Shape-dependent CO2 hydrogenation to methanol over Cu2O nanocubes supported on ZnO

The hydrogenation of CO2 to methanol over Cu/ZnO-based catalysts is highly sensitive to the surface composition and catalyst structure. Thus, its optimization requires a deep understanding of the influence of the pre-catalyst structure on its evolution under realistic reaction conditions, including the formation and stabilization of the most active sites. Here, the role of the pre-catalyst shape (cubic vs spherical) in the activity and selectivity of ZnO-supported Cu nanoparticles was investigated during methanol synthesis. A combination of ex situ, in situ, and operando microscopy, spectroscopy, and diffraction methods revealed drastic changes in the morphology and composition of the shaped pre-catalysts under reaction conditions. In particular, the rounding of the cubes and partial loss of the (100) facets were observed, although such motifs remained in smaller domains. Nonetheless, the initial pre-catalyst structure was found to strongly affect its subsequent transformation in the course of the CO2 hydrogenation reaction and activity/selectivity trends. In particular, the cubic Cu particles displayed an increased activity for methanol production, although at the cost of a slightly reduced selectivity when compared to similarly sized spherical particles. These findings were rationalized with the help of density functional theory calculations.Peer ReviewedPostprint (published version

A comparison of global agricultural monitoring systems and current gaps

Global and regional scale agricultural monitoring systems aim to provide up-to-date information regarding food production to different actors and decision makers in support of global and national food security. To help reduce price volatility of the kind experienced between 2007 and 2011, a global system of agricultural monitoring systems is needed to ensure the coordinated flow of information in a timely manner for early warning purposes. A number of systems now exist that fill this role. This paper provides an overview of the eight main global and regional scale agricultural monitoring systems currently in operation and compares them based on the input data and models used, the outputs produced and other characteristics such as the role of the analyst, their interaction with other systems and the geographical scale at which they operate. Despite improvements in access to high resolution satellite imagery over the last decade and the use of numerous remote-sensing based products by the different systems, there are still fundamental gaps. Based on a questionnaire, discussions with the system experts and the literature, we present the main gaps in the data and in the methods. Finally, we propose some recommendations for addressing these gaps through ongoing improvements in remote sensing, harnessing new and innovative data streams and the continued sharing of more and more data

Impact of COVID-19 on cardiovascular testing in the United States versus the rest of the world

Objectives: This study sought to quantify and compare the decline in volumes of cardiovascular procedures between the United States and non-US institutions during the early phase of the coronavirus disease-2019 (COVID-19) pandemic. Background: The COVID-19 pandemic has disrupted the care of many non-COVID-19 illnesses. Reductions in diagnostic cardiovascular testing around the world have led to concerns over the implications of reduced testing for cardiovascular disease (CVD) morbidity and mortality. Methods: Data were submitted to the INCAPS-COVID (International Atomic Energy Agency Non-Invasive Cardiology Protocols Study of COVID-19), a multinational registry comprising 909 institutions in 108 countries (including 155 facilities in 40 U.S. states), assessing the impact of the COVID-19 pandemic on volumes of diagnostic cardiovascular procedures. Data were obtained for April 2020 and compared with volumes of baseline procedures from March 2019. We compared laboratory characteristics, practices, and procedure volumes between U.S. and non-U.S. facilities and between U.S. geographic regions and identified factors associated with volume reduction in the United States. Results: Reductions in the volumes of procedures in the United States were similar to those in non-U.S. facilities (68% vs. 63%, respectively; p = 0.237), although U.S. facilities reported greater reductions in invasive coronary angiography (69% vs. 53%, respectively; p < 0.001). Significantly more U.S. facilities reported increased use of telehealth and patient screening measures than non-U.S. facilities, such as temperature checks, symptom screenings, and COVID-19 testing. Reductions in volumes of procedures differed between U.S. regions, with larger declines observed in the Northeast (76%) and Midwest (74%) than in the South (62%) and West (44%). Prevalence of COVID-19, staff redeployments, outpatient centers, and urban centers were associated with greater reductions in volume in U.S. facilities in a multivariable analysis. Conclusions: We observed marked reductions in U.S. cardiovascular testing in the early phase of the pandemic and significant variability between U.S. regions. The association between reductions of volumes and COVID-19 prevalence in the United States highlighted the need for proactive efforts to maintain access to cardiovascular testing in areas most affected by outbreaks of COVID-19 infection

First Sagittarius A* Event Horizon Telescope Results. VII. Polarization of the Ring

The Event Horizon Telescope observed the horizon-scale synchrotron emission region around the Galactic center supermassive black hole, Sagittarius A* (Sgr A*), in 2017. These observations revealed a bright, thick ring morphology with a diameter of 51.8 ± 2.3 μas and modest azimuthal brightness asymmetry, consistent with the expected appearance of a black hole with mass M ≈ 4 × 106 M ⊙. From these observations, we present the first resolved linear and circular polarimetric images of Sgr A*. The linear polarization images demonstrate that the emission ring is highly polarized, exhibiting a prominent spiral electric vector polarization angle pattern with a peak fractional polarization of ∼40% in the western portion of the ring. The circular polarization images feature a modestly (∼5%–10%) polarized dipole structure along the emission ring, with negative circular polarization in the western region and positive circular polarization in the eastern region, although our methods exhibit stronger disagreement than for linear polarization. We analyze the data using multiple independent imaging and modeling methods, each of which is validated using a standardized suite of synthetic data sets. While the detailed spatial distribution of the linear polarization along the ring remains uncertain owing to the intrinsic variability of the source, the spiraling polarization structure is robust to methodological choices. The degree and orientation of the linear polarization provide stringent constraints for the black hole and its surrounding magnetic fields, which we discuss in an accompanying publication

Comparison of Global and Regional Land Cover Maps with Statistical Information for the Agricultural Domain in Africa

Accurate information within the agricultural area domain is particularly important for crop monitoring for the purpose of food security. Several institutions monitoring crop status in food-insecure countries and in an early warning systems context are highly interested in crop distribution and crop extent maps. Also the inter-annual variations of crop areas are of high interest and very difficult to produce in highly fragmented rural landscapes as they are commonly found in many African countries. This paper will outline the comparison of four sources of land cover data to determine which product is the most suitable for agricultural monitoring and for the subsequent development of a crop mask, an important input to both food security and monitoring of agricultural expansion. Whereas in earlier papers a global comparison of land cover products was undertaken (Fritz and See, 2005; See and Fritz, 2005), this paper focuses on the agricultural domain in Africa.JRC.H.4-Monitoring Agricultural Resource

14-19 reforms: QCA Centre research study, commentary on the baseline of evidence 2007-2008

This report forms part of a baseline of evidence on the existing situation for 14 to 19 year-olds. In future years, this baseline can be used to help identify changes over time. The findings come from a year-long study of 45 institutions involved in delivering 14-19 education and training. These 45 case studies are representative of the range of relevant institutions in England, including schools, colleges, special projects, and the private sector. All have agreed to continue as part of the ongoing evaluation until 2013/14. The baseline of evidence includes interviews with students in years 11 and 12, governors, staff, parents/carers and partners, and surveys of staff and students, official statistics, and documents from each centre. Findings are presented in relation to four key objectives of the reforms – increasing student enjoyment, achievement, participation, and preparation for citizenship