Magnetic structure of free cobalt clusters studied with Stern-Gerlach deflection experiments

We have studied the magnetic properties of free cobalt clusters in two semi-independent Stern-Gerlach deflection experiments at temperatures between 60 and 307 K. We find that clusters consisting of 13 to 200 cobalt atoms exhibit behavior that is entirely consistent with superparamagnetism, though complicated by finite-system fluctuations in cluster temperature. By fitting the data to the Langevin function, we report magnetic moments per atom for each cobalt cluster size and compare the results of our two measurements and all those performed previously. In addition to a gradual decrease in moment per atom with increasing size, there are oscillations that appear to be caused by geometrical shell structure. We discuss our observations in light of the two competing models for Langevin-like magnetization behavior in free clusters, superparamagnetism and adiabatic magnetization, and conclude that the evidence strongly supports the superparamagnetic model

Rate constant for the reaction of hydroxyl radical with formaldehyde over the temperature range 228-362 K

Absolute rate constants for the reaction OH ? H2CO measured over the temperature range 228-362 K using the flash photolysis-resonance fluorescence technique are given. The results are independent of variations in H2CO concentration, total pressure Ar concentration, and flash intensity (i.e., initial OH concentration). The rate constant is found to be invariant with temperature in this range, the best representation being k sub 1 = (1.05 ? or - 0.11) x 10 to the 11th power cu cm molecule(-1) s(-1) where the error is two standard deviations. This result is compared with previous absolute and relative determinations of k sub 1. The reaction is also discussed from a theoretical point of view

Magnetism and Magnetic Isomers in Free Chromium Clusters

We have used the Stern-Gerlach deflection technique to study magnetism in chromium clusters of 20-133 atoms. Between 60 K and 100 K, we observe that these clusters have large magnetic moments and respond superparamagnetically to applied magnetic fields. Using superparamagnetic theory, we have determined the moment per atom for each cluster size and find that it often far exceeds the moment per atom present anywhere in the bulk antiferromagnetic lattice. Remarkably, our cluster beam contains two magnetically distinguishable forms of each cluster size with >= 34 atoms. We attribute this observation to structural isomers

Upper atmosphere research: Reaction rate and optical measurements

The objective is to provide photochemical, kinetic, and spectroscopic information necessary for photochemical models of the Earth's upper atmosphere and to examine reactions or reactants not presently in the models to either confirm the correctness of their exclusion or provide evidence to justify future inclusion in the models. New initiatives are being taken in technique development (many of them laser based) and in the application of established techniques to address gaps in the photochemical/kinetic data base, as well as to provide increasingly reliable information

Multi-frequency study of Local Group Supernova Remnants The curious case of the Large Magellanic Cloud SNR J0528-6714

Aims. Recent ATCA, XMM-Newton and MCELS observations of the Magellanic Clouds (MCs) cover a number of new and known SNRs which are poorly studied, such as SNR J0528-6714 . This particular SNR exhibits luminous radio-continuum emission, but is one of the unusual and rare cases without detectable optical and very faint X-ray emission (initially detected by ROSAT and listed as object [HP99] 498). We used new multi-frequency radio-continuum surveys and new optical observations at H{\alpha}, [S ii] and [O iii] wavelengths, in combination with XMM-Newton X-ray data, to investigate the SNR properties and to search for a physical explanation for the unusual appearance of this SNR. Methods. We analysed the X-ray and Radio-Continuum spectra and present multi-wavelength morphological studies of this SNR. Results. We present the results of new moderate resolution ATCA observations of SNR J0528-6714. We found that this object is a typical older SNR with a radio spectral index of {\alpha}=-0.36 \pm 0.09 and a diameter of D=52.4 \pm 1.0 pc. Regions of moderate and somewhat irregular polarisation were detected which are also indicative of an older SNR. Using a non-equilibrium ionisation collisional plasma model to describe the X-ray spectrum, we find temperatures kT of 0.26 keV for the remnant. The low temperature, low surface brightness, and large extent of the remnant all indicate a relatively advanced age. The near circular morphology indicates a Type Ia event. Conclusions. Our study revealed one of the most unusual cases of SNRs in the Local Group of galaxies - a luminous radio SNR without optical counterpart and, at the same time, very faint X-ray emission. While it is not unusual to not detect an SNR in the optical, the combination of faint X-ray and no optical detection makes this SNR very unique.Comment: 6 pages, 5 figures, Accepted for publication in A&

Primary Destinationis of South Dakota Wheat, Soybeans and Flaxseed

The present study is designed to provide basic data concerning the movement of South Dakota wheat, soybeans and flaxseed. This information can be used to plan future transportation needs for the state and aid in planning locations of grain elevators and other agri-business firms. If South Dakotans are to have an informed voice in the transportation development of their state it is important to first study the volume and destination of shipments moving into and out of the state

Primary Destinations of South Dakota Corn, Oats, Barley and Sorghum

The purpose of this study is to document the flow of feed grains into and from South Dakota elevators. Primary emphasis is upon determining how the grain moves and where it goes

An inventory and condition survey of rangelands in the Ashburton River catchment, Western Australia

The inventory and condition survey of rangelands in the Ashburton River catchment, undertaken by the Department of Agriculture and Food, Western Australia (DAFWA) between 1976 and 1978, describes and maps the natural resources of the region’s pastoral leasehold land. This survey report provides a baseline record of the existence and condition of the natural area’s resources, to assist with the planning and implementation of land management practices. The report identified and described the condition of soils, landforms, vegetation, habitat, ecosystems, and declared plants and animals. It also assessed the impact of pastoralism and made land management recommendations. The area surveyed covers approximately 93 600km² and includes the catchment of the Ashburton River and part of the catchment of the Yannarie River. About 65% (61 130km²) of the area is occupied by 30 pastoral leases. The remaining 35% (32 470km²) consists of reserves of various kinds, and vacant crown land which is unsuitable for pastoral purposes. The worst areas of degredation and erosion are on the most valuable pasture lands. These areas are readily accessible, close to permanent water supplies and support attractive pastures. Therefore, they received preferential overuse in the early days of settlement, and sensitive parts are now seriously degraded

The m−m-dissimilarity map and representation theory of SLmSL_m

We give another proof that $m$-dissimilarity vectors of weighted trees are points on the tropical Grassmanian, as conjectured by Cools, and proved by Giraldo in response to a question of Sturmfels and Pachter. We accomplish this by relating $m$-dissimilarity vectors to the representation theory of $SL_m.$Comment: 11 pages, 8 figure