52,138 research outputs found
CANOZE measurements of the Arctic ozone hole
In CANOZE 1 (Canadian Ozone Experiment), a series of 20 ozone profile measurements were made in April, 1986 from Alert at 82.5 N. CANOZE is the Canadian program for study of the Arctic winter ozone layer. In CANOZE 2, ozone profile measurements were made at Saskatoon, Edmonton, Churchill and Resolute during February and March, 1987 with ECC ozonesondes. Ground based measurements of column ozone, nitrogen dioxide and hydrochloric acid were conducted at Saskatoon. Two STRATOPROBE balloon flights were conducted on February 26 and March 19, 1987. Two aerosol flights were conducted by the University of Wyoming. The overall results of this study will be reported and compared with the NOZE findings. The results from CANOZE 3 in 1988, are also discussed. In 1988, as part of CANOZE 3, STRATOPROBE balloon flights were conducted from Saskatchewan on January 27 and February 13. A new lightweight infrared instrument was developed and test flown. A science flight was successfully conducted from Alert (82.5 N) on March 9, 1988 when the vortex was close to Alert; a good measurement of the profile of nitric acid was obtained. Overall, the Arctic spring ozone layer exhibits many of the features of the Antarctic ozone phenomenon, although there is obviously not a hole present every year. The Arctic ozone field in March, 1986 demonstrated many similarities to the Antarctic ozone hole. The TOMS imagery showed a crater structure in the ozone field similar to the Antarctic crater in October. Depleted layers of ozone were found in the profiles around 15 km, very similar to those reported from McMurdo. Enhanced levels of nitric acid were measured in air which had earlier been in the vortex. The TOMS imagery for March 1987 did not show an ozone crater, but will be examined for an ozone crater in February and March, 1988, the target date for the CANOZE 3 project
Pair-factorized steady states on arbitrary graphs
Stochastic mass transport models are usually described by specifying hopping
rates of particles between sites of a given lattice, and the goal is to predict
the existence and properties of the steady state. Here we ask the reverse
question: given a stationary state that factorizes over links (pairs of sites)
of an arbitrary connected graph, what are possible hopping rates that converge
to this state? We define a class of hopping functions which lead to the same
steady state and guarantee current conservation but may differ by the induced
current strength. For the special case of anisotropic hopping in two dimensions
we discuss some aspects of the phase structure. We also show how this case can
be traced back to an effective zero-range process in one dimension which is
solvable for a large class of hopping functions.Comment: IOP style, 9 pages, 1 figur
Coping with Poorly Understood Domains: the Example of Internet Trust
The notion of trust, as required for secure operations over the Internet, is important for ascertaining the source of received messages. How can we measure the degree of trust in authenticating the source? Knowledge in the domain is not established, so knowledge engineering becomes knowledge generation rather than mere acquisition. Special techniques are required, and special features of KBS software become more important than in conventional domains. This paper generalizes from experience with Internet trust to discuss some techniques and software features that are important for poorly understood domains
Theoretical and numerical studies of chemisorption on a line with precursor layer diffusion
We consider a model for random deposition of monomers on a line with
extrinsic precursor states. As the adsorbate coverage increases, the system
develops non-trivial correlations due to the diffusion mediated deposition
mechanism. In a numeric simulation, we study various quantities describing the
evolution of the island structure. We propose a simple, self-consistent theory
which incorporates pair correlations. The results for the correlations, island
density number, average island size and probabilities of island nucleation,
growth and coagulation show good agreement with the simulation data.Comment: 17 pages(LaTeX), 11 figures(1 PS file, uuencoded), submmited to Phys.
Rev.
Numerical Evidence for Divergent Burnett Coefficients
In previous papers [Phys. Rev. A {\bf 41}, 4501 (1990), Phys. Rev. E {\bf
18}, 3178 (1993)], simple equilibrium expressions were obtained for nonlinear
Burnett coefficients. A preliminary calculation of a 32 particle Lennard-Jones
fluid was presented in the previous paper. Now, sufficient resources have
become available to address the question of whether nonlinear Burnett
coefficients are finite for soft spheres. The hard sphere case is known to have
infinite nonlinear Burnett coefficients (ie a nonanalytic constitutive
relation) from mode coupling theory. This paper reports a molecular dynamics
caclulation of the third order nonlinear Burnett coefficient of a Lennard-Jones
fluid undergoing colour flow, which indicates that this term is diverges in the
thermodynamic limit.Comment: 12 pages, 9 figure
The beginnings of geography teaching and research in the University of Glasgow: the impact of J.W. Gregory
J.W. Gregory arrived in Glasgow from Melbourne in 1904 to take up the post of foundation Professor of Geology in the University of Glasgow. Soon after his arrival in Glasgow he began to push for the setting up of teaching in Geography in Glasgow, which came to pass in 1909 with the appointment of a Lecturer in Geography. This lecturer was based in the Department of Geology in the University's East Quad. Gregory's active promotion of Geography in the University was matched by his extensive writing in the area, in textbooks, journal articles and popular books. His prodigious output across a wide range of subject areas is variably accepted today, with much of his geomorphological work being judged as misguided to varying degrees. His 'social science' publications - in the areas of race, migration, colonisation and economic development of Africa and Australia - espouse a viewpoint that is unacceptable in the twenty-first century. Nonetheless, that viewpoint sits squarely within the social and economic traditions of Gregory's era, and he was clearly a key 'Establishment' figure in natural and social sciences research in the first half of the twentieth century. The establishment of Geography in the University of Glasgow remains enduring testimony of J.W. Gregory's energy, dedication and foresight
Achieving equity through 'gender autonomy': the challenges for VET policy and practice
This paper is based on research carried out in an EU Fifth Framework project on 'Gender and Qualification'. The research partners from five European countries investigated the impact of gender segregation in European labour markets on vocational education and training, with particular regard to competences and qualifications. The research explored the part played by gender in the vocational education and training experiences of (i) young adults entering specific occupations in child care, electrical engineering and food preparation/service (ii) adults changing occupations
Long range polarization attraction between two different likely charged macroions
It is known that in a water solution with multivalent counterions (Z-ions),
two likely charged macroions can attract each other due to correlations of
Z-ions adsorbed on their surfaces. This "correlation" attraction is
short-ranged and decays exponentially with increasing distance between
macroions at characteristic distance A/2\pi, where A is the average distance
between Z-ions on the surfaces of macroions. In this work, we show that an
additional long range "polarization" attraction exists when the bare surface
charge densities of the two macroions have the same sign, but are different in
absolute values. The key idea is that with adsorbed Z-ions, two insulating
macroions can be considered as conductors with fixed but different electric
potentials. Each potential is determined by the difference between the entropic
bulk chemical potential of a Z-ion and its correlation chemical potential at
the surface of the macroion determined by its bare surface charge density. When
the two macroions are close enough, they get polarized in such a way that their
adjacent spots form a charged capacitor, which leads to attraction. In a salt
free solution this polarization attractive force is long ranged: it decays as a
power of the distance between the surfaces of two macroions, d. The
polarization force decays slower than the van der Waals attraction and
therefore is much larger than it in a large range of distances. In the presence
of large amount of monovalent salt, when A/2\pi<< d<< r_s (r_s is the
Debye-H\"{u}ckel screening radius), this force is still much stronger than the
van der Waals attraction and the correlation attraction mentioned above.Comment: 12 pages, 7 figures. Small change in the text, no change in result
Depletion potentials in highly size-asymmetric binary hard-sphere mixtures: Comparison of accurate simulation results with theory
We report a detailed study, using state-of-the-art simulation and theoretical
methods, of the depletion potential between a pair of big hard spheres immersed
in a reservoir of much smaller hard spheres, the size disparity being measured
by the ratio of diameters q=\sigma_s/\sigma_b. Small particles are treated
grand canonically, their influence being parameterized in terms of their
packing fraction in the reservoir, \eta_s^r. Two specialized Monte Carlo
simulation schemes --the geometrical cluster algorithm, and staged particle
insertion-- are deployed to obtain accurate depletion potentials for a number
of combinations of q\leq 0.1 and \eta_s^r. After applying corrections for
simulation finite-size effects, the depletion potentials are compared with the
prediction of new density functional theory (DFT) calculations based on the
insertion trick using the Rosenfeld functional and several subsequent
modifications. While agreement between the DFT and simulation is generally
good, significant discrepancies are evident at the largest reservoir packing
fraction accessible to our simulation methods, namely \eta_s^r=0.35. These
discrepancies are, however, small compared to those between simulation and the
much poorer predictions of the Derjaguin approximation at this \eta_s^r. The
recently proposed morphometric approximation performs better than Derjaguin but
is somewhat poorer than DFT for the size ratios and small sphere packing
fractions that we consider. The effective potentials from simulation, DFT and
the morphometric approximation were used to compute the second virial
coefficient B_2 as a function of \eta_s^r. Comparison of the results enables an
assessment of the extent to which DFT can be expected to correctly predict the
propensity towards fluid fluid phase separation in additive binary hard sphere
mixtures with q\leq 0.1.Comment: 16 pages, 9 figures, revised treatment of morphometric approximation
and reordered some materia
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