Behavior of fluids in the vicinity of the critical point

Fluid behavior in vicinity of critical poin

Piecewise Cubic Interpolation Methods

Interpolation of one-dimensional data using piecewise cubic interpolants is considered. Methods are presented for modifying the derivative values in the Hermite representation in order to eliminate the ''bumps'' and ''wiggles'' that frequently plague the more common cubic spline or Akima interpolants. The resulting interpolant is C/sup 1/, but generally not C/sup 2/. The report consists of a reproduction of a poster prepared for a meeting. 27 figures

Quenched crystal field disorder and magnetic liquid ground states in Tb2Sn2-xTixO7

Solid-solutions of the "soft" quantum spin ice pyrochlore magnets Tb2B2O7 with B=Ti and Sn display a novel magnetic ground state in the presence of strong B-site disorder, characterized by a low susceptibility and strong spin fluctuations to temperatures below 0.1 K. These materials have been studied using ac-susceptibility and muSR techniques to very low temperatures, and time-of-flight inelastic neutron scattering techniques to 1.5 K. Remarkably, neutron spectroscopy of the Tb3+ crystal field levels appropriate to at high B-site mixing (0.5 < x < 1.5 in Tb2Sn2-xTixO7) reveal that the doublet ground and first excited states present as continua in energy, while transitions to singlet excited states at higher energies simply interpolate between those of the end members of the solid solution. The resulting ground state suggests an extreme version of a random-anisotropy magnet, with many local moments and anisotropies, depending on the precise local configuration of the six B sites neighboring each magnetic Tb3+ ion.Comment: 6 pages, 6 figure

Transport, magnetic, thermodynamic and optical properties in Ti-doped Sr_2RuO_4

We report on electrical resistivity, magnetic susceptibility and magnetization, on heat capacity and optical experiments in single crystals of Sr_2Ru_(1-x)Ti_xO_4. Samples with x=0.1 and 0.2 reveal purely semiconducting resistivity behavior along c and the charge transport is close to localization within the ab-plane. A strong anisotropy in the magnetic susceptibility appears at temperatures below 100 K. Moreover magnetic ordering in c-direction with a moment of order 0.01 mu_B/f.u. occurs at low temperatures. On doping the low-temperature linear term of the heat capacity becomes reduced significantly and probably is dominated by spin fluctuations. Finally, the optical conductivity reveals the anisotropic character of the dc resistance, with the in-plane conductance roughly following a Drude-type behavior and an insulating response along c

Characterization of nonlinear effects in edge filters

A specially designed and produced edge filter with pronounced nonlinear effects is carefully characterized. The nonlinear effects are estimated at the intensities close to the laser-induced damage.Comment: 3 page

Riociguat for the treatment of chronic thromboembolic pulmonary hypertension.

BACKGROUND: Riociguat, a member of a new class of compounds (soluble guanylate cyclase stimulators), has been shown in previous clinical studies to be beneficial in the treatment of chronic thromboembolic pulmonary hypertension. METHODS: In this phase 3, multicenter, randomized, double-blind, placebo-controlled study, we randomly assigned 261 patients with inoperable chronic thromboembolic pulmonary hypertension or persistent or recurrent pulmonary hypertension after pulmonary endarterectomy to receive placebo or riociguat. The primary end point was the change from baseline to the end of week 16 in the distance walked in 6 minutes. Secondary end points included changes from baseline in pulmonary vascular resistance, N-terminal pro-brain natriuretic peptide (NT-proBNP) level, World Health Organization (WHO) functional class, time to clinical worsening, Borg dyspnea score, quality-of-life variables, and safety. RESULTS: By week 16, the 6-minute walk distance had increased by a mean of 39 m in the riociguat group, as compared with a mean decrease of 6 m in the placebo group (least-squares mean difference, 46 m; 95% confidence interval [CI], 25 to 67; P<0.001). Pulmonary vascular resistance decreased by 226 dyn · sec · cm-5in the riociguat group and increased by 23 dyn · sec · cm-5in the placebo group (least-squares mean difference, -246 dyn · sec · cm-5; 95% CI, -303 to -190; P<0.001). Riociguat was also associated with significant improvements in the NT-proBNP level (P<0.001) and WHO functional class (P = 0.003). The most common serious adverse events were right ventricular failure (in 3% of patients in each group) and syncope (in 2% of the riociguat group and in 3% of the placebo group). CONCLUSIONS: Riociguat significantly improved exercise capacity and pulmonary vascular resistance in patients with chronic thromboembolic pulmonary hypertension. (Funded by Bayer HealthCare; CHEST-1 and CHEST-2 ClinicalTrials.gov numbers, NCT00855465 and NCT00910429, respectively.) Copyright © 2013 Massachusetts Medical Society

Nuclear energy density functional from chiral pion-nucleon dynamics: Isovector spin-orbit terms

We extend a recent calculation of the nuclear energy density functional in the systematic framework of chiral perturbation theory by computing the isovector spin-orbit terms: $(\vec \nabla \rho_p- \vec \nabla \rho_n)\cdot(\vec J_p-\vec J_n) G_{so}(k_f)+ (\vec J_p-\vec J_n)^2 G_J(k_f)$. The calculation includes the one-pion exchange Fock diagram and the iterated one-pion exchange Hartree and Fock diagrams. From these few leading order contributions in the small momentum expansion one obtains already a good equation of state of isospin-symmetric nuclear matter. We find that the parameterfree results for the (density-dependent) strength functions $G_{so}(k_f)$ and $G_J(k_f)$ agree fairly well with that of phenomenological Skyrme forces for densities $\rho > \rho_0/10$. At very low densities a strong variation of the strength functions $G_{so}(k_f)$ and $G_J(k_f)$ with density sets in. This has to do with chiral singularities $m_\pi^{-1}$ and the presence of two competing small mass scales $k_f$ and $m_\pi$. The novel density dependencies of $G_{so}(k_f)$ and $G_J(k_f)$ as predicted by our parameterfree (leading order) calculation should be examined in nuclear structure calculations.Comment: 9 pages, 3 figure, published in: Physical Review C68, 014323 (2003