Pressure and chemical substitution effects in the local atomic structure of BaFe2As2

The effects of K and Co substitutions and quasi-hydrostatic applied pressure (P<9 GPa) in the local atomic structure of BaFe2As2, Ba(Fe{0.937}Co{0.063})2As2 and Ba{0.85}K{0.15}Fe2As2 superconductors were investigated by extended x-ray absorption fine structure (EXAFS) measurements in the As K absorption edge. The As-Fe bond length is found to be slightly reduced (<~ 0.01 Angstroms) by both Co and K substitutions, without any observable increment in the corresponding Debye Waller factor. Also, this bond is shown to be compressible (k = 3.3(3)x10^{-3} GPa^{-1}). The observed contractions of As-Fe bond under pressure and chemical substitutions are likely related with a reduction of the local Fe magnetic moments, and should be an important tuning parameter in the phase diagrams of the Fe-based superconductors.Comment: 7 pages, 6 figure

Momentum-independent magnetic excitation continuum in the honeycomb iridate H3_3LiIr2_2O6_6

In the search for realizations of Quantum Spin Liquids (QSL), it is essential to understand the interplay between inherent disorder and the correlated fluctuating spin ground state. H$_3$LiIr$_2$O$_6$ is regarded as a spin liquid proximate to the Kitaev-limit (KQSL) in which H zero-point motion and stacking faults are known to be present. Bond disorder has been invoked to account for the existence of unexpected low-energy spin excitations. Controversy remains about the nature of the underlying correlated state and if any KQSL physics survives. Here, we use resonant X-ray spectroscopies to map the collective excitations in H$_3$LiIr$_2$O$_6$ and characterize its magnetic state. We uncover a broad bandwidth and momentum-independent continuum of magnetic excitations at low temperatures that are distinct from the paramagnetic state. The center energy and high-energy tail of the continuum are consistent with expectations for dominant ferromagnetic Kitaev interactions between dynamically fluctuating spins. The absence of a momentum dependence to these excitations indicates a broken translational invariance. Our data support an interpretation of H$_3$LiIr$_2$O$_6$ as a disordered topological spin liquid in close proximity to bond-disordered versions of the KQSL. Our results shed light on how random disorder affects topological magnetic states and have implications for future experimental and theoretical works toward realizing the Kitaev model in condensed matter system

Collective Phase-like Mode and the Role of Lattice Distortions at TN~TC in RMn2O5 (R= Pr, Sm, Gd, Tb, Bi)

We report on electronic collective excitations in RMn2O5 (R= Pr, Sm, Gd, Tb) showing condensation starting at and below TN\simTC\sim40-50 K. Its origin is understood as partial delocalized eg electron orbitals in the Jahn-Teller distortion of the pyramids dimmer with strong hybridized Mn3+-O bonds. Our local probes, Raman, infrared, and X-ray absorption, back the conclusion by which there is no structural phase transition at TN\simTC. Ferroelectricity is magnetically assisted by electron localization triggering lattice polarizability by unscreening. We have also found phonon hardening as the rare earth is sequentially replaced. This is understood as consequence of lanthanide contraction. It is suggested that partially f-electron screened Rare Earth nuclei might be introducing a perturbation to eg electrons prone to delocalize as the superexchange interaction takes place.Comment: Journal of Physics Cond. Matter April 12, 2012. In pres

Eficácia de diferentes extratores de polifenóis totais e antioxidantes em maçã.

Frutas e hortaliças são fontes naturais de polifenóis com elevada atividade antioxidante. Muitos estudos mostram que entre as frutas, a maça se destaca por ser uma fonte rica em fenóis, especialmente flavonóides. Apresentam elevada capacidade antioxldante, protegendo o organismo dos efeitos prejudiciais ocasionados pelo estresse oxidativo.Resumo

Incommensurate two-dimensional checkerboard charge density wave in the low dimensional superconductor Ta4Pd3Te16

We report the observation of a two-dimensional (2D) checkerboard charge density wave (CDW) in the low-dimensional superconductor Ta4Pd3Te16. By determining its CDW properties across the temperature-pressure (T-P) phase diagram and comparing with prototypical CDW materials, we conclude that Ta4Pd3Te16 features: a) an incommensurate CDW with a mixed character of dimensions (Q1D considering its needle-like shape along the b-axis, Q2D as the CDW has checkerboard wavevectors, and 3D because of CDW projections along all three axes); and b) one of the weakest CDWs compared to its superconductivity (SC), i.e. enhanced SC with respect to CDW, suggesting an interesting interplay of the two orders.Comment: Z.S. and S.J.K. contributed equally to this work / Accepted for publication in Physical Review Research Rapid Communication

Electronic character of charge order in square planar low valence nickelates

Charge order is a central feature of the physics of cuprate superconductors and is known to arise from a modulation of holes with primarily oxygen character. Low-valence nickelate superconductors also host charge order, but the electronic character of this symmetry breaking is unsettled. Here, using resonant inelastic x-ray scattering at the Ni $L_2$-edge, we identify intertwined involvements of Ni $3d_{x^2-y^2}$, $3d_{3z^2-r^2}$, and O $2p_{\sigma}$ orbitals in the formation of diagonal charge order in an overdoped low-valence nickelate La$_{4}$Ni$_{3}$O$_{8}$. The Ni $3d_{x^2-y^2}$ orbitals, strongly hybridized with planar O $2p_{\sigma}$, largely shape the spatial charge distribution and lead to Ni site-centered charge order. The $3d_{3z^2-r^2}$ orbitals play a small, but non-negligible role in the charge order as they hybridize with the rare-earth $5d$ orbitals. Our results reveal that the low-energy physics and ground-state character of these nickelates are more complex than those in cuprates.Comment: Accepted in Physical Review X; 7 pages plus references and supplementary material