Modelling of epitaxial graphene functionalization

A new model for graphene, epitaxially grown on silicon carbide is proposed. Density functional theory modelling of epitaxial graphene functionalization by hydrogen, fluorine and phenyl groups has been performed with hydrogen and fluorine showing a high probability of cluster formation in high adatom concentration. It has also been shown that the clusterization of fluorine adatoms provides midgap states in formation due to significant flat distortion of graphene. The functionalization of epitaxial graphene using larger species (methyl and phenyl groups) renders cluster formation impossible, due to the steric effect and results in uniform coverage with the energy gap opening.Comment: 15 pages, 4 figures, to appear in Nanotechnolog

The distribution of oxygen at the Ni81Fe19/Ta interface

The knowledge of how oxygen atoms are distributed at a magnetic-metal / oxide, or magnetic-metal / non-magnetic-metal interface, can be an useful tool to optimize device production. Multilayered Ni81Fe19 / Ta samples consisting of 15 bilayers of 2.5 nm each, grown onto glass substrates by magnetron sputtering from Ni81Fe19 and Ta targets, have been investigated. X-ray absorption near edge structure, extended X-Ray absorption fine structure, small angle X-ray diffraction, and simulations, were used to characterize the samples. Oxygen atoms incorporated onto Ni81Fe19 films during O2 exposition are mainly bonded to Fe atoms. This partial oxidation of the Ni81Fe19 surface works as a barrier to arriving Ta atoms, preventing intermixing at the Ni81Fe19 / Ta interface. The reduction of the Ni81Fe19 surface by the formation of TaO x is observed.Comment: 14 pages, 9 figures, accepted for publication in Advances in Materials Science and Engineerin

Quantum capacitor with discrete charge-anticharge: spectrum and forces

The quantum capacitor with discrete charge is modeled by a Hamiltonian containing an inductive intrinsic term (tunnel effect between plates). The spectrum is obtained using a double Hilbert space. Fluctuations in the charge-anticharge pairs (zero total charge) give rise to an elementary attraction which is compared to the Casimir force. In this case, the field-fluctuations force could be also interpreted as charge-fluctuations force

Ultracold mixtures of metastable He and Rb: scattering lengths from ab initio calculations and thermalization measurements

We have investigated the ultracold interspecies scattering properties of metastable triplet He and Rb. We performed state-of-the-art ab initio calculations of the relevant interaction potential, and measured the interspecies elastic cross section for an ultracold mixture of metastable triplet $^4$He and $^{87}$Rb in a quadrupole magnetic trap at a temperature of 0.5 mK. Our combined theoretical and experimental study gives an interspecies scattering length $a_{4+87}=+17^{+1}_{-4}$ $a_0$, which prior to this work was unknown. More general, our work shows the possibility of obtaining accurate scattering lengths using ab initio calculations for a system containing a heavy, many-electron atom, such as Rb.Comment: 11 pages, 11 figures, accepted for publication in Phys. Rev.

Mathematical Model of Easter Island Society Collapse

In this paper we consider a mathematical model for the evolution and collapse of the Easter Island society, starting from the fifth century until the last period of the society collapse (fifteen century). Based on historical reports, the available primary sources consisted almost exclusively on the trees. We describe the inhabitants and the resources as an isolated system and both considered as dynamic variables. A mathematical analysis about why the structure of the Easter Island community collapse is performed. In particular, we analyze the critical values of the fundamental parameters driving the interaction humans-environment and consequently leading to the collapse. The technological parameter, quantifying the exploitation of the resources, is calculated and applied to the case of other extinguished civilization (Cop\'an Maya) confirming, with a sufficiently precise estimation, the consistency of the adopted model.Comment: 9 pages, 1 figure, final version published on EuroPhysics Letter

DRIS standards for nutritional evaluation of Phaseolus vulgaris in Cerrado, Goiás State, Brazil.

The knowledge of nutritional requirements of beans, the efficiency of soil acidity correction and the fertilization programs are essential to increase productivity. The Integrated Recommendation and Diagnosis System (DRIS) assists with nutritional diagnosis of cultivated plants based on existing interactions between nutrients and the hierarchizing of limitations. This study aimed at establishing standards using the DRIS method for areas of production of irrigated common beans and at determining the most limiting nutritional factors to production using leaf analyses interpreted by concentration ranges and DRIS. Eighteen different beanproducing areas were selected in a central pivot irrigation system, from which 82 sampling points were established to collect leaves of crop and determine their nutritional contents. The reference population had productivity of over 3,000 kg ha- 1. Using DRIS, we determined that phosphorus is the most limiting nutrient regarding its deficiency, with great sensitivity to diagnose nutritional problems of plants, especially micronutrients. Phosphorus (68.3%), molybdenum (65.9%), iron (64.6 %) and sodium (63.4%) and are nutrients with highest percentage of samples presenting levels below adequate according to sufficiency ranges for plants. Using DRIS, we can evaluate interactions among nutrients and determine of the magnitude of crop nutritional limitation whether due to deficiency or excess. These results may indicate which nutrients are limiting the crop productive capacity, allowing greater efficiency in its correction in soil

Phase-coherence time saturation in mesoscopic systems: wave function collapse

A finite phase-coherence time $\tau_{\phi}^{meas}$ emerges from iterative measurement onto a quantum system. For a rapid sequence, the phase-coherence time is found explicitly. For the stationary charge conduction problem, it is bounded. At all order, in the time-interval of measurements, we propose a general expression for $\tau_{\phi}^{meas}$.Comment: 8 pages, 0 figures, Late

Spin-Electron-Phonon Excitation in Re-based Half-Metallic Double Perovskites

A remarkable hardening (~ 30 cm-1) of the normal mode of vibration associated with the symmetric stretching of the oxygen octahedra for the Ba2FeReO6 and Sr2CrReO6 double perovskites is observed below the corresponding magnetic ordering temperatures. The very large magnitude of this effect and its absence for the anti-symmetric stretching mode provide evidence against a conventional spin-phonon coupling mechanism. Our observations are consistent with a collective excitation formed by the combination of the vibrational mode with oscillations of local Fe or Cr 3d and Re 5d occupations and spin magnitudes.Comment: 12 pages, 4 figure