581 research outputs found
Dynamics and kinetics of molecular high Rydberg states in the presence of an electrical field an experimental and classical computational study
In search of multipolar order on the Penrose tiling
Based on Monte Carlo calculations, multipolar ordering on the Penrose tiling,
relevant for two-dimensional molecular adsorbates on quasicrystalline surfaces
and for nanomagnetic arrays, has been analyzed. These initial investigations
are restricted to multipolar rotors of rank one through four - described by
spherical harmonics Ylm with l=1...4 and restricted to m=0 - positioned on the
vertices of the rhombic Penrose tiling. At first sight, the ground states of
odd-parity multipoles seem to exhibit long-range multipolar order, indicated by
the appearance of a superstructure in the form of the decagonal
Hexagon-Boat-Star tiling, in agreement with previous investigations of dipolar
systems. Yet careful analysis establishes that long-range multipolar order is
absent in all cases investigated here, and only short-range order exists. This
result should be taken as a warning for any future analysis of order in either
real or simulated arrangements of multipoles on quasiperiodic templates
Cascade Encryption Revisited
The security of cascade blockcipher encryption is an important and well-studied problem in theoretical cryptography with practical implications. It is well-known that double encryption improves the security only marginally, leaving triple encryption as the shortest reasonable cascade. In a recent paper, Bellare and Rogaway showed that in the ideal cipher model, triple encryption is significantly more secure than single and double encryption, stating the security of longer cascades as an open question.
In this paper, we propose a new lemma on the indistinguishability of systems extending Maurer\u27s theory of random systems. In addition to being of independent interest, it allows us to compactly rephrase Bellare and Rogaway\u27s proof strategy in this framework, thus making the argument more abstract and hence easy to follow. As a result, this allows us to address the security of longer cascades as well as some errors in their paper. Our result implies that for blockciphers with smaller key space than message space (e.g. DES), longer cascades improve the security of the encryption up to a certain limit. This partially answers the open question mentioned above
Towards magnetic slowing of atoms and molecules
We outline a method to slow paramagnetic atoms or molecules using pulsed
magnetic fields. We also discuss the possibility of producing trapped particles
by adiabatic deceleration of a magnetic trap. We present numerical simulation
results for the slowing and trapping of molecular oxygen
Comment on ``Antiferromagnetic Potts Models''
We show that the Wang-Swendsen-Koteck\'y algorithm for antiferromagnetic -state Potts models is nonergodic at zero temperature for on periodic lattices where are relatively prime. For and/or other lattice sizes or boundary conditions, the ergodicity at zero temperature is an open question
Unsplittable coverings in the plane
A system of sets forms an {\em -fold covering} of a set if every point
of belongs to at least of its members. A -fold covering is called a
{\em covering}. The problem of splitting multiple coverings into several
coverings was motivated by classical density estimates for {\em sphere
packings} as well as by the {\em planar sensor cover problem}. It has been the
prevailing conjecture for 35 years (settled in many special cases) that for
every plane convex body , there exists a constant such that every
-fold covering of the plane with translates of splits into
coverings. In the present paper, it is proved that this conjecture is false for
the unit disk. The proof can be generalized to construct, for every , an
unsplittable -fold covering of the plane with translates of any open convex
body which has a smooth boundary with everywhere {\em positive curvature}.
Somewhat surprisingly, {\em unbounded} open convex sets do not misbehave,
they satisfy the conjecture: every -fold covering of any region of the plane
by translates of such a set splits into two coverings. To establish this
result, we prove a general coloring theorem for hypergraphs of a special type:
{\em shift-chains}. We also show that there is a constant such that, for
any positive integer , every -fold covering of a region with unit disks
splits into two coverings, provided that every point is covered by {\em at
most} sets
Localized helium excitations in 4He_N-benzene clusters
We compute ground and excited state properties of small helium clusters 4He_N
containing a single benzene impurity molecule. Ground-state structures and
energies are obtained for N=1,2,3,14 from importance-sampled, rigid-body
diffusion Monte Carlo (DMC). Excited state energies due to helium vibrational
motion near the molecule surface are evaluated using the projection operator,
imaginary time spectral evolution (POITSE) method. We find excitation energies
of up to ~23 K above the ground state. These states all possess vibrational
character of helium atoms in a highly anisotropic potential due to the aromatic
molecule, and can be categorized in terms of localized and collective
vibrational modes. These results appear to provide precursors for a transition
from localized to collective helium excitations at molecular nanosubstrates of
increasing size. We discuss the implications of these results for analysis of
anomalous spectral features in recent spectroscopic studies of large aromatic
molecules in helium clusters.Comment: 15 pages, 5 figures, submitted to Phys. Rev.
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