Coal desulfurization by low temperature chlorinolysis, phase 2

An engineering scale reactor system was constructed and operated for the evaluation of five high sulfur bituminous coals obtained from Kentucky, Ohio, and Illinois. Forty-four test runs were conducted under conditions of 100 by 200 mesh coal,solvents - methlychloroform and water, 60 to 130 C, 0 to 60 psig, 45 to 90 minutes, and gaseous chlorine flow rate of up to 24 SCFH. Sulfur removals demonstrated for the five coals were: maximum total sulfur removal of 46 to 89% (4 of 5 coals with methylchloroform) and 0 to 24% with water. In addition, an integrated continuous flow mini-pilot plant was designed and constructed for a nominal coal rate of 2 kilograms/hour which will be operated as part of the follow-on program. Equipment flow sheets and design drawings are included for both the batch and continuous flow mini-pilot plants

Coal desulfurization by low temperature chlorinolysis, phase 1

The reported activity covers laboratory scale experiments on twelve bituminous, sub-bituminous and lignite coals, and preliminary design and specifications for bench-scale and mini-pilot plant equipment

Using Classical Probability To Guarantee Properties of Infinite Quantum Sequences

We consider the product of infinitely many copies of a spin-$1\over 2$ system. We construct projection operators on the corresponding nonseparable Hilbert space which measure whether the outcome of an infinite sequence of $\sigma^x$ measurements has any specified property. In many cases, product states are eigenstates of the projections, and therefore the result of measuring the property is determined. Thus we obtain a nonprobabilistic quantum analogue to the law of large numbers, the randomness property, and all other familiar almost-sure theorems of classical probability.Comment: 7 pages in LaTe

Probability distribution of residence times of grains in models of ricepiles

We study the probability distribution of residence time of a grain at a site, and its total residence time inside a pile, in different ricepile models. The tails of these distributions are dominated by the grains that get deeply buried in the pile. We show that, for a pile of size $L$, the probabilities that the residence time at a site or the total residence time is greater than $t$, both decay as $1/t(\ln t)^x$ for $L^{\omega} \ll t \ll \exp(L^{\gamma})$ where $\gamma$ is an exponent $\ge 1$, and values of $x$ and $\omega$ in the two cases are different. In the Oslo ricepile model we find that the probability that the residence time $T_i$ at a site $i$ being greater than or equal to $t$, is a non-monotonic function of $L$ for a fixed $t$ and does not obey simple scaling. For model in $d$ dimensions, we show that the probability of minimum slope configuration in the steady state, for large $L$, varies as $\exp(-\kappa L^{d+2})$ where $\kappa$ is a constant, and hence $\gamma = d+2$.Comment: 13 pages, 23 figures, Submitted to Phys. Rev.

Equilibrium of anchored interfaces with quenched disordered growth

The roughening behavior of a one-dimensional interface fluctuating under quenched disorder growth is examined while keeping an anchored boundary. The latter introduces detailed balance conditions which allows for a thorough analysis of equilibrium aspects at both macroscopic and microscopic scales. It is found that the interface roughens linearly with the substrate size only in the vicinity of special disorder realizations. Otherwise, it remains stiff and tilted.Comment: 6 pages, 3 postscript figure

Exact moments in a continuous time random walk with complete memory of its history

We present a continuous time generalization of a random walk with complete memory of its history [Phys. Rev. E 70, 045101(R) (2004)] and derive exact expressions for the first four moments of the distribution of displacement when the number of steps is Poisson distributed. We analyze the asymptotic behavior of the normalized third and fourth cumulants and identify new transitions in a parameter regime where the random walk exhibits superdiffusion. These transitions, which are also present in the discrete time case, arise from the memory of the process and are not reproduced by Fokker-Planck approximations to the evolution equation of this random walk.Comment: Revtex4, 10 pages, 2 figures. v2: applications discussed, clarity improved, corrected scaling of third momen

Open vs.Closed standards for ambient intelligence: an exploratory study of adoption

Emerging forms of structurally complex information systems, such as Ambient Intelligence (AmI), requires the integration of a range of technologies. To enable such systems’ development there is a reliance on interoperability standards. However, due to their inherent characteristics, the adoption of open or closed standards by technology vendors can have impacts the later stages of the adoption and diffusion of systems. This paper reports on research-in-progress which explores the adoption of open and closed standards by technology vendors engaged in AmI development. Existing models of innovation adoption and diffusion fail to adequately account for adoption in more complex technological contexts. In order to address such deficiencies, current perspectives on standards are discussed, before a conceptual framework for structuring the research is proposed which integrates both existing adoption theory and standards-oriented research. The use of the European Consumer Electronics sector as a unit of analysis is discussed, before concluding with an overview of how the study will progress

Entropy-driven cutoff phenomena

In this paper we present, in the context of Diaconis' paradigm, a general method to detect the cutoff phenomenon. We use this method to prove cutoff in a variety of models, some already known and others not yet appeared in literature, including a chain which is non-reversible w.r.t. its stationary measure. All the given examples clearly indicate that a drift towards the opportune quantiles of the stationary measure could be held responsible for this phenomenon. In the case of birth- and-death chains this mechanism is fairly well understood; our work is an effort to generalize this picture to more general systems, such as systems having stationary measure spread over the whole state space or systems in which the study of the cutoff may not be reduced to a one-dimensional problem. In those situations the drift may be looked for by means of a suitable partitioning of the state space into classes; using a statistical mechanics language it is then possible to set up a kind of energy-entropy competition between the weight and the size of the classes. Under the lens of this partitioning one can focus the mentioned drift and prove cutoff with relative ease.Comment: 40 pages, 1 figur

Truncation effects in superdiffusive front propagation with L\'evy flights

A numerical and analytical study of the role of exponentially truncated L\'evy flights in the superdiffusive propagation of fronts in reaction-diffusion systems is presented. The study is based on a variation of the Fisher-Kolmogorov equation where the diffusion operator is replaced by a $\lambda$-truncated fractional derivative of order $\alpha$ where $1/\lambda$ is the characteristic truncation length scale. For $\lambda=0$ there is no truncation and fronts exhibit exponential acceleration and algebraic decaying tails. It is shown that for $\lambda \neq 0$ this phenomenology prevails in the intermediate asymptotic regime $(\chi t)^{1/\alpha} \ll x \ll 1/\lambda$ where $\chi$ is the diffusion constant. Outside the intermediate asymptotic regime, i.e. for $x > 1/\lambda$, the tail of the front exhibits the tempered decay $\phi \sim e^{-\lambda x}/x^{(1+\alpha)}$, the acceleration is transient, and the front velocity, $v_L$, approaches the terminal speed $v_* = (\gamma - \lambda^\alpha \chi)/\lambda$ as $t\to \infty$, where it is assumed that $\gamma > \lambda^\alpha \chi$ with $\gamma$ denoting the growth rate of the reaction kinetics. However, the convergence of this process is algebraic, $v_L \sim v_* - \alpha /(\lambda t)$, which is very slow compared to the exponential convergence observed in the diffusive (Gaussian) case. An over-truncated regime in which the characteristic truncation length scale is shorter than the length scale of the decay of the initial condition, $1/\nu$, is also identified. In this extreme regime, fronts exhibit exponential tails, $\phi \sim e^{-\nu x}$, and move at the constant velocity, $v=(\gamma - \lambda^\alpha \chi)/\nu$.Comment: Accepted for publication in Phys. Rev. E (Feb. 2009