Optoelectronic properties of triphenylamine based dyes for solar cell applications. A DFT study

Indexación: Scopus.GSM thanks to the Department of Chemistry at the Universidad Andres Bello, Concepcion, Chile. LHMH gratefully acknowledges financial support from CONACYT (Projects CB2015-257823) and to the Universidad Autónoma del Estado de Hidalgo.Dye-sensitized solar cells (DSSCs) based on triphenylamine (TPA) as a donor group linked with the acceptor cyanoacrylic acid electron acceptor by 2,2'-bithiophene as π-bridged (D-π-A) has been investigated by Density Functional Theory (DFT) at the B3LYP/6-311G(d,p) level of theory, to establish the conformational orientation of cyanoacrylic acid group as well as evaluate the effect of planarizing the 2,2'-bithiophene unit in position 3 and 3' by electron withdrawing or donor groups on the electronic structure properties of ground and doping(n,p) states. Also, the Time Dependent Density Functional Theory (TD-DFT) at the CPCM-TD-CAM-B3LYP//CAM-B3LYP/6-311G(d,p) level of theory were selected to modulate the electronic absorption spectra and charge-transfer capabilities of the molecules analyzed in the present work. The results indicate that adding an auxiliary donor or withdrawing group to the 2,2'-bithiophene in the (D-π-A) arrangement allow to modify the LUMO's energy of the dyes, while the HOMO's energy is slightly affected. © 2018 Sociedade Brasileira de Quimica. All rights reserved.http://quimicanova.sbq.org.br/imagebank/pdf/AR20170232.pd

Comparison of Compressive Strength and Flexural Capacity between Engineered Cementitious Composites (Bendable Concrete) and Conventional Concrete used in Bangladesh

The Engineered Cementitious Composites (ECC) is made of the same ingredients as in regular concrete. The coarse aggregate is replaced with tiny Polyvinyl Alcohol fibres. This structure offers maximum flexibility and it is expected to cost less. It looks exactly like normal concrete, but under excessive strain, the ECC concrete allows, the specially coated network of fibre in the cement to slide within the cement, thus avoiding the inflexibility that causes brittleness and breakage. As this is a special type of concrete there are no defined codes for it, thus for these reasons, the parameters needed are to be obtained using trial and error method. During the composite preparation, sieve analysis was carried out. Composites were reinforced with Polyvinyl Alcohol (PVA) at the following ratios: 0 % (control), 0.5 %, 1 % and 1.5 %. The cylindrical specimens were subjected to compression and the slab specimens were subjected to flexural test using a Universal Testing Machine, while acquiring data with GOM Correlation Software. Test results reveal that fibre ratio 1% is most acceptable for attaining best compressive strength along with high flexural value. Even though 1% fibre content concrete in the flexural strength test showed 33% less strength of what 1.5% fibre content concrete gained, in the long run, for having the highest compressive strength value (almost 62% more than of 0% fibre content concrete and 15% more than of 1.5% fibre content concrete), 1% fibre content concrete is most suited for constructions

Peripheral fundus findings in X-linked retinoschisis

BACKGROUND/AIMS: Vitreous haemorrhage (VH) and retinal detachment (RD) cause a precipitous decline in vision in a subset of patients with X-linked retinoschisis (XLRS), an otherwise a slowly progressive condition. This study aims to report the frequency of macular and peripheral retinal findings in a large cohort of patients with XLRS and to determine whether peripheral retinal findings are associated with VH and RD. METHODS: A retrospective observational case series was performed in 65 patients with XLRS with a pathogenic variant in retinoschisin 1. Chart review included examination notes, fundus photographs and optical coherence tomography (OCT). Fisher exact tests and univariable logistic regression analysis were used to determine the association between peripheral retinal findings (including retinoschisis, metallic sheen, vascular sheathing, pigmentary changes, white spiculations and vitreous veils) and complications (including VH and RD). RESULTS: Seven eyes (8%) showed normal macular structure on OCT. Peripheral retinoschisis was significantly associated with both VH and RD. Out of 10 eyes with complications, 9 (90%) had peripheral retinoschisis, compared with 33 out of 116 eyes (28%) without complications (p=0.0014). In addition, each additional peripheral finding increased the odds of RD by a factor of 4.06 (95% CI 1.58 to 10.39, p=0.028). There were no complications in the 28 eyes with a normal periphery (p=0.84) or in the 35 eyes with metallic sheen (p=0.42). CONCLUSION: The data suggest that patients with peripheral retinoschisis are at increased risk for VH and RD. Furthermore, patients with additional peripheral retinal findings together with peripheral schisis may carry additional risk for RD

Radiation Tolerance of 65nm CMOS Transistors

We report on the effects of ionizing radiation on 65nm CMOS transistors held at approximately -20C during irradiation. The pattern of damage observed after a total dose of 1 Grad is similar to damage reported in room temperature exposures, but we observe less damage than was observed at room temperature

Bullous X linked retinoschisis: clinical features and prognosis

BACKGROUND/AIMS: A subset of patients with X linked retinoschisis (XLRS) have bullous schisis cavities in the peripheral retina. This study describes the characteristics and prognosis of the bullous form of XLRS. METHODS: A retrospective case series was performed of nine patients with molecularly proven bullous XLRS seen at a single tertiary centre. RESULTS: All cases of bullous peripheral schisis were bilateral, with one unilateral case at presentation which developed into bilateral bullous schisis over time. The mean age of onset was 1.9 years (range: 1 month-7 years, SD: 2.1 years) and at clinical diagnosis was 5.9 years (range: 1 month-27 years, SD: 9.0 years). Mean follow-up was 11 years (range: 6 months-36 years, SD: 10.8 years). Strabismus was the most common presentation (n=7). Other presenting complaints included decreased vision, floaters and an irregularly shaped pupil. The most frequently associated ocular features were strabismus (100%), vitreous haemorrhage (4/18 eyes, 22%), nystagmus (2/9, 22%) and persistent fetal vasculature (1/18, 6%). Localised tractional detachment was seen in 2/18 (11%) eyes, total detachment that underwent surgical repair in 1/18 (6%) and pigmented demarcation lines in a further 22% of the eyes. There was one eye with exudative retinal detachment. CONCLUSION: In XLRS, bullous schisis may be congenital or develop soon after birth and most commonly presents with strabismus. Cases may be complicated by some form of retinal detachment, which may be tractional or a Coats-like exudative detachment

Transformasi Mp-wavelet Tipe B Dan Aplikasinya Pada Pemampatan Citra

Sekarang ini banyak dikembangkan metode penyelesaian masalah secara komputasi. Pada penelitian ini dikonstruksi suatu transformasi wavelet menggunakan operator dalam aljabar max-plus yang disebut sebagai MP-Wavelet. Hasil konstruksi ini secara komputasi membutuhkan waktu yang lebih cepat daripada transformasi wavelet pada umumnya. Pada konstruksi ini dihasilkan satu tipe MP-Wavelet yang disebut dengan MP-Wavelet tipe B. MP-Wavelet tipa ini merupakan pengembangan dari penelitian Fahim yang dipublikasikan pada “Seminar Nasional Pendidikan Sains Tahun 2014” dan “Konferensi Nasional Matemtika 17”. Tipe B ini digunakan untuk pemampatan citra. Untuk melihat hasil rekonstruksi pada proses pemampatan citra “Lena”. Dari simulasi pemampatan ini didapatkan bahwa MP-Wavelet tipe B ini menghasilkan rekonstruksi citra yang lebih baik daripada tipe I yang dikonstruksi oleh Nobuhara (2010); dan tipe I serta tipe A Fahim (2014)

Pedagogical Scenarization for Virtual Environments for Training: Towards Genericity, Coherence and Adaptivity

With the appearance of new computer technologies, having access to information, learning a language, a job, or a skill, etc, is become possible and easier at any time, and at any place. Virtual Environments for Training (VET) is one of those technologies. VETs are based on virtual reality technique to put learners in training situations that emulate real situations. VETs have proven to be advantageous to put learners into varied training situations to acquire knowledge and competencies, especially when these situations are very dangerous, unrealizable, or expensive in reality. To exploit an EVTrsquo;s potentials and control the behavior of it users, the trainer create a pedagogical scenario. A pedagogical scenario must let the possibility to the learner to build his own path, at the same time maintaining the coherence of learning. We present in this paper a new approach, which aims at adapting the pedagogical scenario to learnerrsquo;s needs, and focuses on maintaining the learning coherence

A phylogeny analysis on six mullet species (Teleosti: Mugillidae) using PCR-sequencing method

In this study, genetic differences and phylogenic relationships among six Mugillidae species (Mugil cephalus, M. capito, Liza subviridis, L. saliens, L. aurata, Valamugil buchanani) were determined using PCR-sequencing. M. cephalus, L. subviridis, and V. buchanani from the Persian Gulf and Oman Sea, and L. aurata and L. saliens from the Caspian Sea were collected. Samples of an imported, Egyptian species M. capito were obtained from the Gomishan Research Center in Gorgan. Total DNA from the samples were extracted according to phenol-chloroform procedure. The extracted total DNAs were amplified using polymerase chain reaction (PCR) and then sequenced. The number of bases in the mitochondrial 16s rRNA genome used in this study approximated 600 base pairs. The size of the bands was identical in all the studied species and no heteroplasmia was observed. In addition, the numbers of variable, preserved, and Pi sites were about 114/624, 488/624, and 110/624, respectively. Analysis of the sequences showed great differences between Mugil species and the other studied species. The phylogenetic tree obtained through Neighbor-Joining method revealed that L. saliens and L. aurata were in the same branch while L. subviridis was in a separate branch. In contrast, Maximum Parsimony tree located L. subviridis and L. aurata in a single branch and assigned L. saliens to a distinct branch. This result brings in the question of monophyletic origin of the genus Liza