Study of mural paintings by Fulvio Pennacchi in Sao Paulo City by mineralogical techniques

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)The present research deals with two mural paintings made in 1947 with the fresco technique by Fulvio Pennacchi in the Catholic Chapel of the Hospital das Clinicas (Sao Paulo City, Brazil), namely the Virgin Annunciation and the Supper at Emmaus. This study regards the materials and painting techniques used by the artist, based on historical research, on in situ observations and laboratory analytical techniques (stereomicroscopy, scanning electron microscopy with an energy dispersive spectrometer, X-ray diffractometry, electron microprobe, images obtained with UV-light), aiming to improve the methods of characterization of objects of our cultural heritage, and to enhance its preservation accordingly. The results lead to the identification of the plaster components and of distinct layers in the frescoes, besides further information on grain size, impurities and textures, composition of pigments, and features of deterioration, such as efflorescences. The degree of degradation of the murals painting was assessed by this way. Our data suggest that a single layer of plaster was used by Pennacchi, as a common mortar with fine- and medium-grained aggregates. Differences in texture were obtained by adding gypsum to the plaster.811115126Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)FAPESP [05/51310-3

The effect of hydrothermal alteration on the Sr and Nd isotopic signatures of the Barra do Itapirapua Carbonatite, Southern Brazil

The Cretaceous Barra do Itapirapua carbonatite in southern Brazil experienced extensive postmagmatic hydrothermal alteration. In this article, Sr and Nd isotope ratios of coexisting samples of hydrothermally overprinted and of preserved, nonoverprinted carbonatite are presented. Hydrothermal alteration caused strong REE enrichment, leading to the formation of minerals of the bastnaesite group. In the overprinted carbonatite, Nd contents reach 4000 ppm, two orders of magnitude higher than in the fresh carbonatite, but epsilon(Nd) varies only within a range of 3.4 units. In contrast, Sr was leached from the carbonatite during the postmagmatic alteration; hence values of around 10,000 ppm in the fresh carbonatite drop to about 1000 ppm in the overprinted samples. Leaching is accompanied by a variation of Sr isotopic composition toward more radiogenic values, resulting in an increase of 15 units in epsilon(Sr). Variation of Sr isotopic composition is related to postmagmatic alteration and is decoupled from the variation of Nd isotopic composition, ruling out heterogeneities in the mantle source as the main cause of isotopic variability in the data set. Furthermore, this cannot be explained by bulk crustal contamination. A two-step model is proposed in which (1) a REE-rich, carbonatite-derived hydrothermal fluid overprinted the pristine carbonatite, causing REE-enrichment with a relative small change of isotopic composition; and (2) crust-derived hydrothermal fluids percolated the cooling carbonatite, leaching the original Sr from the carbonatite and introducing a more radiogenic Sr isotopic signature. The amounts of carbonatite-derived Nd with primitive, carbonatite-like Nd isotope ratios introduced during the first stage of hydrothermal alteration are high enough to buffer the effect of crust-derived Nd on the Nd isotopic composition of the overprinted carbonatite

Hydrothermal rare earth elements mineralization in the Barra do Itapirapua carbonatite, southern Brazil: behaviour of selected trace elements and stable isotopes (C, O)

The Bura do Itapira pua carbonatite is located in southern Brazil and belongs to the Cretaceous Ponta Grossa alkaline-carbonatitic province related to the opening of the South Atlantic. The carbonatite complex is emplaced in Proterozoic granites and is mainly composed of plutonic magnesio- to ferrocarbonatite, with smaller amounts of subvolcanic magnesiocarbonatite. Hydrothermal alteration of the carbonatite has led to the formation of quartz, apatite, fluorite, rue earth fluorocarbonates, barite and sulfides in variable proportions. Trace element data, delta(13)C and delta(18)O are presented here, with the aim of better understanding the geochemical nature of hydrothermal alteration related to rare earth elements (REE) mineralization. The non-overprinted plutonic carbonatite shows the lowest REE contents, and its primitive carbon and oxygen stable isotopic composition places it in the field of primary igneous carbonatites. Two types of hydrothermally overprinted plutonic carbonatites can be distinguished based on secondary minerals and geochemical composition. Type I contains mainly quartz, rare earth fluorocarbonates and apatite as hydrothermal secondary minerals, and has steep chondrite normalized REE patterns, with Sigma(REE+Y) of up to 3 wt.% (i.e., two orders of magnitude higher than in fresh plutonic samples). In contrast, the Type II overprint contains apatite, fluorite and barite as dominant hydrothermal minerals, and is characterized by heavy REE enrichment relative to the fresh samples, with flat chondrite normalized REE patterns. Carbon and oxygen stable isotope ratios of Types I and II are elevated (delta(18)O + 8 to + 12 parts per thousand; delta(13)C - 6 to - 2 parts per thousand) relative to the fresh samples. Hydrothermally overprinted carbonatites exposed to weathering show even higher delta(18)O values (delta(18)O 13 to 25 parts per thousand) but no additional REE enrichment. The subvolcanic carbonatite has anomalously high delta(13)C of up to + 1 parts per thousand, which suggests crustal contamination through interaction with carbonate-bearing metasediments. (C) 1999 Elsevier B.V. B.V. All rights reserved

Physical properties of palm fruits processed with tools by wild bearded capuchins (Cebus libidinosus)

Habitually, capuchin monkeys access encased hard foods by using their canines and premolars and/or by pounding the food on hard surfaces. Instead, the wild bearded capuchins (Cebus libidinosus) of Boa Vista (Brazil) routinely crack palm fruits with tools. We measured size, weight, structure, and peak-force-at-failure of the four palm fruit species most frequently processed with tools by wild capuchin monkeys living in Boa Vista. Moreover, for each nut species we identify whether peak-force-at-failure was consistently associated with greater weight/volume, endocarp, thickness, and structural complexity. The goals of this study were (a) to investigate whether these palm fruits are difficult, or impossible, to access other than with tools and (b) to collect data on the physical properties of palm fruits that are comparable to those available for the nuts cracked open with tools by wild chimpanzees. Results showed that the four nut species differ in terms of peak-force-at-failure and that peak-force-at-failure is positively associated with greater weight (and consequently volume) and apparently with structural complexity (i.e. more kernels and thus more partitions); finally for three out of four nut species shell thickness is also positively associated with greater volume. The finding that the nuts exploited by capuchins with tools have very high resistance values support the idea that tool use is indeed mandatory to crack them open. Finally, the peak-force-at-failure of the piassava nuts is similar to that reported for the very tough panda nuts cracked open by wild chimpanzees; this highlights the ecological importance of tool use for exploiting high resistance foods in this capuchin species

Distribution of potential suitable hammers and transport of hammer tools and nuts by wild capuchin monkeys

Selection and transport of objects to use as tools at a distant site are considered to reflect planning. Ancestral humans transported tools and tool-making materials as well as food items. Wild chimpanzees also transport selected hammer tools and nuts to anvil sites. To date, we had no other examples of selection and transport of stone tools among wild nonhuman primates. Wild bearded capuchins (Cebus libidinosus) in Boa Vista (Piaui, Brazil) routinely crack open palm nuts and other physically well-protected foods on level surfaces (anvils) using stones (hammers) as percussive tools. Here we present indirect evidence, obtained by a transect census, that stones suitable for use as hammers are rare (study 1) and behavioral evidence of hammer transport by twelve capuchins (study 2). To crack palm nuts, adults transported heavier and harder stones than to crack other less resistant food items. These findings show that wild capuchin monkeys selectively transport stones of appropriate size and hardness to use as hammers, thus exhibiting, like chimpanzees and humans, planning in tool-use activities

Effect of nitrogen doses on disease severity and watermelon yield Influência de doses de nitrogênio na severidade de doenças e na produtividade da melancia

Nitrogen fertilization is an important step for watermelon (Citrullus lanatus) production due to its influence over yield, fruit quality, and disease severity. Currently, the gummy stem blight (Didymella bryoniae) and the downy mildew (Pseudoperonospora cubensis) can be taken as the most important watermelon diseases, since they impose severe impairment to the crop. Furthermore, studies focusing on plant responses to nitrogen fertilization regarding fruit yield and quality, and disease resistance are rare. Hence, the present study aimed at evaluating the effect of nitrogen doses on fruit yield and quality, and on disease prevalence in watermelon. Two experiments were carried out at the Universidade Federal de Tocantins, employing sprinkler irrigation, in an area previously used to grow watermelon. The experimental design was blocks at random, with five treatments (N doses, applied twice as side-dressing, in kg ha-1, as follows: T1= control treatment without N, T2= 20, T3= 40, T4= 80, and T5= 120), and four replications. Urea (45% N) was used as the N source. In the first assay, the highest fruit yield and average weight were observed when 40 kg ha-1 of N were applied. The highest severity of the gummy stem blight was observed when the highest nitrogen doses were applied (80 and 120 kg ha-1). In the second assay, the highest severity levels of the gummy stem blight, as well as of mildew, were observed again when N doses were the highest (80 and 120 kg ha-1). The lowest severity levels for both diseases were observed in the control treatment.<br>A adubação nitrogenada é importante para a cultura da melancia (Citrullus lanatus) por afetar diretamente a produtividade, a qualidade dos frutos e a severidade de doenças. Atualmente, o crestamento gomoso (Didymella bryoniae) e o míldio (Pseudoperonospora cubensis) podem ser consideradas as doenças mais importantes da melancia devido aos prejuízos que podem causar na lavoura. Estudos envolvendo a aplicação de doses de nitrogênio e seus efeitos na produtividade, qualidade de frutos e manifestação de doenças são escassos. Desta forma, o presente trabalho teve como objetivo avaliar diferentes doses de nitrogênio e seus efeitos na produtividade, características dos frutos e na prevalência de doenças da melancieira. Foram conduzidos dois ensaios na Universidade Federal do Tocantins, sob irrigação por aspersão, em área anteriormente cultivada com melancia. Foi utilizado o delineamento experimental de blocos ao acaso, com cinco tratamentos (doses de nitrogênio, aplicados em duas vezes em cobertura, em kg ha-1, sendo T1= testemunha sem nitrogênio em cobertura, T2= 20, T3= 40, T4= 80 e T5= 120) e quatro repetições. A uréia foi utilizada como fonte de nitrogênio (45% de N). No ensaio I, verificou-se maior produtividade e maior peso médio de frutos no tratamento que recebeu 40 kg ha-1. Níveis mais altos de severidade do crestamento gomoso foram verificados nos tratamentos que receberam maiores dosagens de nitrogênio (80 e 120 kg). No ensaio II, nos tratamentos com 80 e 120 kg ha de N foram observados os níveis mais altos de míldio e crestamento gomoso. Menores níveis dessas doenças foram verificados no tratamento testemunha