278 research outputs found
A Hierarchy of Transport Approximations for High Energy Heavy (HZE) Ions
The transport of high energy heavy (HZE) ions through bulk materials is studied neglecting energy dependence of the nuclear cross sections. A three term perturbation expansion appears to be adequate for most practical applications for which penetration depths are less than 30 g per sq cm of material. The differential energy flux is found for monoenergetic beams and for realistic ion beam spectral distributions. An approximate formalism is given to estimate higher-order terms
Assessment of pesticide residues in tomatoes and watermelons (fruits) from markets in Dar es Salaam, Tanzania
This study investigated the levels of pesticide residues in selected fruits from major markets in Dar es Salaam city. Samples of tomatoes and watermelons were analysed for eighteen organochlorine, organophosphorus and pyrethroid pesticide residues. Extraction was performed using acetone followed by dichloromethane: cyclohexane mixture and the extracts were cleanedup using florisil. The compounds were determined by gas chromatography–mass spectrometry (GC–MS). Pesticides and metabolites were detected in 95.8% of the samples. The compounds detected included chlorpyrifos, α-endosulfan, β-endosulfan and cypermethrin and their highest concentrations were 3810 ± 50, 370 ± 20, 120 ± 6 and 50 ± 4 ng/g, respectively. Others were p,p'- DDD, o,p'-DDD, p,p'-DDE and α-HCH with highest concentrations varying from 1 ± 0.5 to 20 ± 1.2 ng/g. There were no significant variations in concentrations of the pesticide residues between the fruits and among the sampling sites, indicating similarities in contamination patterns. The concentrations of the contaminants were above the maximum residue limits (MRLs) in 41.7% to 50% of the tomatoes and watermelons indicating risks and concerns for public health. The Tanzanian agrochemicals and food regulatory agencies (e.g. TPRI, TFDA and TBS) and the government in general should ensure strict applications of laws that regulate pesticides in the country and develop effective educational programmes for farmers to apply good agricultural practices such as reducing the use of pesticides, applying appropriate pesticides and doses, and restrict the spray before harvesting. The consumers should thoroughly wash or process the fruits to reduce the levels.Keywords: Pesticides, Fruits, Food, Contamination, Tanzani
Determination of Levels of Organochlorine, Organophosphorus, and Pyrethroid Pesticide Residues in Vegetables from Markets in Dar es Salaam by GC-MS
This study investigated the levels of pesticides and metabolites in vegetables from major markets in Dar es Salaam city, Tanzania. Samples of fresh cabbage, spinach, and onions from the markets were analysed for pesticide residues. Extraction was performed using acetone followed by dichloromethane : cyclohexane mixture and the extracts were cleaned up using Florisil. The compounds were determined by gas chromatography-mass spectrometry (GC-MS). Pesticides and metabolites were detected in 72.2% of the samples. The detected pesticide residues and their highest mean concentrations were p,p′-DDT 4.00 × 10−3 mg/kg, p,p′-DDD 6.40 × 10−1 mg/kg, o,p′-DDD 1.00 × 10−2 mg/kg, α-endosulfan 6.00 × 10−1 mg/kg, β-endosulfan 2.10 × 10−1 mg/kg, chlorpyrifos 3.00 mg/kg, and cypermethrin 4.00 × 10−2 mg/kg. The most frequently detected compounds were p,p′-DDD and chlorpyrifos. The order of contamination was spinach > cabbage > onions. Generally, there were no significant variations in concentrations of pesticide residues among samples and sampling sites, which indicated similarities in contamination patterns. The concentrations of contaminants were above the maximum residue limits (MRLs) in 33.3–50% of the samples. The findings indicated risks and concerns for public health
A Multi-Area Architecture for Real-Time Feedback-Based Optimization of Distribution Grids
A challenge in transmission-distribution coordination is how to quickly and
reliably coordinate Distributed Energy Resources (DERs) across large
multi-stakeholder Distribution Networks (DNs) to support the Transmission
Network (TN), while ensuring operational constraints continue to be met within
the DN. Here we propose a hierarchical feedback-based control architecture for
coordination of DERs in DNs, enabling the DN to quickly respond to power
set-point requests from the Transmission System Operator (TSO) while
maintaining local DN constraints. Our scheme allows for multiple
independently-managed areas within the DN to optimize their local resources
while coordinating to support the TN, and while maintaining data privacy; the
only required inter-area communication is between physically adjacent areas
within the DN control hierarchy. We conduct a rigorous stability analysis,
establishing intuitive conditions for closed-loop stability, and provide
detailed tuning recommendations. The proposal is validated via case studies on
multiple feeders, including IEEE-123 and IEEE-8500, using a custom MATLAB-based
application which integrates with OpenDSS. The simulation results show that the
proposed structure is highly scalable and can quickly coordinate DERs in
response to TSO commands, while responding to local disturbances within the DN
and maintaining DN operational limits.Comment: 13 pages, 11 figures, for the supplement document (pdf), see
https://1drv.ms/b/s!AmH_VfOdVVKazYUpDEVplHjtvj-7ZA?e=oyfXD
Confined Shocks inside Isolated Liquid Volumes -- A New Path of Erosion?
The unique confinement of shock waves inside isolated liquid volumes
amplifies the density of shock-liquid interactions. We investigate this
universal principle through an interdisciplinary study of shock-induced
cavitation inside liquid volumes, isolated in 2 and 3 dimensions. By combining
high-speed visualizations of ideal water drops realized in microgravity with
smoothed particle simulations we evidence strong shock-induced cavitation at
the focus of the confined shocks. We extend this analysis to
ground-observations of jets and drops using an analytic model, and argue that
cavitation caused by trapped shocks offers a distinct mechanism of erosion in
high-speed impacts (>100 m/s).Comment: 4 page letter, 4 figure
Luminescence from hydrodynamic cavitation
The majority of the research on cavitation luminescence has focused on the sonoluminescence or chemiluminescence generated by cavitation induced through ultrasound, with a lesser body of work on the luminescence induced by laser- or spark induced cavitation. In such circumstances, the cavitation is generated in liquids where, on the broad scale, there is usually assumed to be no net liquid flow (although of course there are small-scale flows as a result of the cavitation itself, through radiation forces, streaming, microstreaming and turbulence). Little attention has been paid to the luminescence that accompanies (undesirable) cavitation in pumps and turbines or in marine propellers. In the present study, the sonoluminescence specific to air/water vapour bubbles, collapsing within a cavitation tunnel, is addressed. The particular case of leading edge cavitation over a two-dimensional hydrofoil is considered in detail. Hence, strong instabilities develop, causing the attached cavity to shed large clouds of micro bubbles. The spatial and temporal properties of the emitted luminescence were studied using an intensified charge coupled device video camera and a photomultiplier (PM). The light emission was found to extend downstream from the region of cavity closure, to the region where the travelling vortices collapse. Examination of the PM signal on short time scales showed that the emitted luminescence consisted of relatively intense flashes of short duration (as with other forms of luminescence). Individual flashes were often found to be clustered in time. Over longer time scales, clear evidence of periodicity was found in the PM signals. Further analysis showed that bursts of light were being emitted at the Strouhal frequency (for the shedding of transcient cavities)
Scalable Environment for Quantification of Uncertainty and Optimization in Industrial Applications (SEQUOIA)
Peer Reviewedhttps://deepblue.lib.umich.edu/bitstream/2027.42/143027/1/6.2017-1327.pd
Detection of mutations in gyrB using denaturing high performance liquid chromatography (DHPLC) among Salmonella enterica serovar Typhi and Paratyphi A
Background:- Fluoroquinolone resistance is mediated by mutations in the quinolone-resistance determining region (QRDR) of the topoisomerase genes. Denaturing high performance liquid chromatography (DHPLC) was evaluated for detection of clinically important mutations in gyrB among Salmonella. Method:- S. Typhi and S. ParatyphiA characterised for mutation in QRDR of gyrA, parC and parE were studied for mutation in gyrB by DHPLC and validated by sequencing. Result:- The DHPLC analysis was able to resolve the test mutant from isolates with wild type gyrB and distinguished mutants from other mutant by peak profile and shift in retention time. Three sequence variants were detected at codon 464, and a novel mutation Ser→Thr was also detected. gyrB mutation was associated with non classical quinolone resistance (NALS-CIPDS) in 34 isolates of S. Typhi only and was distinct from classical quinolone resistance associated with gyrA mutations (NALR-CIPDS). Conclusion: DHPLC is effective for the detection of mutation and can reduce the need forsequencing to detect clinically significant gyrB mutations.
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