Effects of agricultural land management changes on surface water quality: A review of meso-scale catchment research

Measuring the environmental impacts of agricultural practice is critical for policy formulation and review, including policies implemented to improve water quality. Here, studies that measured such impacts in surface waters of hydrologically diverse meso-scale catchments (1–100 km2) were reviewed. Positive water quality effects were measured in 17 out of 25 reviewed studies. Successful farm practices included improved landscape engineering, improved crop management and reductions in farming intensity. Positive effects occurred from 1 to 10 years after the measures were implemented, with the response time broadly increasing with catchment size. However, it took from 4 to 20 years to confidently detect the effects. Policy makers and scientists should account for these hydrological and biogeochemical time lags when setting policy and planning monitoring in meso-scale catchments. To successfully measure policy effects, rates of practice change should also be measured with targeted water quality parameters

The effects of hyperoxia on repeated sprint cycling performance & muscle fatigue

ObjectivesHyperoxia (>21% oxygen) can evoke performance improvements in aerobic and anaerobic exercise. The aims of the current study were to determine the effects of breathing hyperoxic gas (fraction of inspired oxygen [FiO2] 1.00) on repeated cycle performance, and to assess the nature and extent of fatigue after intermittent sprinting.Design & methodsTesting (n = 14 males) comprised two visits to the laboratory. Each session involved 10 × 15 s repeated cycle sprints breathing FiO2 1.00 (hyperoxia) or FiO2 0.21 (normoxia). Muscle fatigue was measured pre and post sprints using Maximal Voluntary Contraction (MVC), voluntary activation (VA) and potentiated doublet twitch (PTF). Blood lactate (BLa) was taken between sprints.Paired samples t-tests were used to examine difference between conditions in power output (peak and mean Watts) and BLa. Two-way ANOVA was used to examine fatigue variables pre and post sprints according to condition.ResultsMean power output was 4% greater in hyperoxia (p < 0.01), with no difference in peak power (p > 0.05). There was a significant increase in BLa in hyperoxia compared with normoxia (p < 0.01) in sprints 4 and 8, as well as meaningful difference in sprints 4–10. There was no significant difference in fatigue factors (MVC, VA and PTF) (p > 0.05) in response to the cycling, although a large drop in PTF occurred in both conditions.ConclusionHyperoxia can elicit improvements in mean cycling power, with no significant change in post exercise muscle fatigue. Hyperoxia as a training aid may provide performance enhancing effects during repeated sprint cycling by reducing concurrent muscle fatigue, primarily via peripheral factors

Technical Note: Field experiences using UV/VIS sensors for high-resolution monitoring of nitrate in groundwater

peer-reviewedTwo different in situ spectrophotometers are compared that were used in the field to determine nitrate-nitrogen (NO3-N) concentrations at two distinct spring discharge sites. One sensor was a double wavelength spectrophotometer (DWS) and the other a multiple wavelength spectrophotometer (MWS). The objective of the study was to review the hardware options, determine ease of calibration, accuracy, influence of additional substances and to assess positive and negative aspects of the two sensors as well as troubleshooting and trade-offs. Both sensors are sufficient to monitor highly time-resolved NO3-N concentrations in emergent groundwater. However, the chosen path length of the sensors had a significant influence on the sensitivity and the range of detectable NO3-N. The accuracy of the calculated NO3-N concentrations of the sensors can be affected if the content of additional substances such as turbidity, organic matter, nitrite or hydrogen carbonate significantly varies after the sensors have been calibrated to a particular water matrix. The MWS offers more possibilities for calibration and error detection but requires more expertise compared with the DWS.The authors would like to acknowledge the Teagasc Walsh Fellowship scheme for funding the study in Ireland, and the German federal Ministry of Education and Research (BMBF) for sponsoring the SMART-project (grant no. 02WM1079-1086, 02WM1211-1212) for the study in Jordan.Teagasc Walsh Fellowship Programm

Mobilisation or dilution? Nitrate response of karst springs to high rainfall events

peer-reviewedNitrate (NO3−) contamination of groundwater associated with agronomic activity is of major concern in many countries. Where agriculture, thin free draining soils and karst aquifers coincide, groundwater is highly vulnerable to nitrate contamination. As residence times and denitrification potential in such systems are typically low, nitrate can discharge to surface waters unabated. However, such systems also react quickest to agricultural management changes that aim to improve water quality. In response to storm events, nitrate concentrations can alter significantly, i.e. rapidly decreasing or increasing concentrations. The current study examines the response of a specific karst spring situated on a grassland farm in South Ireland to rainfall events utilising high-resolution nitrate and discharge data together with on-farm borehole groundwater fluctuation data. Specifically, the objectives of the study are to formulate a scientific hypothesis of possible scenarios relating to nitrate responses during storm events, and to verify this hypothesis using additional case studies from the literature. This elucidates the controlling key factors that lead to mobilisation and/or dilution of nitrate concentrations during storm events. These were land use, hydrological condition and karstification, which in combination can lead to differential responses of mobilised and/or diluted nitrate concentrations. Furthermore, the results indicate that nitrate response in karst is strongly dependent on nutrient source, whether mobilisation and/or dilution occur and on the pathway taken. This will have consequences for the delivery of nitrate to a surface water receptor. The current study improves our understanding of nitrate responses in karst systems and therefore can guide environmental modellers, policy makers and drinking water managers with respect to the regulations of the European Union (EU) Water Framework Directive (WFD). In future, more research should focus on the high-resolution monitoring of karst aquifers to capture the high variability of hydrochemical processes, which occur at time intervals of hours to days.Teagasc Walsh Fellowship Programm

Influence of Land Management on Soil Erosion, Connectivity and Sediment Delivery in Agricultural Catchments:Closing the Sediment Budget

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