calculate the exponents in the new universality class. A notable finding is that star and chain polymers react in qualitatively different manner on the presence of disorder: the corresponding scaling exponents increase for chains and decrease for stars. We discuss the physical consequences of this difference.Comment: Submitted to the Proceedings of the International Conference "Path Integrals - New Trends and Perspectives", September 23-28, 2007, Dresden, German

Entropy-induced separation of star polymers in porous media

We present a quantitative picture of the separation of star polymers in a solution where part of the volume is influenced by a porous medium. To this end, we study the impact of long-range-correlated quenched disorder on the entropy and scaling properties of $f$-arm star polymers in a good solvent. We assume that the disorder is correlated on the polymer length scale with a power-law decay of the pair correlation function $g(r) \sim r^{-a}$. Applying the field-theoretical renormalization group approach we show in a double expansion in $\epsilon=4-d$ and $\delta=4-a$ that there is a range of correlation strengths $\delta$ for which the disorder changes the scaling behavior of star polymers. In a second approach we calculate for fixed space dimension $d=3$ and different values of the correlation parameter $a$ the corresponding scaling exponents $\gamma_f$ that govern entropic effects. We find that $\gamma_f-1$, the deviation of $\gamma_f$ from its mean field value is amplified by the disorder once we increase $\delta$ beyond a threshold. The consequences for a solution of diluted chain and star polymers of equal molecular weight inside a porous medium are: star polymers exert a higher osmotic pressure than chain polymers and in general higher branched star polymers are expelled more strongly from the correlated porous medium. Surprisingly, polymer chains will prefer a stronger correlated medium to a less or uncorrelated medium of the same density while the opposite is the case for star polymers.Comment: 14 pages, 7 figure