154 research outputs found

    Oral Health and Dental Anxiety in a German Practice-based Sample

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    Objective Does dental anxiety have an effect on dental and periodontal health? Methods Survey data was collected from n = 200 adults (53 % females, average age 49 years) in a cross-sectional study. Dental anxiety was measured with the modified dental anxiety scale (MDAS, score 1–5, the greater the score, the greater the anxiety). Clinical parameters including probing depth (PD), clinical attachment level (CAL), plaque index (SLI), and bleeding on probing (BoP) as well as the DMFT index were recorded and statistically analyzed. Results Rating of dental anxiety was higher in women than in men (65 vs 35 %). Subjects with higher MDAS values visited the dentist less frequently (p = 0.001) and had more decay (DT 6.7 ± 4.2 vs 1.7 ± 2.4; p \u3c 0.001) but fewer filled teeth than subjects with lower ratings of dental anxiety (FT 7.1 ± 4.5 vs 9.8 ± 5.7; p = 0.042). There were no differences in PD or CAL between subjects with or without dental anxiety, while patients with higher MDAS value showed significantly more BoP (50 ± 19 vs 34 ± 20 %; p = 0.002) than patients with low MDAS scores (no or low dental anxiety). Conclusions Patients with higher ratings of dental anxiety had significantly more caries experience and gingivitis. Therefore, dental anxiety is associated with negative effect on dental and periodontal health. Clinical relevance Identifying patients with high dental anxiety and helping to manage this anxiety has important implications to improve oral health in adults. The MDAS appears to be an easy and efficient tool that can be used to identify patients with dental anxiety in dental practices

    Cytoskeleton organisation during the infection of three brown algal species, Ectocarpus siliculosus, Ectocarpus crouaniorum and Pylaiella littoralis, by the intracellular marine oomycete Eurychasma dicksonii

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    Funded by •University of Athens •TOTAL Foundation •European Commission •ASSEMBLE. Grant Number: 227788 •MASTS •Scottish Funding Council. Grant Number: HR09011 •UK NERC. Grant Number: NE/J00460X/1Peer reviewedPostprintPostprin

    Enhanced magnetization of ultrathin NiFe2_2O4_4 films on SrTiO3_3(001) related to cation disorder and anomalous strain

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    NiFe2_2O4_4 thin films with varying thickness were grown on SrTiO3_3(001) by reactive molecular beam epitaxy. Soft and hard x-ray photoelectron spectroscopy measurements reveal a homogeneous cation distribution throughout the whole film with stoichiometric Ni:Fe ratios of 1:2 independent of the film thickness. Low energy electron diffraction and high resolution (grazing incidence) x-ray diffraction in addition to x-ray reflectivity experiments were conducted to obtain information of the film surface and bulk structure, respectively. For ultrathin films up to 7.3 nm, lateral tensile and vertical compressive strain is observed, contradicting an adaption at the interface of NiFe2_2O4_4 film and substrate lattice. The applied strain is accompanied by an increased lateral defect density, which is decaying for relaxed thicker films and attributed to the growth of lateral grains. Determination of cationic site occupancies in the inverse spinel structure by analysis of site sensitive diffraction peaks reveals low tetrahedral occupancies for thin, strained NiFe2_2O4_4 films, resulting in partial presence of deficient rock salt like structures. These structures are assumed to be responsible for the enhanced magnetization of up to \sim250\% of the NiFe2_2O4_4 bulk magnetization as observed by superconducting quantum interference device magnetometry for ultrathin films below 7.3 nm thickness.Comment: 11 pages, 9 figure

    The Mediterranean deep-water kelp Laminaria rodriguezii is an endangered species in the Adriatic Sea

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    Acknowledgments Thanks are due to Klaus Lüning for a gametophyte culture of L. abyssalis, and to Britta Schaffelke for a herbarium specimen of L. rodriguezii from the western Mediterranean. We are grateful to the Total Foundation (Paris) for funding this study within the framework of the project “Brown algal ecology and biodiversity in the eastern Mediterranean Sea”, and to the MASTS pooling initiative (Marine Alliance for Science and Technology for Scotland, funded by the Scottish Funding Council and contributing institutions; grant reference HR09011), as well as Croatian Ministry of Science, Education and Sports for supporting project “Benthic communities in the Adriatic Sea (Project ID: 0001005)”. Open access via Springer Compact AgreementPeer reviewedPublisher PD

    Electronic structure study by means of X-ray spectroscopy and theoretical calculations of the "ferric star" single molecule magnet

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    The electronic structure of the single molecule magnet system M[Fe(L)2]3*4CHCl3 (M=Fe,Cr; L=CH3N(CH2CH2O)2) has been studied using X-ray photoelectron spectroscopy, X-ray absorption spectroscopy, soft X-ray emission spectroscopy, and density functional calculations. There is good agreement between theoretical calculations and experimental data. The valence band mainly consists of three bands between 2 eV and 30 eV. Both theory and experiments show that the top of the valence band is dominated by the hybridization between Fe 3d and O 2p bands. From the shape of the Fe 2p spectra it is argued that Fe in the molecule is most likely in the 2+ charge state. Its neighboring atoms (O,N) exhibit a magnetic polarisation yielding effective spin S=5/2 per iron atom, giving a high spin state molecule with a total S=5 effective spin for the case of M = Fe.Comment: Fig.2 replaced as it will appear in J. Chem. Phy

    Iodine and fluorine concentrations in seaweeds of the Arabian Gulf identified by morphology and DNA barcodes

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    Acknowledgements: We are grateful to the Kuwait Institute for Scientific Research (KISR) for PhD funding for Hanan Al-Adilah. We are thankful the sequencing facility in Kuwait University (Project # GS01/02) and Department of Marine Sciences for using their facilities and labs. We would equally like to thank the UK Natural Environment Research Council for their support to FCK (program Oceans 2025 – WP 4.5 and grants NE/D521522/1 and NE/J023094/1). This work also received support from the Marine Alliance for Science and Technology for Scotland pooling initiative. MASTS is funded by the Scottish Funding Council (grant reference HR09011) and contributing institutions.Peer reviewedPublisher PD

    Juvenile morphology of the large Antarctic canopy-forming brown alga, Desmarestia menziesii J. Agardh

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    Open Access via Springer Compact Agreement. We are grateful to the UK Natural Environment Research Council for funding to FCK (grants NE/D521522/1 and NE/J023094/1), in particular through the Collaborative Antarctic Science Scheme (Grant CASS-134, 2017) to FCK and LSP. Funding for cruise-based observations in 2019 was from US National Science Foundation award OPP-1744550 to CDA. We thank Kate Stanton, Teresa Murphy and Ben Robinson (British Antarctic Survey) for support with diving operations around Rothera in January–February 2018, and also Richard L. Moe (UC Berkeley) for locating specimens corresponding to the morphology described here in the UC collection. Special thanks are due to Charlie Bibby (Financial Times) for taking professional photographs of the unknown Desmarestia sp. in the aquarium of the Bonner Lab at Rothera (Fig. 2a). We would also like to thank Richard L. Moe (UC Berkeley) and Christian Wiencke (AWI Bremerhaven) for their very helpful reviews of this paper. Also, the MASTS pooling initiative (Marine Alliance for Science and Technology for Scotland, funded by the Scottish Funding Council and contributing institutions; grant reference HR09011) is gratefully acknowledged for supporting FCK. This research contributes to the SCAR Ant-ERA research programme.Peer reviewedPublisher PD

    Resonant Inelastic X-ray Scattering Studies of Elementary Excitations

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    In the past decade, Resonant Inelastic X-ray Scattering (RIXS) has made remarkable progress as a spectroscopic technique. This is a direct result of the availability of high-brilliance synchrotron X-ray radiation sources and of advanced photon detection instrumentation. The technique's unique capability to probe elementary excitations in complex materials by measuring their energy-, momentum-, and polarization-dependence has brought RIXS to the forefront of experimental photon science. We review both the experimental and theoretical RIXS investigations of the past decade, focusing on those determining the low-energy charge, spin, orbital and lattice excitations of solids. We present the fundamentals of RIXS as an experimental method and then review the theoretical state of affairs, its recent developments and discuss the different (approximate) methods to compute the dynamical RIXS response. The last decade's body of experimental RIXS data and its interpretation is surveyed, with an emphasis on RIXS studies of correlated electron systems, especially transition metal compounds. Finally, we discuss the promise that RIXS holds for the near future, particularly in view of the advent of x-ray laser photon sources.Comment: Review, 67 pages, 44 figure

    Morphological, genotypic and metabolomic signatures confirm interfamilial hybridization between the ubiquitous kelps Macrocystis (Arthrothamnaceae) and Lessonia (Lessoniaceae)

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    We thank the support from G. Millne (UoA), M. Rateb (UoA) and D. Zagal (UACh) in the histological preparations, mass spectrometry set-up and the cultivation of the hybrid progeny, respectively. PM and LM developed part of this work with BecasChile (Fondecyt) funding, specifically grants No. 72130422 (PM) and No. 73140389 (LM). We would like to acknowledge the British Council Newton Fund Institutional Links, project No. 261781172 for funding SS a postdoctoral research fellow. We are also grateful to the UK Natural Environment Research Council for their support to FCK (program Oceans 2025–WP 4.5 and grants NE/D521522/1 and NE/ J023094/1). This work also received support from the Marine Alliance for Science and Technology for Scotland pooling initiative. MASTS is funded by the Scottish Funding Council (grant reference HR09011) and contributing institutions. RW thanks financial support from Gobierno Regional de Los Lagos (grants FIC 2012 E7259-2 and FIC 2013 BIP30234872-0) and Fondef, Conicyt (HUAM AQ12I0010), which allows the sampling expeditions at Chiloe Island by PM, LM, DJP.Peer reviewedPublisher PD

    Imaging Molecular Structure through Femtosecond Photoelectron Diffraction on Aligned and Oriented Gas-Phase Molecules

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    This paper gives an account of our progress towards performing femtosecond time-resolved photoelectron diffraction on gas-phase molecules in a pump-probe setup combining optical lasers and an X-ray Free-Electron Laser. We present results of two experiments aimed at measuring photoelectron angular distributions of laser-aligned 1-ethynyl-4-fluorobenzene (C8H5F) and dissociating, laseraligned 1,4-dibromobenzene (C6H4Br2) molecules and discuss them in the larger context of photoelectron diffraction on gas-phase molecules. We also show how the strong nanosecond laser pulse used for adiabatically laser-aligning the molecules influences the measured electron and ion spectra and angular distributions, and discuss how this may affect the outcome of future time-resolved photoelectron diffraction experiments.Comment: 24 pages, 10 figures, Faraday Discussions 17
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