Evolution of the electronic structure with size in II-VI semiconductor nanocrystals

In order to provide a quantitatively accurate description of the band gap variation with sizes in various II-VI semiconductor nanocrystals, we make use of the recently reported tight-binding parametrization of the corresponding bulk systems. Using the same tight-binding scheme and parameters, we calculate the electronic structure of II-VI nanocrystals in real space with sizes ranging between 5 and 80 {\AA} in diameter. A comparison with available experimental results from the literature shows an excellent agreement over the entire range of sizes.Comment: 17 pages, 4 figures, accepted in Phys. Rev.

Supermassive binary black holes among cosmic gamma-ray sources

Supermassive binary black holes (SBBHs) are a natural outcome of galaxy mergers. Here we show that low-frequency ($f \leq 10^{-6}$ Hz) quasi-periodic variability observed from cosmic blazar sources can provide substantial inductive support for the presence of close (d \lppr 0.1 pc) SBBHs at their centers. It is argued on physical grounds that such close binary systems are likely to give rise to different (although not independent) periodicities in the radio, optical and X-ray/TeV regime, and, hence that detection of appropriate period ratios significantly corroborates the SBBH interpretation. This is illustrated for a binary model where optical longterm periodicity is related to accretion disk interactions, radio periodicity to Newtonian jet precession, and periodicities in the high energy bands to the orbital motion of the jet. We use the observed periodicities to constrain the properties for a sample of SBBH candidates including OJ 287 and AO 0235+16, and discuss the results within the context of jet activity and binary evolution.Comment: 4 pages, based on presentation at "The multimessenger approach to unidentified gamma-ray sources", Barcelona/Spain, July 2006; accepted for publication in Astrophysics and Space Science; references update