238 research outputs found
Single charge and exciton dynamics probed by molecular-scale-induced electroluminescence
Excitons and their constituent charge carriers play the central role in
electroluminescence mechanisms determining the ultimate performance of organic
optoelectronic devices. The involved processes and their dynamics are often
studied with time-resolved techniques limited by spatial averaging that
obscures the properties of individual electron-hole pairs. Here we overcome
this limit and characterize single charge and exciton dynamics at the nanoscale
by using time-resolved scanning tunnelling microscopy-induced luminescence
(TR-STML) stimulated with nanosecond voltage pulses. We use isolated defects in
C thin films as a model system into which we inject single charges and
investigate the formation dynamics of a single exciton. Tuneable hole and
electron injection rates are obtained from a kinetic model that reproduces the
measured electroluminescent transients. These findings demonstrate that TR-STML
can track dynamics at the quantum limit of single charge injection and can be
extended to other systems and materials important for nanophotonic devices
syn-Dispiro[1,3-dioxolane-2,17′-pentacyclo[12.2.1.16,9.02,13.05,10]octadecane-18′,2′′-[1,3]dioxolane]-7′,15′-diene
The title compound, C22H28O4, is composed of a central octadecane ring and two spiro[bicyclo[2.2.1]hept[2]ene-7,2′-[1,3]dioxolane] units. This polycycle has pseudo twofold symmetry and the central cyclooctane ring has a distorted boat configuration
The VITROVAC Cavity for the TERA/PIMMS Medical Synchrotron
A proton and light-ion medical synchrotron is characterised by a large frequency swing for the RF between the injection and the top energy. For this purpose, a VITROVAC®-loaded RF cavity has been developed for the Proton-Ion Medical Machine Study (PIMMS) at CERN, and for TERA, the Italian project of a proton and light-ion synchrotron for cancer therapy, based on the PIMMS study. The main features are a large frequency swing, particularly extended to the low frequency range, a very large relative permeability and a low Q factor. The total power needed is less than 100 kW, while a very small bias power is required for the frequency tuning. The main mechanical characteristics are compactness (less than 1.5 m), and simplicity of construction. As a result, the requirements of the medical synchrotron are comfortably satisfied, namely: 0.4 to 3 MHz swing, 3 kV peak voltage at a repetition rate of less than 1 s
Extracting the Transport Channel Transmissions in Scanning Tunneling Microscopy using the Superconducting Excess Current
Transport through quantum coherent conductors, like atomic junctions, is
described by the distribution of conduction channels. Information about the
number of channels and their transmission can be extracted from various
sources, such as multiple Andreev reflections, dynamical Coulomb blockade, or
shot noise. We complement this set of methods by introducing the
superconducting excess current as a new tool to continuously extract the
transport channel transmissions of an atomic scale junction in a scanning
tunneling microscope. In conjunction with ab initio simulations, we employ this
technique in atomic aluminum junctions to determine the influence of the
structure adjacent to the contact atoms on the transport properties.Comment: 8 pages, 9 figures, including supporting informatio
- …