Corrosion inhibition of mild steel in 15 wt.% HCl by durum wheat

The toxicity of most commercial corrosion inhibitors and strict environmental legislations have required the development of environmentally-friendly, cheap and non-toxic inhibitors. The use of natural products, especially of plant origin as corrosion inhibitors has become an area of increasing research because plant extracts contain an incredibly rich source of natural chemical compounds which can be extracted by simple procedures at low-cost. Durum wheat was investigated in this work because functional groups were identified which suggested that it could be a promising potential inhibitor. The corrosion of mild steel in 15 wt.% HCl solution with and without Durum wheat was investigated and directly compared to results from two commercial corrosion inhibitors, propargyl alcohol and 2- mercaptobenzimidazole, under the same conditions, by comparing weight loss with and without inhibition. The durum wheat powder and adsorbed films were characterised by Fourier transform infrared spectroscopy (FTIR), and the exposed samples were characterised using SEM, EDS spectroscopy and surface profilometry. The effects of concentration, temperature (20-60°C) and immersion time (5-24 h) on the corrosion inhibition were investigated. Durum wheat was shown to be a successful green corrosion inhibitor with a room temperature inhibition efficiency of 97% (as compared to values of 99% and 97% for propargyl alcohol and 2 - mercapto benzimidazole respectively) and at a lower cost per l L of corrosive solution. However, at the severe corrosive conditions chosen for this research, the inhibition performance of both durum wheat and 2- mercaptobenzimidazole was influenced by time and temperature, and the durum wheat corrosion inhibition was reduced to 78% after 24 hours at 60°C, compared to 88% for 2- mercaptobenzimidazole. All the inhibitors investigated obeyed Langmuir adsorption isotherm

Reducing porosity in AlSi10Mg parts processed by selective laser melting

Selective laser melting (SLM) is widely gaining popularity as an alternative manufacturing technique for complex and customized parts. SLM is a near net shape process with minimal post processing machining required dependent upon final application. The fact that SLM produces little waste and enables more optimal designs also raises opportunities for environmental advantages. The use of aluminium (Al) alloys in SLM is still quite limited due to difficulties in processing that result in parts with high degrees of porosity. However, Al alloys are favoured in many high-end applications for their exceptional strength and stiffness to weight ratio meaning that they are extensively used in the automotive and aerospace industries. This study investigates the windows of parameters required to produce high density parts from AlSi10Mg alloy using selective laser melting. A compromise between the different parameters and scan strategies was achieved and used to produce parts achieving a density of 99.8%

Mechanical behavior optimization of chitosan extracted from shrimp shells as a sustainable material for shopping bags

The use of biodegradable materials for shopping bag production, and other products made from plastics, has recently been an object of intense research—with the aim of reducing the environmental burdens given by conventional materials. Chitosan is a potential material because of its biocompatibility, degradability, and non-toxicity. It is a semi-natural biopolymeric material produced by the deacetylation of chitin, which is the second most abundant natural biopolymer (after cellulose). Chitin is found in the exoskeleton of insects, marine crustaceans, and the cell walls of certain fungi and algae. The raw materials most abundantly available are the shells of crab, shrimp, and prawn. Hence, in this study chitosan was selected as one of the main components of biodegradable materials used for shopping bag production. Firstly, chitin was extracted from shrimp shell waste and then converted to chitosan. The chitosan was next ground to a powder. Although, currently, polyethylene bags are prepared by blown extrusion, in this preliminary research the chitosan powder was dissolved in a solvent and the films were cast. Composite films with several fillers were used as a reinforcement at different dosages to optimize mechanical properties, which have been assessed using tensile tests. These results were compared with those of conventional polyethylene bags used in Egypt. Overall, the chitosan films were found to have a lower ductility but appeared to be strong enough to fulfill shopping bag functions. The addition of fillers, such as chitin whiskers and rice straw, enhanced the mechanical properties of chitosan films, while the addition of chitin worsened overall mechanical behavior

Selective laser melting of aluminium alloys

Metal additive manufacturing (AM) processes, such as selective laser melting, enable powdered metals to be formed into arbitrary 3D shapes. For aluminium alloys, which are desirable in many high-value applications for their low density and good mechanical performance, selective laser melting is regarded as challenging due to the difficulties in laser melting aluminium powders. However, a number of studies in recent years have demonstrated successful aluminium processing, and have gone on to explore its potential for use in advanced, AM componentry. In addition to enabling the fabrication of highly complex structures, selective laser melting produces parts with characteristically fine microstructures that yield distinct mechanical properties. Research is rapidly progressing in this field, with promising results opening up a range of possible applications across scientific and industrial sectors. This paper reports on recent developments in this area of research as well as highlighting some key topics that require further attention

Nanoindentation shows uniform local mechanical properties across melt pools and layers produced by selective laser melting of AlSi10Mg alloy

Single track and single layer AlSi10Mg has been produced by selective laser melting (SLM) of alloy powder on a AlSi12 cast substrate. The SLM technique produced a cellular-dendritic ultra-fined grained microstructure. Chemical composition mapping and nanoindentation showed higher hardness in the SLM material compared to its cast counterpart. Importantly, although there was some increase of grain size at the edge of melt pools, nanoindentation showed that the hardness (i.e. yield strength) of the material was uniform across overlapping tracks. This is attributed to the very fine grain size and homogeneous distribution of Si throughout the SLM material

Mechanical Properties of Selective Laser Melted AlSi10Mg: Nano, Micro, and Macro Properties

The selective laser melting (SLM) of aluminium alloys is of great current interest at both the industrial and research levels. Aluminium poses a challenge to SLM compared with other candidate materials, such as titanium alloys, stainless steels, and nickel-based alloys, because of its high thermal diffusivity and low infrared absorptivity and tendency to result in relatively porous parts. However, recent studies have reported the successful production of dense AlSi10Mg parts using SLM. In this study, we report on the nano, micro, and macroscopic mechanical properties of dense AlSi10Mg samples fabricated by SLM. Nanoindentation revealed the hardness profile across individual melt pools building up the parts to be uniform. This is due to the fine microstructure and uniform chemical elements distribution developed during the process due to rapid solidification. Micro-hardness testing showed anisotropy in properties according to the build orientation driven by the texture produced during solidification. Lastly, the tensile and compressive behaviours of the parts were examined showing high strength under both loading conditions as well as adequate amounts of strain. These superior mechanical properties compared to those achieved via conventional manufacturing promote SLM as promising for several applications.Mechanical Engineerin

The use of decellularised animal tissue to study disseminating cancer cells

Since the establishment of cell culture, common practice has been to grow adherent cells in 2D monolayers. Although cells behave completely differently when grown under these artificial conditions, the ease of 2D culturing has meant that this practice still prevails, and adopting conditions that more closely reflect the natural microenvironment has been met with substantial inertia. The alternative, animal models that mimic natural human physiology, are less accessible, strictly regulated and require licences and expensive facilities. Although transition from 2D to 3D cell culturing is gathering momentum, there is a clear need for alternative culturing methods that more closely resemble in vivo conditions. Here, we show that decellularised organs gleaned from discarded animal carcasses are ideal biomimetic scaffolds to support secondary tumour initiation in vitro. Further, we describe how to decellularise tissue and perform basic histochemistry and immunofluorescence procedures for cell and matrix detection. Cancer cell behaviour on this matrix is followed by way of an example. Because integration into the traditional work flow is easy and inexpensive, we hope this article will encourage other researchers to adopt this approach

On the formation of AlSi10Mg single tracks and layers in selective laser melting: microstructure and nano-mechanical properties

Selective laser melting (SLM) is a relatively new manufacturing technique that can be used to process a range of materials. Aluminum alloys are potential candidates for SLM but are more difficult to process than the titanium alloys more commonly used with this technique. This is because of the former’s physical properties that can result in high levels of porosity in the final parts. Although the majority of studies to date into the processing of Al alloys by SLM have considered the development of load bearing objects, in particular porosity reduction and mechanical characterization of the parts, it is also important to study the single tracks formed during the process. This paper studies the effect of changing the scan speed on the formation of fusion lines and single tracks from an Al alloy, as well as their overlap to form a single layer. The geometrical features of the melt pools as well as the boundaries of continuity and/or irregularities were defined and showed dependence on scan speed. Keyhole mode melting domination was observed. The scan tracks and layers were porosity-free suggesting pores to form with layer accumulation. Investigations showed that increasing the layer thickness should be avoided as it promoted defects. Energy dispersive X-ray (EDX) mapping was implemented to compare the chemical composition distribution in the SLM material and its as-cast counterpart. A fine microstructure with homogenous distribution of the alloying elements was observed. Nanoindentation and EDX were used to establish an understanding of the hardness profile across melt pools of single tracks and their interrelation to the chemical composition. The elemental distribution yielded uniform high nano-hardness with no spatial variation across the SLM material

Low-Voltage SEM of Natural Plant Fibers: Microstructure Properties (Surface and Cross-Section) and their Link to the Tensile Properties

In this study, the microstructure of different natural plant fibers (flax, jute, ramie, and sisal fibers) were characterized by using low-voltage Scanning Electron Microscopy (LV-SEM). The LV-SEM observations indicated that jute and sisal fibers exhibit less variation in terms of the fiber cross-sectional area, internal lumen shape and size, and cell wall thickness in comparison to flax and ramie fibers. We find that this is also reflected in the tensile properties of the fibers. The tensile properties of single ramie fibers and their fracture behavior was investigated in detail. The stress-strain behavior showed two distinctive regimes. For linear curves, the tensile strength varies from 648-1086 MPa whereas nonlinear curves result in much lower values (177-452) MPa. This variation was linked to differences in the microstructure of the fibers. The LV-SEM of the tensile fracture surfaces of ramie fibers revealed details on the cell wall structure and its fracture behavior under tensile load. Moreover, the SEM images confirm that the collapse of the primary cell wall generally leads to a non-linear stress-strain curve for single ramie fibers