196 research outputs found
On the hydrolysis of the Dysprosium(III) ion
The hydrolysis of the Dysprosium (III) (Dy 3+ ) ion has been investigated at 25°C in 1, 2 and 3 molal (Na)ClO4 medium through a combined potentiometricâcoulometric methodology. At each perchlorate concentration the formation constants of the complexes DyOH 2+ , Dy2(OH)2 4+ and Dy5(OH)9 6+ have been determined. The values have then been extrapolated to zero ionic strength by using the Specific Interaction Theory. Analogies with the hydrolysis mechanism of other lanthanides are pointed out. This paper is just the first to be reported of a series of studies undertaken with the aim to prove that a single mechanism of hydrolysis applies to all the trivalent lanthanides and probably to the corresponding actinides, too radioactive to be investigated directly
Observation of the TeV gamma-ray source MGRO J1908+06 with ARGO-YBJ
The extended gamma ray source MGRO J1908+06, discovered by the Milagro air
shower detector in 2007, has been observed for about 4 years by the ARGO-YBJ
experiment at TeV energies, with a statistical significance of 6.2 standard
deviations. The peak of the signal is found at a position consistent with the
pulsar PSR J1907+0602. Parametrizing the source shape with a two-dimensional
Gauss function we estimate an extension \sigma = 0.49 \pm 0.22 degrees,
consistent with a previous measurement by the Cherenkov Array H.E.S.S.. The
observed energy spectrum is dN/dE = 6.1 \pm 1.4 \times 10^-13 (E/4 TeV)^{-2.54
\pm 0.36} photons cm^-2 s^-1 TeV^-1, in the energy range 1-20 TeV. The measured
gamma ray flux is consistent with the results of the Milagro detector, but is
2-3 times larger than the flux previously derived by H.E.S.S. at energies of a
few TeV. The continuity of the Milagro and ARGO-YBJ observations and the stable
excess rate observed by ARGO-YBJ along 4 years of data taking support the
identification of MGRO J1908+06 as the steady powerful TeV pulsar wind nebula
of PSR J1907+0602, with an integrated luminosity above 1 TeV about 1.8 times
the Crab Nebula luminosity.Comment: 6 pages, accepted for pubblication by ApJ. Replaced to correct the
author lis
Origin of the Spin-Orbital Liquid State in a Nearly J=0 Iridate Ba3ZnIr2O9
We show using detailed magnetic and thermodynamic studies and theoretical calculations that the ground state of Ba3ZnIr2O9 is a realization of a novel spin-orbital liquid state. Our results reveal that Ba3ZnIr2O9 with Ir5+ (5d(4)) ions and strong spin-orbit coupling (SOC) arrives very close to the elusive J = 0 state but each Ir ion still possesses a weak moment. Ab initio density functional calculations indicate that this moment is developed due to superexchange, mediated by a strong intradimer hopping mechanism. While the Ir spins within the structural Ir2O9 dimer are expected to form a spin-orbit singlet state (SOS) with no resultant moment, substantial frustration arising from interdimer exchange interactions induce quantum fluctuations in these possible SOS states favoring a spin-orbital liquid phase down to at least 100 mK
Avaliação e caracterização da pastilha sensora de um eletrodo de segunda espĂ©cie sensĂvel a oxalato
Long-term Monitoring on Mrk 501 for Its VHE gamma Emission and a Flare in October 2011
As one of the brightest active blazars in both X-ray and very high energy
-ray bands, Mrk 501 is very useful for physics associated with jets
from AGNs. The ARGO-YBJ experiment is monitoring it for -rays above 0.3
TeV since November 2007. Starting from October 2011 the largest flare since
2005 is observed, which lasts to about April 2012. In this paper, a detailed
analysis is reported. During the brightest -rays flaring episodes from
October 17 to November 22, 2011, an excess of the event rate over 6 is
detected by ARGO-YBJ in the direction of Mrk 501, corresponding to an increase
of the -ray flux above 1 TeV by a factor of 6.62.2 from its steady
emission. In particular, the -ray flux above 8 TeV is detected with a
significance better than 4 . Based on time-dependent synchrotron
self-Compton (SSC) processes, the broad-band energy spectrum is interpreted as
the emission from an electron energy distribution parameterized with a single
power-law function with an exponential cutoff at its high energy end. The
average spectral energy distribution for the steady emission is well described
by this simple one-zone SSC model. However, the detection of -rays
above 8 TeV during the flare challenges this model due to the hardness of the
spectra. Correlations between X-rays and -rays are also investigated.Comment: have been accepted for publication at Ap
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